Tuning the magnetoelastic transition in (Mn,Fe)2(P,Si) by B, C, and N doping
The critical temperature and first-order character of the magnetoelastic transition in (Mn,Fe)2(P,Si) are tunable by doping the structure with B, C and N atoms. Neutron diffraction experiments reveal that B substitutes Si on the 1b site of the hexagonal P-62m structure, C occupies the interstitial 6...
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Veröffentlicht in: | Scripta materialia 2016-11, Vol.124, p.129-132 |
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creator | Miao, X.F. Thang, N.V. Caron, L. Yibole, H. Smith, R.I. van Dijk, N.H. Brück, E. |
description | The critical temperature and first-order character of the magnetoelastic transition in (Mn,Fe)2(P,Si) are tunable by doping the structure with B, C and N atoms. Neutron diffraction experiments reveal that B substitutes Si on the 1b site of the hexagonal P-62m structure, C occupies the interstitial 6j and 6k sites, while N distributes on both the 1b and interstitial 6j and 6k sites. The tuning mechanism has been discussed in terms of the subtle variations in electronic configuration around the Fe atoms, which can be used to tailor the magnetoelastic transition.
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doi_str_mv | 10.1016/j.scriptamat.2016.07.015 |
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[Display omitted]</description><subject>Atomic structure</subject><subject>Critical temperature</subject><subject>Doping</subject><subject>Electronics</subject><subject>Interstitials</subject><subject>Magnetocaloric effect</subject><subject>Magnetoelastic transition</subject><subject>Neutron diffraction</subject><subject>Phase transformations</subject><subject>Transition metals</subject><subject>Tuning</subject><issn>1359-6462</issn><issn>1872-8456</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNqFkE1LAzEQhhdRsFb_Q44tdNd8dLPboy1WhfoB1nPIJpOass2uSSr035tSwaOnGYbnfWGeLEMEFwQTfrstgvK2j3InY0HTpcBVgUl5lg1IXdG8npb8PO2snOV8yulldhXCFmPMCSWDbLXeO-s2KH4C2smNg9hBK0O0CkUvXbDRdg5Zh0bPbrKEMR29Td7tGDUHNJ-gxQRJp9EL0l2fWq6zCyPbADe_c5h9LO_Xi8d89frwtLhb5YoxGnOpm2mjKFBeN3UNDYDBJZXVDCsGyhhmmASsqkSYxFBNNJgpq7hpGNe6YsNsdOrtffe1hxDFzgYFbSsddPsgSM1KTmqOaULrE6p8F4IHI3pvd9IfBMHiKFBsxZ9AcRQocCWSwBSdn6KQXvm24BNowSnQ1oOKQnf2_5IfHCJ9zw</recordid><startdate>201611</startdate><enddate>201611</enddate><creator>Miao, X.F.</creator><creator>Thang, N.V.</creator><creator>Caron, L.</creator><creator>Yibole, H.</creator><creator>Smith, R.I.</creator><creator>van Dijk, N.H.</creator><creator>Brück, E.</creator><general>Elsevier Ltd</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><orcidid>https://orcid.org/0000-0003-4930-9108</orcidid></search><sort><creationdate>201611</creationdate><title>Tuning the magnetoelastic transition in (Mn,Fe)2(P,Si) by B, C, and N doping</title><author>Miao, X.F. ; Thang, N.V. ; Caron, L. ; Yibole, H. ; Smith, R.I. ; van Dijk, N.H. ; Brück, E.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c332t-adb4bc2e268b88ebeef052a790c3ecff3f3ae0c72e2f2682d1def4376fb36dd73</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Atomic structure</topic><topic>Critical temperature</topic><topic>Doping</topic><topic>Electronics</topic><topic>Interstitials</topic><topic>Magnetocaloric effect</topic><topic>Magnetoelastic transition</topic><topic>Neutron diffraction</topic><topic>Phase transformations</topic><topic>Transition metals</topic><topic>Tuning</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Miao, X.F.</creatorcontrib><creatorcontrib>Thang, N.V.</creatorcontrib><creatorcontrib>Caron, L.</creatorcontrib><creatorcontrib>Yibole, H.</creatorcontrib><creatorcontrib>Smith, R.I.</creatorcontrib><creatorcontrib>van Dijk, N.H.</creatorcontrib><creatorcontrib>Brück, E.</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Scripta materialia</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Miao, X.F.</au><au>Thang, N.V.</au><au>Caron, L.</au><au>Yibole, H.</au><au>Smith, R.I.</au><au>van Dijk, N.H.</au><au>Brück, E.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Tuning the magnetoelastic transition in (Mn,Fe)2(P,Si) by B, C, and N doping</atitle><jtitle>Scripta materialia</jtitle><date>2016-11</date><risdate>2016</risdate><volume>124</volume><spage>129</spage><epage>132</epage><pages>129-132</pages><issn>1359-6462</issn><eissn>1872-8456</eissn><abstract>The critical temperature and first-order character of the magnetoelastic transition in (Mn,Fe)2(P,Si) are tunable by doping the structure with B, C and N atoms. Neutron diffraction experiments reveal that B substitutes Si on the 1b site of the hexagonal P-62m structure, C occupies the interstitial 6j and 6k sites, while N distributes on both the 1b and interstitial 6j and 6k sites. The tuning mechanism has been discussed in terms of the subtle variations in electronic configuration around the Fe atoms, which can be used to tailor the magnetoelastic transition.
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subjects | Atomic structure Critical temperature Doping Electronics Interstitials Magnetocaloric effect Magnetoelastic transition Neutron diffraction Phase transformations Transition metals Tuning |
title | Tuning the magnetoelastic transition in (Mn,Fe)2(P,Si) by B, C, and N doping |
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