Deformylation Reaction by a Nonheme Manganese(III)-Peroxo Complex via Initial Hydrogen-Atom Abstraction

Metal–peroxo intermediates are key species in the catalytic cycles of nonheme metalloenzymes, but their chemical properties and reactivity patterns are still poorly understood. The synthesis and characterization of a manganese(III)–peroxo complex with a pentadentate bispidine ligand system and its r...

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Veröffentlicht in:	Angewandte Chemie 2016-09, Vol.128 (37), p.11257-11261
Hauptverfasser:	Barman, Prasenjit, Upadhyay, Pranav, Faponle, Abayomi S., Kumar, Jitendra, Nag, Sayanta Sekhar, Kumar, Devesh, Sastri, Chivukula V., de Visser, Sam P.
Format:	Artikel
Sprache:	eng
Schlagworte:	Biomimetische Modelle Catalysis Chemistry Deformation effects Deformation mechanisms Dichtefunktionaltheorie Enzymmodelle Isotope effect Ligands Mathematical models Origins Reaktionsmechanismen Synthesis Wasserstoffatomabsplatung
Online-Zugang:	Volltext
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