Mechanistic insights into sodium storage in hard carbon anodes using local structure probes
Operando Na solid-state NMR and pair distribution function analysis experiments provide insights into the structure of hard carbon anodes in sodium-ion batteries. Capacity results from "diamagnetic" sodium ions first adsorbing onto pore surfaces, defects and between expanded layers, before...
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Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2016-01, Vol.52 (84), p.12430-12433 |
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creator | Stratford, Joshua M Allan, Phoebe K Pecher, Oliver Chater, Philip A Grey, Clare P |
description | Operando
Na solid-state NMR and pair distribution function analysis experiments provide insights into the structure of hard carbon anodes in sodium-ion batteries. Capacity results from "diamagnetic" sodium ions first adsorbing onto pore surfaces, defects and between expanded layers, before pooling into larger quasi-metallic clusters/expanded carbon sheets at lower voltages. |
doi_str_mv | 10.1039/c6cc06990h |
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Na solid-state NMR and pair distribution function analysis experiments provide insights into the structure of hard carbon anodes in sodium-ion batteries. Capacity results from "diamagnetic" sodium ions first adsorbing onto pore surfaces, defects and between expanded layers, before pooling into larger quasi-metallic clusters/expanded carbon sheets at lower voltages.</description><subject>Anodes</subject><subject>Carbon</subject><subject>Clusters</subject><subject>Electric potential</subject><subject>Porosity</subject><subject>Rechargeable batteries</subject><subject>Sodium</subject><subject>Voltage</subject><issn>1359-7345</issn><issn>1364-548X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNqNkE1LxDAQhoMo7rp68QdIjiJU89kmRynqCiteFAQPJUmn20rbrEl78N_bdVfPzmVehod34EHonJJrSri-calzJNWa1AdoTnkqEinU2-E2S51kXMgZOonxg0xDpTpGM5ZljLFUzdH7E7ja9E0cGoebPjbreohTGDyOvmzGDsfBB7OG6YZrE0rsTLC-x6b3JUQ8xqZf49Y7005kGN0wBsCb4C3EU3RUmTbC2X4v0Ov93Uu-TFbPD4_57SpxXGdDkjGwSumMCcfBUmqs04Jao0oniZNMKF5RI2SlbWUrDawEUypwTJIqozblC3S5653efo4Qh6JrooO2NT34MRZUCakIJ1r8A-WSa6WYmtCrHeqCjzFAVWxC05nwVVBSbL0XeZrnP96XE3yx7x1tB-Uf-iuafwN-9X8p</recordid><startdate>20160101</startdate><enddate>20160101</enddate><creator>Stratford, Joshua M</creator><creator>Allan, Phoebe K</creator><creator>Pecher, Oliver</creator><creator>Chater, Philip A</creator><creator>Grey, Clare P</creator><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><orcidid>https://orcid.org/0000-0002-6867-4226</orcidid></search><sort><creationdate>20160101</creationdate><title>Mechanistic insights into sodium storage in hard carbon anodes using local structure probes</title><author>Stratford, Joshua M ; Allan, Phoebe K ; Pecher, Oliver ; Chater, Philip A ; Grey, Clare P</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c397t-72eb889724c3eb11abc941ba8dc50c52483f1a45f9bfbf9e2dead8ec250f71b63</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Anodes</topic><topic>Carbon</topic><topic>Clusters</topic><topic>Electric potential</topic><topic>Porosity</topic><topic>Rechargeable batteries</topic><topic>Sodium</topic><topic>Voltage</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Stratford, Joshua M</creatorcontrib><creatorcontrib>Allan, Phoebe K</creatorcontrib><creatorcontrib>Pecher, Oliver</creatorcontrib><creatorcontrib>Chater, Philip A</creatorcontrib><creatorcontrib>Grey, Clare P</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Chemical communications (Cambridge, England)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Stratford, Joshua M</au><au>Allan, Phoebe K</au><au>Pecher, Oliver</au><au>Chater, Philip A</au><au>Grey, Clare P</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Mechanistic insights into sodium storage in hard carbon anodes using local structure probes</atitle><jtitle>Chemical communications (Cambridge, England)</jtitle><addtitle>Chem Commun (Camb)</addtitle><date>2016-01-01</date><risdate>2016</risdate><volume>52</volume><issue>84</issue><spage>12430</spage><epage>12433</epage><pages>12430-12433</pages><issn>1359-7345</issn><eissn>1364-548X</eissn><abstract>Operando
Na solid-state NMR and pair distribution function analysis experiments provide insights into the structure of hard carbon anodes in sodium-ion batteries. Capacity results from "diamagnetic" sodium ions first adsorbing onto pore surfaces, defects and between expanded layers, before pooling into larger quasi-metallic clusters/expanded carbon sheets at lower voltages.</abstract><cop>England</cop><pmid>27722268</pmid><doi>10.1039/c6cc06990h</doi><tpages>4</tpages><orcidid>https://orcid.org/0000-0002-6867-4226</orcidid><oa>free_for_read</oa></addata></record> |
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subjects | Anodes Carbon Clusters Electric potential Porosity Rechargeable batteries Sodium Voltage |
title | Mechanistic insights into sodium storage in hard carbon anodes using local structure probes |
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