Decarboxylation as the Key Step in C−C Bond‐Forming Reactions
C−C bond forming reactions incarnate the core of organic synthesis because of their fundamental applications to molecular diversity and complexity. In recent years, use of carboxylic acid as one of the coupling partners in place of conventional organometallic reagents has seen an upsurge due to its...
Gespeichert in:
| Veröffentlicht in: | Chemistry : a European journal 2017-06, Vol.23 (31), p.7382-7401 |
|---|---|
| Hauptverfasser: | , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 7401 |
|---|---|
| container_issue | 31 |
| container_start_page | 7382 |
| container_title | Chemistry : a European journal |
| container_volume | 23 |
| creator | Patra, Tuhin Maiti, Debabrata |
| description | C−C bond forming reactions incarnate the core of organic synthesis because of their fundamental applications to molecular diversity and complexity. In recent years, use of carboxylic acid as one of the coupling partners in place of conventional organometallic reagents has seen an upsurge due to its potency to generate similar organometallic intermediates after decarboxylation. This Review provides an overview on the most recent progress in the field of C−C bond formation involving decarboxylation as a key step. Different important developments, which are not included in earlier Reviews in this area, have been summarized with representative examples and discussions on their reaction mechanisms.
C here: This Review article covers the recent and important developments in the rapidly growing field of decarboxylative C−C bond formation. |
| doi_str_mv | 10.1002/chem.201604496 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1841802924</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1904141005</sourcerecordid><originalsourceid>FETCH-LOGICAL-c5466-8fe53b360f99563f89f41d28138ad7571bc03235a7fa043ed4548c5dd92c06bf3</originalsourceid><addsrcrecordid>eNqFkDtPwzAURi0EoqWwMiJLLCwpficeS2gpogiJx2w5jkNT5VHiVJCNkRHxE_tLSNVSJBamu5zv6OoAcIxRHyNEzs3U5n2CsECMSbEDupgT7FFf8F3QRZL5nuBUdsCBczOEkBSU7oMO8QMufSy7YHBpja6i8q3JdJ2WBdQO1lMLb2wDH2o7h2kBw-XHVwgvyiJevn-OyipPi2d4b7VZDdwh2Et05uzR5vbA02j4GI69yd3VdTiYeIYzIbwgsZxGVKBESi5oEsiE4ZgEmAY69rmPI4MooVz7iUaM2phxFhgex5IYJKKE9sDZ2juvypeFdbXKU2dslunClguncMBwgIgkrEVP_6CzclEV7XcKS8Qwa9PxluqvKVOVzlU2UfMqzXXVKIzUKq5axVXbuO3gZKNdRLmNt_hPzRaQa-A1zWzzj06F4-Htr_wb7PWFNA</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1904141005</pqid></control><display><type>article</type><title>Decarboxylation as the Key Step in C−C Bond‐Forming Reactions</title><source>Access via Wiley Online Library</source><creator>Patra, Tuhin ; Maiti, Debabrata</creator><creatorcontrib>Patra, Tuhin ; Maiti, Debabrata</creatorcontrib><description>C−C bond forming reactions incarnate the core of organic synthesis because of their fundamental applications to molecular diversity and complexity. In recent years, use of carboxylic acid as one of the coupling partners in place of conventional organometallic reagents has seen an upsurge due to its potency to generate similar organometallic intermediates after decarboxylation. This Review provides an overview on the most recent progress in the field of C−C bond formation involving decarboxylation as a key step. Different important developments, which are not included in earlier Reviews in this area, have been summarized with representative examples and discussions on their reaction mechanisms.
C here: This Review article covers the recent and important developments in the rapidly growing field of decarboxylative C−C bond formation.</description><identifier>ISSN: 0947-6539</identifier><identifier>EISSN: 1521-3765</identifier><identifier>DOI: 10.1002/chem.201604496</identifier><identifier>PMID: 27859719</identifier><language>eng</language><publisher>Germany: Wiley Subscription Services, Inc</publisher><subject>Carboxylic acids ; Chemistry ; Coupling (molecular) ; C−C coupling ; Decarboxylation ; Intermediates ; Reaction mechanisms ; Reagents ; Reviews ; synthetic methods</subject><ispartof>Chemistry : a European journal, 2017-06, Vol.23 (31), p.7382-7401</ispartof><rights>2017 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.</rights><rights>2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c5466-8fe53b360f99563f89f41d28138ad7571bc03235a7fa043ed4548c5dd92c06bf3</citedby><cites>FETCH-LOGICAL-c5466-8fe53b360f99563f89f41d28138ad7571bc03235a7fa043ed4548c5dd92c06bf3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fchem.201604496$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fchem.201604496$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1417,27924,27925,45574,45575</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/27859719$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Patra, Tuhin</creatorcontrib><creatorcontrib>Maiti, Debabrata</creatorcontrib><title>Decarboxylation as the Key Step in C−C Bond‐Forming Reactions</title><title>Chemistry : a European journal</title><addtitle>Chemistry</addtitle><description>C−C bond forming reactions incarnate the core of organic synthesis because of their fundamental applications to molecular diversity and complexity. In recent years, use of carboxylic acid as one of the coupling partners in place of conventional organometallic reagents has seen an upsurge due to its potency to generate similar organometallic intermediates after decarboxylation. This Review provides an overview on the most recent progress in the field of C−C bond formation involving decarboxylation as a key step. Different important developments, which are not included in earlier Reviews in this area, have been summarized with representative examples and discussions on their reaction mechanisms.
