Hydrothermal synthesis and characterization of a series of luminescent Ag() coordination polymers with two new multidentate bis-(1,2,3-triazole) ligands: structural diversity, polymorphism and photoluminescent sensing
In this work, two new multidentate bis-(1,2,3-triazole) ligands 1-(4-(2 H -1,2,3-triazol-2-yl)butyl)-1 H -1,2,3-triazole (L 1 ) and 1,6-bis(2 H -1,2,3-triazol-2-yl)hexane (L 2 ) have been designed and synthesized. Under hydrothermal conditions, a series of luminescent Ag( i ) coordination polymers,...
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| creator | Huo, Jian Zhong Su, Xiu Mei Wu, Xiang Xia Liu, Yuan Yuan Ding, Bin |
| description | In this work, two new multidentate bis-(1,2,3-triazole) ligands 1-(4-(2
H
-1,2,3-triazol-2-yl)butyl)-1
H
-1,2,3-triazole (L
1
) and 1,6-bis(2
H
-1,2,3-triazol-2-yl)hexane (L
2
) have been designed and synthesized. Under hydrothermal conditions, a series of luminescent Ag(
i
) coordination polymers, namely, {[Ag(L
1
)
2
](PF
6
)}
n
(
1
), {[Ag
2
(L
1
)
2
(bbtr)](BF
4
)
2
}
n
(
2
), {[Ag
2
(L
1
)
2
(bbtr)](BF
4
)
2
}
n
(
3
), {[Ag
2
(L
1
)
2
(bbtr)](PF
6
)
2
}
n
(
4
) and [Ag
2
(L
2
)(NO
3
)
2
]
n
(
5
) (bbtr = 1,4-di(1,2,3-triazol-1-yl)butane) can be isolated. For
1
, bidentate L
1
ligands bridge neighboring Ag(
i
) ions, forming a 1D tubular framework. Further, when L
1
and bbtr are used to react with AgBF
4
, two scarcely reported mixed-ligand polymorphic cluster-based Ag
I
frameworks,
2
(1D) and
3
(2D), can be isolated under different reaction temperatures. Further, free BF
4
anions within the crystalline framework of
2
can be exchanged with PF
6
anions to generate the anion exchanged crystalline product {[Ag
2
(L
1
)
2
(bbtr)](PF
6
)
2
}
n
(
4
) in a single-crystal-to-single-crystal (SCSC) manner. For
5
, tetradentate L
2
ligands bridge neighboring Ag
I
centers, leading to a 3D coordination polymer. The solid state luminescence properties of
15
have been investigated, indicating strong fluorescent emissions. Additionally, luminescence measurements illustrate that complex
5
exhibits highly selective and sensitive luminescence sensing of Cr
2
O
7
2
ions in aqueous solutions with high quenching efficiency (
K
sv
= 1.53 10
4
L mol
1
) and low detection limit (0.23 M (S/N = 3)), which make it a promising candidate for sensing Cr
2
O
7
2
anion pollutants in the actual measurement process.
5
is the first coordination polymer based on a bis-(1,2,3-triazole) derivative as luminescent probes of Cr
2
O
7
2
ions in aqueous solutions.
In this work, a series of luminescent Ag(
i
) coordination polymers with two new bis-(1,2,3-triazole) ligands have been prepared and characterized. |
| doi_str_mv | 10.1039/c6ce01275b |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1835638704</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1835638704</sourcerecordid><originalsourceid>FETCH-LOGICAL-c286t-fa8ea3bb8612adfbf43cd11d4cb5081872c8f1562b1ad80135abb9a37d23a6053</originalsourceid><addsrcrecordid>eNpNkU9v1DAQxSNEJUrhwh3Jxy3aUDtOvC63sioUqVIv5RyN_2RjlNjB47BKvynfBrdB0NO8kX7z5kmvKN4x-pFRfnmhhbaUVbtGvShOWS1EKSnnL5_pV8VrxB-Uspoxelr8vllMDKm3cYSB4OKzRIcEvCG6hwg62egeILngSegIEMy7xUc9zKPzFrX1iVwdNudEhxCN8ys8hWEZbURydKkn6RiIt0cyzkNyJl9AskQ5LDdsW215maKDhzDYczK4Q36OnwimOOs0x5zLuF_ZyaVlu9qGOPUOx6eUUx9SeB4FrUfnD2-Kkw4GtG__zrPi-5fr-_1NeXv39dv-6rbUlRSp7EBa4EpJwSownepqrg1jptaqoZLJXaVlxxpRKQZGUsYbUOoS-M5UHARt-FmxWX2nGH7OFlM7uhxkGMDbMGPLJG8ElztaZ_TDiuoYEKPt2im6EeLSMto-9tfuxf76qb_PGX6_whH1P-5_v_wPYcyeVw</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1835638704</pqid></control><display><type>article</type><title>Hydrothermal synthesis and characterization of a series of luminescent Ag() coordination polymers with two new multidentate bis-(1,2,3-triazole) ligands: structural diversity, polymorphism and photoluminescent sensing</title><source>Royal Society Of Chemistry Journals 2008-</source><source>Alma/SFX Local Collection</source><creator>Huo, Jian Zhong ; Su, Xiu Mei ; Wu, Xiang Xia ; Liu, Yuan Yuan ; Ding, Bin</creator><creatorcontrib>Huo, Jian Zhong ; Su, Xiu Mei ; Wu, Xiang Xia ; Liu, Yuan Yuan ; Ding, Bin</creatorcontrib><description>In this work, two new multidentate bis-(1,2,3-triazole) ligands 1-(4-(2
