Enhancement of magnetic anisotropy in a Mn-Bi heterobimetallic complex
A novel Mn 2+ Bi 3+ heterobimetallic complex, featuring the closest Mn Bi interaction for a paramagnetic molecular species, exhibits unusually large axial zero-field splitting. We attribute this enhancement to the proximity of Mn 2+ to a heavy main group element, namely, bismuth. A novel Mn 2+ Bi 3+...
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2016-09, Vol.52 (76), p.11394-11397 |
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| container_end_page | 11397 |
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| container_issue | 76 |
| container_start_page | 11394 |
| container_title | Chemical communications (Cambridge, England) |
| container_volume | 52 |
| creator | Pearson, Tyler J Fataftah, Majed S Freedman, Danna E |
| description | A novel Mn
2+
Bi
3+
heterobimetallic complex, featuring the closest Mn Bi interaction for a paramagnetic molecular species, exhibits unusually large axial zero-field splitting. We attribute this enhancement to the proximity of Mn
2+
to a heavy main group element, namely, bismuth.
A novel Mn
2+
Bi
3+
heterobimetallic complex, featuring the closest Mn Bi interaction for a paramagnetic molecular species, exhibits unusually large axial zero-field splitting. |
| doi_str_mv | 10.1039/c6cc06369a |
| format | Article |
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2+
Bi
3+
heterobimetallic complex, featuring the closest Mn Bi interaction for a paramagnetic molecular species, exhibits unusually large axial zero-field splitting. We attribute this enhancement to the proximity of Mn
2+
to a heavy main group element, namely, bismuth.
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Bi
3+
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2+
Bi
3+
heterobimetallic complex, featuring the closest Mn Bi interaction for a paramagnetic molecular species, exhibits unusually large axial zero-field splitting. We attribute this enhancement to the proximity of Mn
2+
to a heavy main group element, namely, bismuth.
A novel Mn
2+
Bi
3+
heterobimetallic complex, featuring the closest Mn Bi interaction for a paramagnetic molecular species, exhibits unusually large axial zero-field splitting.</description><subject>Bismuth</subject><subject>Magnetic anisotropy</subject><subject>Proximity</subject><subject>Splitting</subject><issn>1359-7345</issn><issn>1364-548X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNqN0T1PwzAQgGELgWgpLOygjAgpYMex44wlagGpiKUDW2RfzjQoX9ipRP89KS1lxYst3aMbXhNyyegdozy9BwlAJZepPiJjxmUcili9HW_fIg0THosROfP-gw6HCXVKRlGSMMapHJP5rFnpBrDGpg9aG9T6vcG-hEA3pW9713aboGwCHbw04UMZrLBH15qyxl5X1cCgrbsKv87JidWVx4v9PSHL-WyZPYWL18fnbLoIgcdRHxasYKowxmjKKOWMpRinMuIoIAItwKqIM5NAiiAYGGoVWGOspAWmsVV8Qm52azvXfq7R93ldesCq0g22a58zFQs1pIjif1AuhlSJTAd6u6PgWu8d2rxzZa3dJmc03xbOM5llP4WnA77e712bGosD_U06gKsdcB4O078v4t-y03_4</recordid><startdate>20160915</startdate><enddate>20160915</enddate><creator>Pearson, Tyler J</creator><creator>Fataftah, Majed S</creator><creator>Freedman, Danna E</creator><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20160915</creationdate><title>Enhancement of magnetic anisotropy in a Mn-Bi heterobimetallic complex</title><author>Pearson, Tyler J ; Fataftah, Majed S ; Freedman, Danna E</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c342t-d1d18dbbba01003119e49623e5c2ca5cf8231b7c9ec51cb0f8cfbbf60de94f83</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Bismuth</topic><topic>Magnetic anisotropy</topic><topic>Proximity</topic><topic>Splitting</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Pearson, Tyler J</creatorcontrib><creatorcontrib>Fataftah, Majed S</creatorcontrib><creatorcontrib>Freedman, Danna E</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Chemical communications (Cambridge, England)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Pearson, Tyler J</au><au>Fataftah, Majed S</au><au>Freedman, Danna E</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Enhancement of magnetic anisotropy in a Mn-Bi heterobimetallic complex</atitle><jtitle>Chemical communications (Cambridge, England)</jtitle><addtitle>Chem Commun (Camb)</addtitle><date>2016-09-15</date><risdate>2016</risdate><volume>52</volume><issue>76</issue><spage>11394</spage><epage>11397</epage><pages>11394-11397</pages><issn>1359-7345</issn><eissn>1364-548X</eissn><abstract>A novel Mn
2+
Bi
3+
heterobimetallic complex, featuring the closest Mn Bi interaction for a paramagnetic molecular species, exhibits unusually large axial zero-field splitting. We attribute this enhancement to the proximity of Mn
2+
to a heavy main group element, namely, bismuth.
A novel Mn
2+
Bi
3+
heterobimetallic complex, featuring the closest Mn Bi interaction for a paramagnetic molecular species, exhibits unusually large axial zero-field splitting.</abstract><cop>England</cop><pmid>27711306</pmid><doi>10.1039/c6cc06369a</doi><tpages>4</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1359-7345 |
| ispartof | Chemical communications (Cambridge, England), 2016-09, Vol.52 (76), p.11394-11397 |
| issn | 1359-7345 1364-548X |
| language | eng |
| recordid | cdi_proquest_miscellaneous_1845806324 |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Bismuth Magnetic anisotropy Proximity Splitting |
| title | Enhancement of magnetic anisotropy in a Mn-Bi heterobimetallic complex |
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