Tuning the magnetoelastic transition in (Mn,Fe)2(P,Si) by B, C, and N doping

The critical temperature and first-order character of the magnetoelastic transition in (Mn,Fe)2(P,Si) are tunable by doping the structure with B, C and N atoms. Neutron diffraction experiments reveal that B substitutes Si on the 1b site of the hexagonal P-62m structure, C occupies the interstitial 6...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Scripta materialia 2016-11, Vol.124, p.129-132
Hauptverfasser: Miao, X.F., Thang, N.V., Caron, L., Yibole, H., Smith, R.I., van Dijk, N.H., Brück, E.
Format: Artikel
Sprache:eng
Schlagworte:
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 132
container_issue
container_start_page 129
container_title Scripta materialia
container_volume 124
creator Miao, X.F.
Thang, N.V.
Caron, L.
Yibole, H.
Smith, R.I.
van Dijk, N.H.
Brück, E.
description The critical temperature and first-order character of the magnetoelastic transition in (Mn,Fe)2(P,Si) are tunable by doping the structure with B, C and N atoms. Neutron diffraction experiments reveal that B substitutes Si on the 1b site of the hexagonal P-62m structure, C occupies the interstitial 6j and 6k sites, while N distributes on both the 1b and interstitial 6j and 6k sites. The tuning mechanism has been discussed in terms of the subtle variations in electronic configuration around the Fe atoms, which can be used to tailor the magnetoelastic transition. [Display omitted]
doi_str_mv 10.1016/j.scriptamat.2016.07.015
format Article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1835618602</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><els_id>S1359646216303190</els_id><sourcerecordid>1835618602</sourcerecordid><originalsourceid>FETCH-LOGICAL-c332t-adb4bc2e268b88ebeef052a790c3ecff3f3ae0c72e2f2682d1def4376fb36dd73</originalsourceid><addsrcrecordid>eNqFkE1LAzEQhhdRsFb_Q44tdNd8dLPboy1WhfoB1nPIJpOass2uSSr035tSwaOnGYbnfWGeLEMEFwQTfrstgvK2j3InY0HTpcBVgUl5lg1IXdG8npb8PO2snOV8yulldhXCFmPMCSWDbLXeO-s2KH4C2smNg9hBK0O0CkUvXbDRdg5Zh0bPbrKEMR29Td7tGDUHNJ-gxQRJp9EL0l2fWq6zCyPbADe_c5h9LO_Xi8d89frwtLhb5YoxGnOpm2mjKFBeN3UNDYDBJZXVDCsGyhhmmASsqkSYxFBNNJgpq7hpGNe6YsNsdOrtffe1hxDFzgYFbSsddPsgSM1KTmqOaULrE6p8F4IHI3pvd9IfBMHiKFBsxZ9AcRQocCWSwBSdn6KQXvm24BNowSnQ1oOKQnf2_5IfHCJ9zw</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1835618602</pqid></control><display><type>article</type><title>Tuning the magnetoelastic transition in (Mn,Fe)2(P,Si) by B, C, and N doping</title><source>Access via ScienceDirect (Elsevier)</source><creator>Miao, X.F. ; Thang, N.V. ; Caron, L. ; Yibole, H. ; Smith, R.I. ; van Dijk, N.H. ; Brück, E.</creator><creatorcontrib>Miao, X.F. ; Thang, N.V. ; Caron, L. ; Yibole, H. ; Smith, R.I. ; van Dijk, N.H. ; Brück, E.</creatorcontrib><description>The critical temperature and first-order character of the magnetoelastic transition in (Mn,Fe)2(P,Si) are tunable by doping the structure with B, C and N atoms. Neutron diffraction experiments reveal that B substitutes Si on the 1b site of the hexagonal P-62m structure, C occupies the interstitial 6j and 6k sites, while N distributes on both the 1b and interstitial 6j and 6k sites. The tuning mechanism has been discussed in terms of the subtle variations in electronic configuration around the Fe atoms, which can be used to tailor the magnetoelastic transition. [Display omitted]</description><identifier>ISSN: 1359-6462</identifier><identifier>EISSN: 1872-8456</identifier><identifier>DOI: 10.1016/j.scriptamat.2016.07.015</identifier><language>eng</language><publisher>Elsevier Ltd</publisher><subject>Atomic structure ; Critical temperature ; Doping ; Electronics ; Interstitials ; Magnetocaloric effect ; Magnetoelastic transition ; Neutron diffraction ; Phase transformations ; Transition metals ; Tuning</subject><ispartof>Scripta materialia, 2016-11, Vol.124, p.129-132</ispartof><rights>2016 Elsevier B.V.