H
-1,2,3-triazol-2-yl)butyl)-1
H
-1,2,3-triazole (L
1
) and 1,6-bis(2
H
-1,2,3-triazol-2-yl)hexane (L
2
) have been designed and synthesized. Under hydrothermal conditions, a series of luminescent Ag(
i
) coordination polymers, namely, {[Ag(L
1
)
2
](PF
6
)}
n
(
1
), {[Ag
2
(L
1
)
2
(bbtr)](BF
4
)
2
}
n
(
2
), {[Ag
2
(L
1
)
2
(bbtr)](BF
4
)
2
}
n
(
3
), {[Ag
2
(L
1
)
2
(bbtr)](PF
6
)
2
}
n
(
4
) and [Ag
2
(L
2
)(NO
3
)
2
]
n
(
5
) (bbtr = 1,4-di(1,2,3-triazol-1-yl)butane) can be isolated. For
1
, bidentate L
1
ligands bridge neighboring Ag(
i
) ions, forming a 1D tubular framework. Further, when L
1
and bbtr are used to react with AgBF
4
, two scarcely reported mixed-ligand polymorphic cluster-based Ag
I
frameworks,
2
(1D) and
3
(2D), can be isolated under different reaction temperatures. Further, free BF
4
anions within the crystalline framework of
2
can be exchanged with PF
6
anions to generate the anion exchanged crystalline product {[Ag
2
(L
1
)
2
(bbtr)](PF
6
)
2
}
n
(
4
) in a single-crystal-to-single-crystal (SCSC) manner. For
5
, tetradentate L
2
ligands bridge neighboring Ag
I
centers, leading to a 3D coordination polymer. The solid state luminescence properties of
15
have been investigated, indicating strong fluorescent emissions. Additionally, luminescence measurements illustrate that complex
5
exhibits highly selective and sensitive luminescence sensing of Cr
2
O
7
2
ions in aqueous solutions with high quenching efficiency (
K
sv
= 1.53 10
4
L mol
1
) and low detection limit (0.23 M (S/N = 3)), which make it a promising candidate for sensing Cr
2
O
7
2
anion pollutants in the actual measurement process.
5
is the first coordination polymer based on a bis-(1,2,3-triazole) derivative as luminescent probes of Cr
2
O
7
2
ions in aqueous solutions.
In this work, a series of luminescent Ag(
i
) coordination polymers with two new bis-(1,2,3-triazole) ligands have been prepared and characterized.</description><identifier>ISSN: 1466-8033</identifier><identifier>EISSN: 1466-8033</identifier><identifier>DOI: 10.1039/c6ce01275b</identifier><language>eng</language><subject>Anion exchanging ; Coordination polymers ; Crystal structure ; Detection ; Exchange ; Ligands ; Luminescence ; Photoluminescence</subject><ispartof>CrystEngComm, 2016-01, Vol.18 (35), p.664-6652</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c286t-fa8ea3bb8612adfbf43cd11d4cb5081872c8f1562b1ad80135abb9a37d23a6053</citedby><cites>FETCH-LOGICAL-c286t-fa8ea3bb8612adfbf43cd11d4cb5081872c8f1562b1ad80135abb9a37d23a6053</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids></links><search><creatorcontrib>Huo, Jian Zhong</creatorcontrib><creatorcontrib>Su, Xiu Mei</creatorcontrib><creatorcontrib>Wu, Xiang Xia</creatorcontrib><creatorcontrib>Liu, Yuan Yuan</creatorcontrib><creatorcontrib>Ding, Bin</creatorcontrib><title>Hydrothermal synthesis and characterization of a series of luminescent Ag() coordination polymers with two new multidentate bis-(1,2,3-triazole) ligands: structural diversity, polymorphism and photoluminescent sensing</title><title>CrystEngComm</title><description>In this work, two new multidentate bis-(1,2,3-triazole) ligands 1-(4-(2
H
-1,2,3-triazol-2-yl)butyl)-1
H
-1,2,3-triazole (L
1
) and 1,6-bis(2
H
-1,2,3-triazol-2-yl)hexane (L
2
