Photoinduced Regio- and Stereoselective Introduction of Phenylchalcogeno Moieties to Ethynylferrocene

Photoinduced Regio- and Stereoselective Introduction of Phenylchalcogeno Moieties to Ethynylferrocene

Upon photoirradiation, diphenyl diselenide and diphenyl ditelluride reacted with ethynylferrocene to afford the corresponding bischalcogenated vinylferrocenes. Regio- and stereoselectivities were determined by X-ray crystal analysis, and redox properties were investigated by cyclic voltammetry.

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Veröffentlicht in:Bulletin of the Chemical Society of Japan 2014-04, Vol.87 (4), p.550-552
Hauptverfasser: Nomoto, Akihiro, Hayashi, Satoko, Fujiyama, Takuya, Ikeda, Takuma, Hirata, Kiichi, Tohoma, Jun, Kakiuchi, Kiyomi, Nakanishi, Waro, Ogawa, Akiya
Format: Artikel
Sprache:eng
Schlagworte:
Crystals
Selenides
Stereoselectivity
Voltammetry
X-rays
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Beschreibung
Zusammenfassung:Upon photoirradiation, diphenyl diselenide and diphenyl ditelluride reacted with ethynylferrocene to afford the corresponding bischalcogenated vinylferrocenes. Regio- and stereoselectivities were determined by X-ray crystal analysis, and redox properties were investigated by cyclic voltammetry.
ISSN:0009-2673
1348-0634
DOI:10.1246/bcsj.20130160