Functional models of nonheme diiron enzymes: kinetic and computational evidence for the formation of oxoiron(iv) species from peroxo-diiron(iii) complexes, and their reactivity towards phenols and H2O2

The reactivity of the previously reported peroxo adducts [Fe2(μ-O2)(L(1))4(CH3CN)2](2+), and [Fe2(μ-O2)(L(2))4(CH3CN)2](2+), (L(1) = 2-(2'-pyridyl)benzimidazole and L(2) = 2-(2'-pyridyl)-N-methylbenzimidazole) towards H2O2 as catalase mimics, and towards various phenols as functional RNR-R...

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Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2016-10, Vol.45 (37), p.14709-14718
Hauptverfasser:	Szávuly, Miklós István, Surducan, Mihai, Nagy, Emőke, Surányi, Mátyás, Speier, Gábor, Silaghi-Dumitrescu, Radu, Kaizer, József
Format:	Artikel
Sprache:	eng
Schlagworte:	Activation Activation analysis Catalase Computation Enzymes Formations Phenols Reaction kinetics
Online-Zugang:	Volltext
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