Amine-Activated Iron Catalysis: Air- and Moisture-Stable Alkene and Alkyne Hydrofunctionalization

A simple alkylamine [(iPr)2NEt] has been used to activate an air‐ and moisture‐stable iron(II) pre‐catalyst for alkene and alkyne hydrofunctionalization reactions. This amine activation has enabled the highly operationally simple hydrosilylation and hydroboration of alkenes and alkynes using just 0....

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Veröffentlicht in:	Advanced synthesis & catalysis 2016-07, Vol.358 (15), p.2404-2409
Hauptverfasser:	Challinor, Amy J., Calin, Marc, Nichol, Gary S., Carter, Neil B., Thomas, Stephen P.
Format:	Artikel
Sprache:	eng
Schlagworte:	Activation Alkylamines Alkynes Amines Catalysis hydrosilylation Inert Iron Olefins sustainable chemistry
Online-Zugang:	Volltext
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