General Method for the Synthesis of Functionalized Tetrabenzo[8]circulenes

Functionalized derivatives of the saddle-shaped molecule tetrabenzo[8]­circulene were successfully synthesized through a Diels–Alder/oxidative cyclodehydrogenation approach. This methodology improves on our previously reported synthesis, affording products containing both electron-rich and electron-...

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Veröffentlicht in:	Journal of organic chemistry 2016-12, Vol.81 (23), p.12001-12005
Hauptverfasser:	Miller, Robert W, Averill, Summer E, Van Wyck, Stephen J, Whalley, Adam C
Format:	Artikel
Sprache:	eng
Schlagworte:	Benzene - chemistry Carbon-13 Magnetic Resonance Spectroscopy Cycloaddition Reaction Electrochemical Techniques Models, Molecular Oxidation-Reduction Polycyclic Aromatic Hydrocarbons - chemistry Proton Magnetic Resonance Spectroscopy Spectrometry, Mass, Electrospray Ionization
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