Synthesis of Atisine, Ajaconine, Denudatine, and Hetidine Diterpenoid Alkaloids by a Bioinspired Approach

A unified approach to four different (atisine, ajaconine, denudatine, and hetidine) diterpenoid alkaloid skeletons was developed and applied to the total synthesis of the natural products dihydroajaconine (2, atisine type) and gymnandine (4, denudatine type). The synthesis features a biogenetically...

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Veröffentlicht in:	Angewandte Chemie International Edition 2016-12, Vol.55 (50), p.15667-15671
Hauptverfasser:	Li, Xiao-Huan, Zhu, Min, Wang, Zhi-Xiu, Liu, Xiao-Yu, Song, Hao, Zhang, Dan, Wang, Feng-Peng, Qin, Yong
Format:	Artikel
Sprache:	eng
Schlagworte:	alkaloids biomimetic synthesis cyclization terpenoids total synthesis
Online-Zugang:	Volltext
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