The Effect of Polymer-Substrate Interaction on the Nucleation Property： Comparing Study of Graphene and Hexagonal Boron Nitride Nanosheets
Hexagonal boron nitride nanosheets （BNNSs） can work as a more efficient nucleating agent for two polyesters compared to graphene. Studies on the crystallization and dewetting processes of two polyesters, poly（butylene succinate） and poly（butylene adipate）, on the two substrate surfaces prove that th...
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| Veröffentlicht in: | Chinese journal of polymer science 2016-08, Vol.34 (8), p.1021-1031 |
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| container_title | Chinese journal of polymer science |
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| creator | Tang, Yi-ren Li, Ting Ye, Hai-mu Xu, Jun Guo, Bao-hua |
| description | Hexagonal boron nitride nanosheets （BNNSs） can work as a more efficient nucleating agent for two polyesters compared to graphene. Studies on the crystallization and dewetting processes of two polyesters, poly（butylene succinate） and poly（butylene adipate）, on the two substrate surfaces prove that the interaction between BNNSs and the polyesters is stronger than that between graphene and the polyesters. This strong interaction induces the pre-ordered conformation of molten PBA which has been identified by the in situ FTIR spectra. Thus BNNSs possess higher nucleation property than graphene. Finally, a new polymer-substrate interaction induced nucleation mechanism was proposed to explain the nucleation efficiency difference between graphene and BNNSs. |
| doi_str_mv | 10.1007/s10118-016-1816-2 |
| format | Article |
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Studies on the crystallization and dewetting processes of two polyesters, poly（butylene succinate） and poly（butylene adipate）, on the two substrate surfaces prove that the interaction between BNNSs and the polyesters is stronger than that between graphene and the polyesters. This strong interaction induces the pre-ordered conformation of molten PBA which has been identified by the in situ FTIR spectra. Thus BNNSs possess higher nucleation property than graphene. Finally, a new polymer-substrate interaction induced nucleation mechanism was proposed to explain the nucleation efficiency difference between graphene and BNNSs.</description><identifier>ISSN: 0256-7679</identifier><identifier>EISSN: 1439-6203</identifier><identifier>DOI: 10.1007/s10118-016-1816-2</identifier><language>eng</language><publisher>Beijing: Chinese Chemical Society and Institute of Chemistry, CAS</publisher><subject>Boron nitride ; Characterization and Evaluation of Materials ; Chemistry ; Chemistry and Materials Science ; Condensed Matter Physics ; Crystallization ; Dewetting ; Graphene ; Industrial Chemistry/Chemical Engineering ; Nanostructure ; Nucleation ; Polyester resins ; Polymer Sciences ; Spectra ; 六方氮化硼 ; 强相互作用 ; 核性质 ; 石墨 ; 纳米 ; 聚丁二酸丁二醇酯 ; 聚合物基体 ; 聚合物基质</subject><ispartof>Chinese journal of polymer science, 2016-08, Vol.34 (8), p.1021-1031</ispartof><rights>Chinese Chemical Society, Institute of Chemistry, Chinese Academy of Sciences and Springer-Verlag Berlin Heidelberg 2016</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c391t-ca2824605b7a8d59d760c3ceec21f1d838985f7511a7912cc8d6b0ae498e0fd33</citedby><cites>FETCH-LOGICAL-c391t-ca2824605b7a8d59d760c3ceec21f1d838985f7511a7912cc8d6b0ae498e0fd33</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Uhttp://image.cqvip.com/vip1000/qk/86788X/86788X.jpg</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10118-016-1816-2$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10118-016-1816-2$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27923,27924,41487,42556,51318</link.rule.ids></links><search><creatorcontrib>Tang, Yi-ren</creatorcontrib><creatorcontrib>Li, Ting</creatorcontrib><creatorcontrib>Ye, Hai-mu</creatorcontrib><creatorcontrib>Xu, Jun</creatorcontrib><creatorcontrib>Guo, Bao-hua</creatorcontrib><title>The Effect of Polymer-Substrate Interaction on the Nucleation Property： Comparing Study of Graphene and Hexagonal Boron Nitride Nanosheets</title><title>Chinese journal of polymer science</title><addtitle>Chin J Polym Sci</addtitle><addtitle>Chinese Journal of Polymer Science</addtitle><description>Hexagonal boron nitride nanosheets （BNNSs） can work as a more efficient nucleating agent for two polyesters compared to graphene. Studies on the crystallization and dewetting processes of two polyesters, poly（butylene succinate） and poly（butylene adipate）, on the two substrate surfaces prove that the interaction between BNNSs and the polyesters is stronger than that between graphene and the polyesters. This strong interaction induces the pre-ordered conformation of molten PBA which has been identified by the in situ FTIR spectra. Thus BNNSs possess higher nucleation property than graphene. Finally, a new polymer-substrate interaction induced nucleation mechanism was proposed to explain the nucleation efficiency difference between graphene and BNNSs.