A general approach to iridoids by applying a new Julia olefination and a tandem anion-radical-carbocation crossover reaction
A unified, asymmetric approach to the total synthesis of naturally occurring iridoids is presented. The synthesis features a recently discovered ortho → α transmetalation of alkyl aryl sulfone carbanions, thus enabling Julia reactions, by which so far hardly accessible disilylated olefins have been...
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| Veröffentlicht in: | Organic & biomolecular chemistry 2016-10, Vol.14 (40), p.9612-9621 |
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| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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