C here: This Review article covers the recent and important developments in the rapidly growing field of decarboxylative C−C bond formation.</description><subject>Carboxylic acids</subject><subject>Chemistry</subject><subject>Coupling (molecular)</subject><subject>C−C coupling</subject><subject>Decarboxylation</subject><subject>Intermediates</subject><subject>Reaction mechanisms</subject><subject>Reagents</subject><subject>Reviews</subject><subject>synthetic methods</subject><issn>0947-6539</issn><issn>1521-3765</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><recordid>eNqFkDtPwzAURi0EoqWwMiJLLCwpficeS2gpogiJx2w5jkNT5VHiVJCNkRHxE_tLSNVSJBamu5zv6OoAcIxRHyNEzs3U5n2CsECMSbEDupgT7FFf8F3QRZL5nuBUdsCBczOEkBSU7oMO8QMufSy7YHBpja6i8q3JdJ2WBdQO1lMLb2wDH2o7h2kBw-XHVwgvyiJevn-OyipPi2d4b7VZDdwh2Et05uzR5vbA02j4GI69yd3VdTiYeIYzIbwgsZxGVKBESi5oEsiE4ZgEmAY69rmPI4MooVz7iUaM2phxFhgex5IYJKKE9sDZ2juvypeFdbXKU2dslunClguncMBwgIgkrEVP_6CzclEV7XcKS8Qwa9PxluqvKVOVzlU2UfMqzXXVKIzUKq5axVXbuO3gZKNdRLmNt_hPzRaQa-A1zWzzj06F4-Htr_wb7PWFNA</recordid><startdate>20170601</startdate><enddate>20170601</enddate><creator>Patra, Tuhin</creator><creator>Maiti, Debabrata</creator><general>Wiley Subscription Services, Inc</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>K9.</scope><scope>7X8</scope></search><sort><creationdate>20170601</creationdate><title>Decarboxylation as the Key Step in C−C Bond‐Forming Reactions</title><author>Patra, Tuhin ; Maiti, Debabrata</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c5466-8fe53b360f99563f89f41d28138ad7571bc03235a7fa043ed4548c5dd92c06bf3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Carboxylic acids</topic><topic>Chemistry</topic><topic>Coupling (molecular)</topic><topic>C−C coupling</topic><topic>Decarboxylation</topic><topic>Intermediates</topic><topic>Reaction mechanisms</topic><topic>Reagents</topic><topic>Reviews</topic><topic>synthetic methods</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Patra, Tuhin</creatorcontrib><creatorcontrib>Maiti, Debabrata</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>MEDLINE - Academic</collection><jtitle>Chemistry : a European journal</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Patra, Tuhin</au><au>Maiti, Debabrata</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Decarboxylation as the Key Step in C−C Bond‐Forming Reactions</atitle><jtitle>Chemistry : a European journal</jtitle><addtitle>Chemistry</addtitle><date>2017-06-01</date><risdate>2017</risdate><volume>23</volume><issue>31</issue><spage>7382</spage><epage>7401</epage><pages>7382-7401</pages><issn>0947-6539</issn><eissn>1521-3765</eissn><abstract>C−C bond forming reactions incarnate the core of organic synthesis because of their fundamental applications to molecular diversity and complexity. In recent years, use of carboxylic acid as one of the coupling partners in place of conventional organometallic reagents has seen an upsurge due to its potency to generate similar organometallic intermediates after decarboxylation. This Review provides an overview on the most recent progress in the field of C−C bond formation involving decarboxylation as a key step. Different important developments, which are not included in earlier Reviews in this area, have been summarized with representative examples and discussions on their reaction mechanisms.
C here: This Review article covers the recent and important developments in the rapidly growing field of decarboxylative C−C bond formation.</abstract><cop>Germany</cop><pub>Wiley Subscription Services, Inc</pub><pmid>27859719</pmid><doi>10.1002/chem.201604496</doi><tpages>20</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0947-6539 |
| ispartof | Chemistry : a European journal, 2017-06, Vol.23 (31), p.7382-7401 |
| issn | 0947-6539 1521-3765 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_1841802924 |
| source | Access via Wiley Online Library |
| subjects | Carboxylic acids Chemistry Coupling (molecular) C−C coupling Decarboxylation Intermediates Reaction mechanisms Reagents Reviews synthetic methods |
| title | Decarboxylation as the Key Step in C−C Bond‐Forming Reactions |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-26T23%3A42%3A11IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Decarboxylation%20as%20the%20Key%20Step%20in%20C%E2%88%92C%20Bond%E2%80%90Forming%20Reactions&rft.jtitle=Chemistry%20:%20a%20European%20journal&rft.au=Patra,%20Tuhin&rft.date=2017-06-01&rft.volume=23&rft.issue=31&rft.spage=7382&rft.epage=7401&rft.pages=7382-7401&rft.issn=0947-6539&rft.eissn=1521-3765&rft_id=info:doi/10.1002/chem.201604496&rft_dat=%3Cproquest_cross%3E1904141005%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1904141005&rft_id=info:pmid/27859719&rfr_iscdi=true |