) have been designed and synthesized. Under hydrothermal conditions, a series of luminescent Ag(
i
) coordination polymers, namely, {[Ag(L
1
)
2
](PF
6
)}
n
(
1
), {[Ag
2
(L
1
)
2
(bbtr)](BF
4
)
2
}
n
(
2
), {[Ag
2
(L
1
)
2
(bbtr)](BF
4
)
2
}
n
(
3
), {[Ag
2
(L
1
)
2
(bbtr)](PF
6
)
2
}
n
(
4
) and [Ag
2
(L
2
)(NO
3
)
2
]
n
(
5
) (bbtr = 1,4-di(1,2,3-triazol-1-yl)butane) can be isolated. For
1
, bidentate L
1
ligands bridge neighboring Ag(
i
) ions, forming a 1D tubular framework. Further, when L
1
and bbtr are used to react with AgBF
4
, two scarcely reported mixed-ligand polymorphic cluster-based Ag
I
frameworks,
2
(1D) and
3
(2D), can be isolated under different reaction temperatures. Further, free BF
4
anions within the crystalline framework of
2
can be exchanged with PF
6
anions to generate the anion exchanged crystalline product {[Ag
2
(L
1
)
2
(bbtr)](PF
6
)
2
}
n
(
4
) in a single-crystal-to-single-crystal (SCSC) manner. For
5
, tetradentate L
2
ligands bridge neighboring Ag
I
centers, leading to a 3D coordination polymer. The solid state luminescence properties of
15
have been investigated, indicating strong fluorescent emissions. Additionally, luminescence measurements illustrate that complex
5
exhibits highly selective and sensitive luminescence sensing of Cr
2
O
7
2
ions in aqueous solutions with high quenching efficiency (
K
sv
= 1.53 10
4
L mol
1
) and low detection limit (0.23 M (S/N = 3)), which make it a promising candidate for sensing Cr
2
O
7
2
anion pollutants in the actual measurement process.
5
is the first coordination polymer based on a bis-(1,2,3-triazole) derivative as luminescent probes of Cr
2
O
7
2
ions in aqueous solutions.
In this work, a series of luminescent Ag(
i
) coordination polymers with two new bis-(1,2,3-triazole) ligands have been prepared and characterized.</description><subject>Anion exchanging</subject><subject>Coordination polymers</subject><subject>Crystal structure</subject><subject>Detection</subject><subject>Exchange</subject><subject>Ligands</subject><subject>Luminescence</subject><subject>Photoluminescence</subject><issn>1466-8033</issn><issn>1466-8033</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNpNkU9v1DAQxSNEJUrhwh3Jxy3aUDtOvC63sioUqVIv5RyN_2RjlNjB47BKvynfBrdB0NO8kX7z5kmvKN4x-pFRfnmhhbaUVbtGvShOWS1EKSnnL5_pV8VrxB-Uspoxelr8vllMDKm3cYSB4OKzRIcEvCG6hwg62egeILngSegIEMy7xUc9zKPzFrX1iVwdNudEhxCN8ys8hWEZbURydKkn6RiIt0cyzkNyJl9AskQ5LDdsW215maKDhzDYczK4Q36OnwimOOs0x5zLuF_ZyaVlu9qGOPUOx6eUUx9SeB4FrUfnD2-Kkw4GtG__zrPi-5fr-_1NeXv39dv-6rbUlRSp7EBa4EpJwSownepqrg1jptaqoZLJXaVlxxpRKQZGUsYbUOoS-M5UHARt-FmxWX2nGH7OFlM7uhxkGMDbMGPLJG8ElztaZ_TDiuoYEKPt2im6EeLSMto-9tfuxf76qb_PGX6_whH1P-5_v_wPYcyeVw</recordid><startdate>20160101</startdate><enddate>20160101</enddate><creator>Huo, Jian Zhong</creator><creator>Su, Xiu Mei</creator><creator>Wu, Xiang Xia</creator><creator>Liu, Yuan Yuan</creator><creator>Ding, Bin</creator><scope>AAYXX</scope><scope>CITATION</scope><scope>7U5</scope><scope>8FD</scope><scope>L7M</scope></search><sort><creationdate>20160101</creationdate><title>Hydrothermal synthesis and characterization of a series of luminescent Ag() coordination polymers with two new multidentate bis-(1,2,3-triazole) ligands: structural diversity, polymorphism and photoluminescent sensing</title><author>Huo, Jian Zhong ; Su, Xiu Mei ; Wu, Xiang Xia ; Liu, Yuan Yuan ; Ding, Bin</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c286t-fa8ea3bb8612adfbf43cd11d4cb5081872c8f1562b1ad80135abb9a37d23a6053</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Anion exchanging</topic><topic>Coordination polymers</topic><topic>Crystal structure</topic><topic>Detection</topic><topic>Exchange</topic><topic>Ligands</topic><topic>Luminescence</topic><topic>Photoluminescence</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Huo, Jian