The donor OH stretching-libration dynamics of hydrogen-bonded methanol dimers in cryogenic matrices

FTIR spectra of the methanol dimer trapped in neon matrices are presented. The fundamental, overtone and combination bands involving the donor OH libration and stretching motions were observed in order to extract relevant anharmonicity constants. We find a stretching-libration coupling constant of +...

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Veröffentlicht in:	Physical chemistry chemical physics : PCCP 2016-02, Vol.18 (5), p.3739-3745
Hauptverfasser:	Heger, M, Andersen, J, Suhm, M. A, Wugt Larsen, R
Format:	Artikel
Sprache:	eng
Schlagworte:	Anharmonicity Constants Coupling Dimers Hydrogen bonding Methyl alcohol Spectra Stretching
Online-Zugang:	Volltext
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