Selective Production of Carbon Monoxide via Methane Oxychlorination over Vanadyl Pyrophosphate

A catalytic process is demonstrated for the selective conversion of methane into carbon monoxide via oxychlorination chemistry. The process involves addition of HCl to a CH4–O2 feed to facilitate C−H bond activation under mild conditions, leading to the formation of chloromethanes, CH3Cl and CH2Cl2....

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Veröffentlicht in:	Angewandte Chemie International Edition 2016-12, Vol.55 (50), p.15619-15623
Hauptverfasser:	Paunović, Vladimir, Zichittella, Guido, Verel, Réne, Amrute, Amol P., Pérez-Ramírez, Javier
Format:	Artikel
Sprache:	eng
Schlagworte:	C1 chemistry Carbon monoxide heterogeneous catalysis Methane methane oxychlorination natural-gas upgrading
Online-Zugang:	Volltext
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