Mechanistic insights into sodium storage in hard carbon anodes using local structure probes

Operando Na solid-state NMR and pair distribution function analysis experiments provide insights into the structure of hard carbon anodes in sodium-ion batteries. Capacity results from "diamagnetic" sodium ions first adsorbing onto pore surfaces, defects and between expanded layers, before...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2016-01, Vol.52 (84), p.12430-12433
Hauptverfasser: Stratford, Joshua M, Allan, Phoebe K, Pecher, Oliver, Chater, Philip A, Grey, Clare P
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creator Stratford, Joshua M
Allan, Phoebe K
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description Operando Na solid-state NMR and pair distribution function analysis experiments provide insights into the structure of hard carbon anodes in sodium-ion batteries. Capacity results from "diamagnetic" sodium ions first adsorbing onto pore surfaces, defects and between expanded layers, before pooling into larger quasi-metallic clusters/expanded carbon sheets at lower voltages.
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source Royal Society Of Chemistry Journals; Alma/SFX Local Collection
subjects Anodes
Carbon
Clusters
Electric potential
Porosity
Rechargeable batteries
Sodium
Voltage
title Mechanistic insights into sodium storage in hard carbon anodes using local structure probes
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