Photoinduced Regio- and Stereoselective Introduction of Phenylchalcogeno Moieties to Ethynylferrocene

Upon photoirradiation, diphenyl diselenide and diphenyl ditelluride reacted with ethynylferrocene to afford the corresponding bischalcogenated vinylferrocenes. Regio- and stereoselectivities were determined by X-ray crystal analysis, and redox properties were investigated by cyclic voltammetry.

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Veröffentlicht in:Bulletin of the Chemical Society of Japan 2014-04, Vol.87 (4), p.550-552
Hauptverfasser: Nomoto, Akihiro, Hayashi, Satoko, Fujiyama, Takuya, Ikeda, Takuma, Hirata, Kiichi, Tohoma, Jun, Kakiuchi, Kiyomi, Nakanishi, Waro, Ogawa, Akiya
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container_end_page 552
container_issue 4
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container_title Bulletin of the Chemical Society of Japan
container_volume 87
creator Nomoto, Akihiro
Hayashi, Satoko
Fujiyama, Takuya
Ikeda, Takuma
Hirata, Kiichi
Tohoma, Jun
Kakiuchi, Kiyomi
Nakanishi, Waro
Ogawa, Akiya
description Upon photoirradiation, diphenyl diselenide and diphenyl ditelluride reacted with ethynylferrocene to afford the corresponding bischalcogenated vinylferrocenes. Regio- and stereoselectivities were determined by X-ray crystal analysis, and redox properties were investigated by cyclic voltammetry.
doi_str_mv 10.1246/bcsj.20130160
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source Oxford University Press Journals All Titles (1996-Current)
subjects Crystals
Selenides
Stereoselectivity
Voltammetry
X-rays
title Photoinduced Regio- and Stereoselective Introduction of Phenylchalcogeno Moieties to Ethynylferrocene
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