Amine-Activated Iron Catalysis: Air- and Moisture-Stable Alkene and Alkyne Hydrofunctionalization

Amine-Activated Iron Catalysis: Air- and Moisture-Stable Alkene and Alkyne Hydrofunctionalization

A simple alkylamine [(iPr)2NEt] has been used to activate an air‐ and moisture‐stable iron(II) pre‐catalyst for alkene and alkyne hydrofunctionalization reactions. This amine activation has enabled the highly operationally simple hydrosilylation and hydroboration of alkenes and alkynes using just 0....

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Veröffentlicht in:Advanced synthesis & catalysis 2016-07, Vol.358 (15), p.2404-2409
Hauptverfasser: Challinor, Amy J., Calin, Marc, Nichol, Gary S., Carter, Neil B., Thomas, Stephen P.
Format: Artikel
Sprache:eng
Schlagworte:
Activation
Alkylamines
Alkynes
Amines
Catalysis
hydrosilylation
Inert
Iron
Olefins
sustainable chemistry
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container_end_page 2409
container_issue 15
container_start_page 2404
container_title Advanced synthesis & catalysis
container_volume 358
creator Challinor, Amy J.
Calin, Marc
Nichol, Gary S.
Carter, Neil B.
Thomas, Stephen P.
description A simple alkylamine [(iPr)2NEt] has been used to activate an air‐ and moisture‐stable iron(II) pre‐catalyst for alkene and alkyne hydrofunctionalization reactions. This amine activation has enabled the highly operationally simple hydrosilylation and hydroboration of alkenes and alkynes using just 0.25–2 mol% iron catalyst and 1–25 mol% amine. Significantly, these reactions proceed in equal yield under both air and inert reaction conditions.
doi_str_mv 10.1002/adsc.201600570
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source Wiley Online Library Journals Frontfile Complete
subjects Activation
Alkylamines
Alkynes
Amines
Catalysis
hydrosilylation
Inert
Iron
Olefins
sustainable chemistry
title Amine-Activated Iron Catalysis: Air- and Moisture-Stable Alkene and Alkyne Hydrofunctionalization
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