Visible light-induced formation of corrole-manganese(V)-oxo complexes: Observation of multiple oxidation pathways

Two manganese(V)-oxo corroles [MnV(Cor)O] that differ in their electronic environments were produced by visible light irradiation of highly photo-labile corrole-manganese(IV) bromates. The corrole ligands under study include 5,10,15-tris(pentafluorophenyl)corrole (TPFC), and 5,10,15-triphenylcorrole...

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Veröffentlicht in:	Journal of inorganic biochemistry 2016-10, Vol.163, p.39-44
Hauptverfasser:	Ka, Wai Kwong, Ngo, Fung Lee, Ranburger, Davis, Malone, Jonathan, Zhang, Rui
Format:	Artikel
Sprache:	eng
Schlagworte:	Corroles Kinetics Manganese - chemistry Manganese(V)-oxo Oxidation Oxidation-Reduction Porphyrins - chemistry Visible light
Online-Zugang:	Volltext
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