Hydrogenation of Esters to Alcohols Catalyzed by Defined Manganese Pincer Complexes

The first manganese‐catalyzed hydrogenation of esters to alcohols has been developed. The combination of Mn(CO)5Br with [HN(CH2CH2P(Et)2)2] leads to a mixture of cationic and neutral Mn PNP pincer complexes, which enable the reduction of various ester substrates, including aromatic and aliphatic est...

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Veröffentlicht in:	Angewandte Chemie International Edition 2016-12, Vol.55 (49), p.15364-15368
Hauptverfasser:	Elangovan, Saravanakumar, Garbe, Marcel, Jiao, Haijun, Spannenberg, Anke, Junge, Kathrin, Beller, Matthias
Format:	Artikel
Sprache:	eng
Schlagworte:	Alcohol alcohols esters homogeneous catalysis Hydrogenation manganese
Online-Zugang:	Volltext
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