N-Oxides rescue Ru(v) in catalytic Griffith-Ley (TPAP) alcohol oxidations

The redox and ligand exchange reactions of oxido-ruthenium complexes are central to the function of the Sharpless and Griffith-Ley one-step alcohol oxidation protocols. However, their mechanisms have not been elucidated. Cyclic voltammetry and UV-vis spectroelectrochemical analysis of [RuO4](-) has...

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Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2016-01, Vol.52 (67), p.10301-10304
Hauptverfasser:	Zerk, Timothy J, Moore, Peter W, Williams, Craig M, Bernhardt, Paul V
Format:	Artikel
Sprache:	eng
Schlagworte:	Alcohols Catalysis Exchange Ligands Oxidation Ruthenium Valence Voltammetry
Online-Zugang:	Volltext
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