Tuning the magnetoelastic transition in (Mn,Fe)2(P,Si) by B, C, and N doping

The critical temperature and first-order character of the magnetoelastic transition in (Mn,Fe)2(P,Si) are tunable by doping the structure with B, C and N atoms. Neutron diffraction experiments reveal that B substitutes Si on the 1b site of the hexagonal P-62m structure, C occupies the interstitial 6...

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Veröffentlicht in:Scripta materialia 2016-11, Vol.124, p.129-132
Hauptverfasser: Miao, X.F., Thang, N.V., Caron, L., Yibole, H., Smith, R.I., van Dijk, N.H., Brück, E.
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container_end_page 132
container_issue
container_start_page 129
container_title Scripta materialia
container_volume 124
creator Miao, X.F.
Thang, N.V.
Caron, L.
Yibole, H.
Smith, R.I.
van Dijk, N.H.
Brück, E.
description The critical temperature and first-order character of the magnetoelastic transition in (Mn,Fe)2(P,Si) are tunable by doping the structure with B, C and N atoms. Neutron diffraction experiments reveal that B substitutes Si on the 1b site of the hexagonal P-62m structure, C occupies the interstitial 6j and 6k sites, while N distributes on both the 1b and interstitial 6j and 6k sites. The tuning mechanism has been discussed in terms of the subtle variations in electronic configuration around the Fe atoms, which can be used to tailor the magnetoelastic transition. [Display omitted]
doi_str_mv 10.1016/j.scriptamat.2016.07.015
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subjects Atomic structure
Critical temperature
Doping
Electronics
Interstitials
Magnetocaloric effect
Magnetoelastic transition
Neutron diffraction
Phase transformations
Transition metals
Tuning
title Tuning the magnetoelastic transition in (Mn,Fe)2(P,Si) by B, C, and N doping
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