Zhong</creatorcontrib><creatorcontrib>Su, Xiu Mei</creatorcontrib><creatorcontrib>Wu, Xiang Xia</creatorcontrib><creatorcontrib>Liu, Yuan Yuan</creatorcontrib><creatorcontrib>Ding, Bin</creatorcontrib><collection>CrossRef</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>CrystEngComm</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Huo, Jian Zhong</au><au>Su, Xiu Mei</au><au>Wu, Xiang Xia</au><au>Liu, Yuan Yuan</au><au>Ding, Bin</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Hydrothermal synthesis and characterization of a series of luminescent Ag() coordination polymers with two new multidentate bis-(1,2,3-triazole) ligands: structural diversity, polymorphism and photoluminescent sensing</atitle><jtitle>CrystEngComm</jtitle><date>2016-01-01</date><risdate>2016</risdate><volume>18</volume><issue>35</issue><spage>664</spage><epage>6652</epage><pages>664-6652</pages><issn>1466-8033</issn><eissn>1466-8033</eissn><abstract>In this work, two new multidentate bis-(1,2,3-triazole) ligands 1-(4-(2
H
-1,2,3-triazol-2-yl)butyl)-1
H
-1,2,3-triazole (L
1
) and 1,6-bis(2
H
-1,2,3-triazol-2-yl)hexane (L
2
) have been designed and synthesized. Under hydrothermal conditions, a series of luminescent Ag(
i
) coordination polymers, namely, {[Ag(L
1
)
2
](PF
6
)}
n
(
1
), {[Ag
2
(L
1
)
2
(bbtr)](BF
4
)
2
}
n
(
2
), {[Ag
2
(L
1
)
2
(bbtr)](BF
4
)
2
}
n
(
3
), {[Ag
2
(L
1
)
2
(bbtr)](PF
6
)
2
}
n
(
4
) and [Ag
2
(L
2
)(NO
3
)
2
]
n
(
5
) (bbtr = 1,4-di(1,2,3-triazol-1-yl)butane) can be isolated. For
1
, bidentate L
1
ligands bridge neighboring Ag(
i
) ions, forming a 1D tubular framework. Further, when L
1
and bbtr are used to react with AgBF
4
, two scarcely reported mixed-ligand polymorphic cluster-based Ag
I
frameworks,
2
(1D) and
3
(2D), can be isolated under different reaction temperatures. Further, free BF
4
anions within the crystalline framework of
2
can be exchanged with PF
6
anions to generate the anion exchanged crystalline product {[Ag
2
(L
1
)
2
(bbtr)](PF
6
)
2
}
n
(
4
) in a single-crystal-to-single-crystal (SCSC) manner. For
5
, tetradentate L
2
ligands bridge neighboring Ag
I
centers, leading to a 3D coordination polymer. The solid state luminescence properties of
15
have been investigated, indicating strong fluorescent emissions. Additionally, luminescence measurements illustrate that complex
5
exhibits highly selective and sensitive luminescence sensing of Cr
2
O
7
2
ions in aqueous solutions with high quenching efficiency (
K
sv
= 1.53 10
4
L mol
1
) and low detection limit (0.23 M (S/N = 3)), which make it a promising candidate for sensing Cr
2
O
7
2
anion pollutants in the actual measurement process.
5
is the first coordination polymer based on a bis-(1,2,3-triazole) derivative as luminescent probes of Cr
2
O
7
2
ions in aqueous solutions.
In this work, a series of luminescent Ag(
i
) coordination polymers with two new bis-(1,2,3-triazole) ligands have been prepared and characterized.</abstract><doi>10.1039/c6ce01275b</doi><tpages>13</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1466-8033 |
| ispartof | CrystEngComm, 2016-01, Vol.18 (35), p.664-6652 |
| issn | 1466-8033 1466-8033 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_1835638704 |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Anion exchanging Coordination polymers Crystal structure Detection Exchange Ligands Luminescence Photoluminescence |
| title | Hydrothermal synthesis and characterization of a series of luminescent Ag() coordination polymers with two new multidentate bis-(1,2,3-triazole) ligands: structural diversity, polymorphism and photoluminescent sensing |
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