</description><subject>Boron nitride</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Condensed Matter Physics</subject><subject>Crystallization</subject><subject>Dewetting</subject><subject>Graphene</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Nanostructure</subject><subject>Nucleation</subject><subject>Polyester resins</subject><subject>Polymer Sciences</subject><subject>Spectra</subject><subject>六方氮化硼</subject><subject>强相互作用</subject><subject>核性质</subject><subject>石墨</subject><subject>纳米</subject><subject>聚丁二酸丁二醇酯</subject><subject>聚合物基体</subject><subject>聚合物基质</subject><issn>0256-7679</issn><issn>1439-6203</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNp9kN9qFDEUh4MouFYfwLvglTejOclM_lzqUttCqYXW65DNnNmdMptMkwy47-AT-Cy-k69g1i1eCiGB8Pt-h_MR8hbYB2BMfczAAHTDQDag68WfkRW0wjSSM_GcrBjvZKOkMi_Jq5wfGJOt6tSK_LjfIT0fBvSFxoHexumwx9TcLZtckitIr0LB5HwZY6D1lBq_WfyE7u_PbYozpnL4_esnXcf97NIYtvSuLP3hWHeR3LzDgNSFnl7id7eNwU30c0yVvRlLGvta50LMO8SSX5MXg5syvnl6z8i3L-f368vm-uvF1frTdeOFgdJ4xzVvJes2yum-M72SzAuP6DkM0Guhje4G1QE4ZYB7r3u5YQ5bo5ENvRBn5P2pd07xccFc7H7MHqfJBYxLtqBFJ1vNQdUonKI-xZwTDnZO496lgwVmj-btybyt5u3RvOWV4Scmz0cdmOxDXFJdPP8Xevc0aBfD9rFy_yZJaYQxEqT4A8HKlP0</recordid><startdate>20160801</startdate><enddate>20160801</enddate><creator>Tang, Yi-ren</creator><creator>Li, Ting</creator><creator>Ye, Hai-mu</creator><creator>Xu, Jun</creator><creator>Guo, Bao-hua</creator><general>Chinese Chemical Society and Institute of Chemistry, CAS</general><scope>2RA</scope><scope>92L</scope><scope>CQIGP</scope><scope>~WA</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20160801</creationdate><title>The Effect of Polymer-Substrate Interaction on the Nucleation Property： Comparing Study of Graphene and Hexagonal Boron Nitride Nanosheets</title><author>Tang, Yi-ren ; Li, Ting ; Ye, Hai-mu ; Xu, Jun ; Guo, Bao-hua</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c391t-ca2824605b7a8d59d760c3ceec21f1d838985f7511a7912cc8d6b0ae498e0fd33</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Boron nitride</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Condensed Matter Physics</topic><topic>Crystallization</topic><topic>Dewetting</topic><topic>Graphene</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Nanostructure</topic><topic>Nucleation</topic><topic>Polyester resins</topic><topic>Polymer Sciences</topic><topic>Spectra</topic><topic>六方氮化硼</topic><topic>强相互作用</topic><topic>核性质</topic><topic>石墨</topic><topic>纳米</topic><topic>聚丁二酸丁二醇酯</topic><topic>聚合物基体</topic><topic>聚合物基质</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Tang, Yi-ren</creatorcontrib><creatorcontrib>Li, Ting</creatorcontrib><creatorcontrib>Ye, Hai-mu</creatorcontrib><creatorcontrib>Xu, Jun</creatorcontrib><creatorcontrib>Guo, Bao-hua</creatorcontrib><collection>中文科技期刊数据库</collection><collection>中文科技期刊数据库-CALIS站点</collection><collection>中文科技期刊数据库-7.0平台</collection><collection>中文科技期刊数据库- 镜像站点</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Chinese journal of polymer science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Tang, Yi-ren</au><au>Li, Ting</au><au>Ye, Hai-mu</au><au>Xu, Jun</au><au>Guo, Bao-hua</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>The Effect of Polymer-Substrate Interaction on the Nucleation Property： Comparing Study of Graphene and Hexagonal Boron Nitride Nanosheets</atitle><jtitle>Chinese journal of polymer science</jtitle><stitle>Chin J Polym Sci</stitle><addtitle>Chinese Journal of Polymer Science</addtitle><date>2016-08-01</date><risdate>2016</risdate><volume>34</volume><issue>8</issue><spage>1021</spage><epage>1031</epage><pages>1021-1031</pages><issn>0256-7679</issn><eissn>1439-6203</eissn><abstract>Hexagonal boron nitride nanosheets （BNNSs） can work as a more efficient nucleating agent for two polyesters compared to graphene. 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| subjects | Boron nitride Characterization and Evaluation of Materials Chemistry Chemistry and Materials Science Condensed Matter Physics Crystallization Dewetting Graphene Industrial Chemistry/Chemical Engineering Nanostructure Nucleation Polyester resins Polymer Sciences Spectra 六方氮化硼 强相互作用 核性质 石墨 纳米 聚丁二酸丁二醇酯 聚合物基体 聚合物基质 |
| title | The Effect of Polymer-Substrate Interaction on the Nucleation Property： Comparing Study of Graphene and Hexagonal Boron Nitride Nanosheets |
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