Experimental and Computational Studies on the Formation of Thorium-Copper Heterobimetallics

The formation of actinide–transition metal heterobimetallics mediated by a terminal actinide imido complex was comprehensively studied. The reaction of the thorium imido complex [(η5‐C5Me5)2Th=N(mesityl)(DMAP)] (3), prepared from [(η5‐C5Me5)2ThMe2] (1) and mesitylNH2 or [(η5‐C5Me5)2Th(NHmesityl)2] (...

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