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c332t-adb4bc2e268b88ebeef052a790c3ecff3f3ae0c72e2f2682d1def4376fb36dd73</citedby><cites>FETCH-LOGICAL-c332t-adb4bc2e268b88ebeef052a790c3ecff3f3ae0c72e2f2682d1def4376fb36dd73</cites><orcidid>0000-0003-4930-9108</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.scriptamat.2016.07.015$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>315,782,786,3552,27931,27932,46002</link.rule.ids></links><search><creatorcontrib>Miao, X.F.</creatorcontrib><creatorcontrib>Thang, N.V.</creatorcontrib><creatorcontrib>Caron, L.</creatorcontrib><creatorcontrib>Yibole, H.</creatorcontrib><creatorcontrib>Smith, R.I.</creatorcontrib><creatorcontrib>van Dijk, N.H.</creatorcontrib><creatorcontrib>Brück, E.</creatorcontrib><title>Tuning the magnetoelastic transition in (Mn,Fe)2(P,Si) by B, C, and N doping</title><title>Scripta materialia</title><description>The critical temperature and first-order character of the magnetoelastic transition in (Mn,Fe)2(P,Si) are tunable by doping the structure with B, C and N atoms. Neutron diffraction experiments reveal that B substitutes Si on the 1b site of the hexagonal P-62m structure, C occupies the interstitial 6j and 6k sites, while N distributes on both the 1b and interstitial 6j and 6k sites. The tuning mechanism has been discussed in terms of the subtle variations in electronic configuration around the Fe atoms, which can be used to tailor the magnetoelastic transition. [Display omitted]</description><subject>Atomic structure</subject><subject>Critical temperature</subject><subject>Doping</subject><subject>Electronics</subject><subject>Interstitials</subject><subject>Magnetocaloric effect</subject><subject>Magnetoelastic transition</subject><subject>Neutron diffraction</subject><subject>Phase transformations</subject><subject>Transition metals</subject><subject>Tuning</subject><issn>1359-6462</issn><issn>1872-8456</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNqFkE1LAzEQhhdRsFb_Q44tdNd8dLPboy1WhfoB1nPIJpOass2uSSr035tSwaOnGYbnfWGeLEMEFwQTfrstgvK2j3InY0HTpcBVgUl5lg1IXdG8npb8PO2snOV8yulldhXCFmPMCSWDbLXeO-s2KH4C2smNg9hBK0O0CkUvXbDRdg5Zh0bPbrKEMR29Td7tGDUHNJ-gxQRJp9EL0l2fWq6zCyPbADe_c5h9LO_Xi8d89frwtLhb5YoxGnOpm2mjKFBeN3UNDYDBJZXVDCsGyhhmmASsqkSYxFBNNJgpq7hpGNe6YsNsdOrtffe1hxDFzgYFbSsddPsgSM1KTmqOaULrE6p8F4IHI3pvd9IfBMHiKFBsxZ9AcRQocCWSwBSdn6KQXvm24BNowSnQ1oOKQnf2_5IfHCJ9zw</recordid><startdate>201611</startdate><enddate>201611</enddate><creator>Miao, X.F.</creator><creator>Thang, N.V.</creator><creator>Caron, L.</creator><creator>Yibole, H.</creator><creator>Smith, R.I.</creator><creator>van Dijk, N.H.</creator><creator>Brück, E.</creator><general>Elsevier Ltd</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><orcidid>https://orcid.org/0000-0003-4930-9108</orcidid></search><sort><creationdate>201611</creationdate><title>Tuning the magnetoelastic transition in (Mn,Fe)2(P,Si) by B, C, and N doping</title><author>Miao, X.F. ; Thang, N.V. ; Caron, L. ; Yibole, H. ; Smith, R.I. ; van Dijk, N.H. ; Brück, E.