Troger's base functionalized covalent triazine frameworks for CO2 capture

A series of covalent triazine frameworks containing Troger's base segments (CTF-TBs) were designed and prepared by dynamic trimerization under ionothermal conditions, based on the novel dicyano monomer of dicyano Troger's base (DCTB). The CTF-TBs were all amorphous and exhibited surface ar...

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Veröffentlicht in:RSC advances 2016-01, Vol.6 (97), p.94365-94372
Hauptverfasser: Tao, Liming, Niu, Fang, Liu, Jingang, Wang, Tingmei, Wang, Qihua
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creator Tao, Liming
Niu, Fang
Liu, Jingang
Wang, Tingmei
Wang, Qihua
description A series of covalent triazine frameworks containing Troger's base segments (CTF-TBs) were designed and prepared by dynamic trimerization under ionothermal conditions, based on the novel dicyano monomer of dicyano Troger's base (DCTB). The CTF-TBs were all amorphous and exhibited surface areas between 294 to 732 m2 g-1. The effect of reaction conditions including ratio of catalyst/monomer and temperature on the pore properties was discussed. Meanwhile, the adsorption capacity of CO2 for all the CTF-TBs was studied and the CO2 uptake capacity was up to 16.84 wt% at 273 K and 1.10 bar for CTF-TB-3.
doi_str_mv 10.1039/c6ra21196h
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source Royal Society Of Chemistry Journals 2008-
subjects Carbon dioxide
Covalence
Monomers
Porosity
Segments
Surface area
Surface chemistry
Uptakes
title Troger's base functionalized covalent triazine frameworks for CO2 capture
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