Triphenylbismuth carbonate-mediated oxidation of hydroxylamines to nitrones and in situ 1,3-dipolar cycloaddition
Triphenylbismuth carbonate was shown to act as a mild, selective and efficient reagent for the oxidation of hydroxylamines. The developed reaction conditions were shown to be compatible with the in situ trapping of the produced nitrones by a strained alkyne, via a [3 + 2] cycloaddition reaction.
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| Veröffentlicht in: | RSC advances 2016-01, Vol.6 (92), p.89238-89241 |
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| container_end_page | 89241 |
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| container_issue | 92 |
| container_start_page | 89238 |
| container_title | RSC advances |
| container_volume | 6 |
| creator | Nguyen, Dinh-Vu Prakash, Praveen Gravel, Edmond Doris, Eric |
| description | Triphenylbismuth carbonate was shown to act as a mild, selective and efficient reagent for the oxidation of hydroxylamines. The developed reaction conditions were shown to be compatible with the
in situ
trapping of the produced nitrones by a strained alkyne,
via
a [3 + 2] cycloaddition reaction. |
| doi_str_mv | 10.1039/C6RA18578A |
| format | Article |
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in situ
trapping of the produced nitrones by a strained alkyne,
via
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in situ
trapping of the produced nitrones by a strained alkyne,
via
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in situ
trapping of the produced nitrones by a strained alkyne,
via
a [3 + 2] cycloaddition reaction.</abstract><doi>10.1039/C6RA18578A</doi><tpages>4</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 2046-2069 |
| ispartof | RSC advances, 2016-01, Vol.6 (92), p.89238-89241 |
| issn | 2046-2069 2046-2069 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_1845840033 |
| source | Royal Society Of Chemistry Journals 2008- |
| subjects | Alkynes Carbonates Compatibility Cycloaddition Oxidation Reagents Trapping |
| title | Triphenylbismuth carbonate-mediated oxidation of hydroxylamines to nitrones and in situ 1,3-dipolar cycloaddition |
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