Ultrafine Pt Nanoclusters Confined in a Calixarene-Based {Ni24} Coordination Cage for High-Efficient Hydrogen Evolution Reaction

To obtain stable and ultrafine Pt nanoclusters, a trigonal prismatic coordination cage with the sulfur atoms on the edges was solvothermally synthesized to confine them. In the structure of {Ni24(TC4A-SO2)6(TDC)12 (H2O)6} (H4TC4A-SO2 = p-tert-butylsulfonylcalix­[4]­arene; H2TDC = 2,5-thiophenedicarb...

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Veröffentlicht in:	Journal of the American Chemical Society 2016-12, Vol.138 (50), p.16236-16239
Hauptverfasser:	Wang, Shentang, Gao, Xiaohui, Hang, Xinxin, Zhu, Xiaofei, Han, Haitao, Liao, Wuping, Chen, Wei
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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