Characterization and Subsequent Reactivity of an Fe-Peroxo Porphyrin Generated by Electrochemical Reductive Activation of O2

Reductive activation of O2 is achieved by using the [FeIII(F20TPP)­Cl] (F20TPP = 5,10,15,20-tetrakis­(pentafluorophenyl) porphyrinate) porphyrin through electrochemical reduction of the [FeIII(F20TPP)­(O2 •–)] superoxo complex. Formation of the [FeIII(F20TPP)­(OO)]− peroxo species is monitored by us...

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Veröffentlicht in:	Inorganic chemistry 2016-12, Vol.55 (23), p.12204-12210
Hauptverfasser:	Oliveira, Raquel, Zouari, Wiem, Herrero, Christian, Banse, Frédéric, Schöllhorn, Bernd, Fave, Claire, Anxolabéhère-Mallart, Elodie
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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