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c332t-adb4bc2e268b88ebeef052a790c3ecff3f3ae0c72e2f2682d1def4376fb36dd73</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Atomic structure</topic><topic>Critical temperature</topic><topic>Doping</topic><topic>Electronics</topic><topic>Interstitials</topic><topic>Magnetocaloric effect</topic><topic>Magnetoelastic transition</topic><topic>Neutron diffraction</topic><topic>Phase transformations</topic><topic>Transition metals</topic><topic>Tuning</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Miao, X.F.</creatorcontrib><creatorcontrib>Thang, N.V.</creatorcontrib><creatorcontrib>Caron, L.</creatorcontrib><creatorcontrib>Yibole, H.</creatorcontrib><creatorcontrib>Smith, R.I.</creatorcontrib><creatorcontrib>van Dijk, N.H.</creatorcontrib><creatorcontrib>Brück, E.</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Scripta materialia</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Miao, X.F.</au><au>Thang, N.V.</au><au>Caron, L.</au><au>Yibole, H.</au><au>Smith, R.I.</au><au>van Dijk, N.H.</au><au>Brück, E.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Tuning the magnetoelastic transition in (Mn,Fe)2(P,Si) by B, C, and N doping</atitle><jtitle>Scripta materialia</jtitle><date>2016-11</date><risdate>2016</risdate><volume>124</volume><spage>129</spage><epage>132</epage><pages>129-132</pages><issn>1359-6462</issn><eissn>1872-8456</eissn><abstract>The critical temperature and first-order character of the magnetoelastic transition in (Mn,Fe)2(P,Si) are tunable by doping the structure with B, C and N atoms. Neutron diffraction experiments reveal that B substitutes Si on the 1b site of the hexagonal P-62m structure, C occupies the interstitial 6j and 6k sites, while N distributes on both the 1b and interstitial 6j and 6k sites. The tuning mechanism has been discussed in terms of the subtle variations in electronic configuration around the Fe atoms, which can be used to tailor the magnetoelastic transition. [Display omitted]</abstract><pub>Elsevier Ltd</pub><doi>10.1016/j.scriptamat.2016.07.015</doi><tpages>4</tpages><orcidid>https://orcid.org/0000-0003-4930-9108</orcidid></addata></record>
fulltext fulltext
identifier ISSN: 1359-6462
ispartof Scripta materialia, 2016-11, Vol.124, p.129-132
issn 1359-6462
1872-8456
language eng
recordid cdi_proquest_miscellaneous_1835618602
source Access via ScienceDirect (Elsevier)
subjects Atomic structure
Critical temperature
Doping
Electronics
Interstitials
Magnetocaloric effect
Magnetoelastic transition
Neutron diffraction
Phase transformations
Transition metals
Tuning
title Tuning the magnetoelastic transition in (Mn,Fe)2(P,Si) by B, C, and N doping
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-05T18%3A43%3A23IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Tuning%20the%20magnetoelastic%20transition%20in%20(Mn,Fe)2(P,Si)%20by%20B,%20C,%20and%20N%20doping&rft.jtitle=Scripta%20materialia&rft.au=Miao,%20X.F.&rft.date=2016-11&rft.volume=124&rft.spage=129&rft.epage=132&rft.pages=129-132&rft.issn=1359-6462&rft.eissn=1872-8456&rft_id=info:doi/10.1016/j.scriptamat.2016.07.015&rft_dat=%3Cproquest_cross%3E1835618602%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1835618602&rft_id=info:pmid/&rft_els_id=S1359646216303190&rfr_iscdi=true