Facile synthesis of single crystalline sub-micron Cu sub(2)ZnSnS sub(4) (CZTS) powders using solvothermal treatment
Single crystalline sub-micron Cu sub(2)ZnSnS sub(4) (CZTS) powders were successfully synthesized by a facile solvothermal method, using l-cysteine as sulfur precursor. It was confirmed that pure kesterite structured CZTS powders were synthesized at 400 degree C after 5 h, with the irregular polygona...
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| Veröffentlicht in: | RSC advances 2014-12, Vol.5 (9), p.6682-6686 |
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| container_issue | 9 |
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| container_title | RSC advances |
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| creator | Chen, Shanlong Tao, Haijun Shen, Yizhou Zhu, Lumin Zeng, Xiaofei Tao, Jie Wang, Tao |
| description | Single crystalline sub-micron Cu sub(2)ZnSnS sub(4) (CZTS) powders were successfully synthesized by a facile solvothermal method, using l-cysteine as sulfur precursor. It was confirmed that pure kesterite structured CZTS powders were synthesized at 400 degree C after 5 h, with the irregular polygonal particle size being 500 nm to 1 mu m. Interestingly, single crystalline CZTS particles were also obtained by simple solvothermal treatment without post annealing. The H sub(2)S released from l-cysteine had an impact on the growth of CZTS particles at high temperature. Further, the as-synthesized CZTS powders were used as counter electrode for dye-sensitized solar cells (DSSCs) and it is indicated that the CZTS counter electrode based DSSCs show a conversion efficiency of 4.243%. |
| doi_str_mv | 10.1039/c4ra12815j |
| format | Article |
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It was confirmed that pure kesterite structured CZTS powders were synthesized at 400 degree C after 5 h, with the irregular polygonal particle size being 500 nm to 1 mu m. Interestingly, single crystalline CZTS particles were also obtained by simple solvothermal treatment without post annealing. The H sub(2)S released from l-cysteine had an impact on the growth of CZTS particles at high temperature. Further, the as-synthesized CZTS powders were used as counter electrode for dye-sensitized solar cells (DSSCs) and it is indicated that the CZTS counter electrode based DSSCs show a conversion efficiency of 4.243%.</description><identifier>EISSN: 2046-2069</identifier><identifier>DOI: 10.1039/c4ra12815j</identifier><language>eng</language><subject>Conversion ; Crystal structure ; CZT ; Efficiency ; Electrodes ; Photovoltaic cells ; Solar cells ; Synthesis</subject><ispartof>RSC advances, 2014-12, Vol.5 (9), p.6682-6686</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Chen, Shanlong</creatorcontrib><creatorcontrib>Tao, Haijun</creatorcontrib><creatorcontrib>Shen, Yizhou</creatorcontrib><creatorcontrib>Zhu, Lumin</creatorcontrib><creatorcontrib>Zeng, Xiaofei</creatorcontrib><creatorcontrib>Tao, Jie</creatorcontrib><creatorcontrib>Wang, Tao</creatorcontrib><title>Facile synthesis of single crystalline sub-micron Cu sub(2)ZnSnS sub(4) (CZTS) powders using solvothermal treatment</title><title>RSC advances</title><description>Single crystalline sub-micron Cu sub(2)ZnSnS sub(4) (CZTS) powders were successfully synthesized by a facile solvothermal method, using l-cysteine as sulfur precursor. It was confirmed that pure kesterite structured CZTS powders were synthesized at 400 degree C after 5 h, with the irregular polygonal particle size being 500 nm to 1 mu m. Interestingly, single crystalline CZTS particles were also obtained by simple solvothermal treatment without post annealing. The H sub(2)S released from l-cysteine had an impact on the growth of CZTS particles at high temperature. 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| fulltext | fulltext |
| identifier | EISSN: 2046-2069 |
| ispartof | RSC advances, 2014-12, Vol.5 (9), p.6682-6686 |
| issn | 2046-2069 |
| language | eng |
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| source | Royal Society Of Chemistry Journals 2008- |
| subjects | Conversion Crystal structure CZT Efficiency Electrodes Photovoltaic cells Solar cells Synthesis |
| title | Facile synthesis of single crystalline sub-micron Cu sub(2)ZnSnS sub(4) (CZTS) powders using solvothermal treatment |
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