Donor–acceptor optoelectronic molecules based on hexa-peri-hexabenzocoronene and benzothiadiazole units: effect of different combinations
Three donor–acceptor (D–A) conjugated molecules using hexa-peri-hexabenzocoronene (HBC) as D unit while benzo[2,1,3]thiadiazole (BT) as A unit have been synthesized. They have different D–A combination fashions, including D–A, A–D–A and D–A–D. Their thermal, optical, electrochemical properties and m...
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| Veröffentlicht in: | Tetrahedron 2016-07, Vol.72 (29), p.4329-4336 |
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| creator | Liang, Long Chen, Xue-Qiang Liu, Li-Na Ling, Jun Xiang, Xuan Xiao, Wen-Jing Ge, Cong-Wu Zhao, Fu-Gang Xie, Guanghui Lu, Zhengquan Li, Jingjing Li, Wei-Shi |
| description | Three donor–acceptor (D–A) conjugated molecules using hexa-peri-hexabenzocoronene (HBC) as D unit while benzo[2,1,3]thiadiazole (BT) as A unit have been synthesized. They have different D–A combination fashions, including D–A, A–D–A and D–A–D. Their thermal, optical, electrochemical properties and molecular interactions have been thoroughly studied, with particular attention paid on the effect of different D–A combinations. Property comparison reveals that the ADA molecule using HBC as core and two BT units as arms possesses a better light absorption property and a more ordered film structure than the other two. Finally, such ADA molecule displayed the best field-effect transistor and photovoltaic performances.
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| doi_str_mv | 10.1016/j.tet.2016.05.072 |
| format | Article |
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[Display omitted]</description><identifier>ISSN: 0040-4020</identifier><identifier>EISSN: 1464-5416</identifier><identifier>DOI: 10.1016/j.tet.2016.05.072</identifier><language>eng</language><publisher>Elsevier Ltd</publisher><subject>Benzothiadiazole ; Field effect transistors ; Hexa-peri-hexabenzocoronene ; Light absorption ; Molecular interactions ; Molecular structure ; Optical properties ; Optoelectronic molecules ; Optoelectronics ; Photovoltaics ; Solar cells ; Tetrahedrons</subject><ispartof>Tetrahedron, 2016-07, Vol.72 (29), p.4329-4336</ispartof><rights>2016 Elsevier Ltd</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c330t-d1c82e9da84960803eb6b87c5d7961bdde8f9b5d458356633a59a5ee29d06db83</citedby><cites>FETCH-LOGICAL-c330t-d1c82e9da84960803eb6b87c5d7961bdde8f9b5d458356633a59a5ee29d06db83</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0040402016304896$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3537,27903,27904,65309</link.rule.ids></links><search><creatorcontrib>Liang, Long</creatorcontrib><creatorcontrib>Chen, Xue-Qiang</creatorcontrib><creatorcontrib>Liu, Li-Na</creatorcontrib><creatorcontrib>Ling, Jun</creatorcontrib><creatorcontrib>Xiang, Xuan</creatorcontrib><creatorcontrib>Xiao, Wen-Jing</creatorcontrib><creatorcontrib>Ge, Cong-Wu</creatorcontrib><creatorcontrib>Zhao, Fu-Gang</creatorcontrib><creatorcontrib>Xie, Guanghui</creatorcontrib><creatorcontrib>Lu, Zhengquan</creatorcontrib><creatorcontrib>Li, Jingjing</creatorcontrib><creatorcontrib>Li, Wei-Shi</creatorcontrib><title>Donor–acceptor optoelectronic molecules based on hexa-peri-hexabenzocoronene and benzothiadiazole units: effect of different combinations</title><title>Tetrahedron</title><description>Three donor–acceptor (D–A) conjugated molecules using hexa-peri-hexabenzocoronene (HBC) as D unit while benzo[2,1,3]thiadiazole (BT) as A unit have been synthesized. They have different D–A combination fashions, including D–A, A–D–A and D–A–D. Their thermal, optical, electrochemical properties and molecular interactions have been thoroughly studied, with particular attention paid on the effect of different D–A combinations. Property comparison reveals that the ADA molecule using HBC as core and two BT units as arms possesses a better light absorption property and a more ordered film structure than the other two. Finally, such ADA molecule displayed the best field-effect transistor and photovoltaic performances.
[Display omitted]</description><subject>Benzothiadiazole</subject><subject>Field effect transistors</subject><subject>Hexa-peri-hexabenzocoronene</subject><subject>Light absorption</subject><subject>Molecular interactions</subject><subject>Molecular structure</subject><subject>Optical properties</subject><subject>Optoelectronic molecules</subject><subject>Optoelectronics</subject><subject>Photovoltaics</subject><subject>Solar cells</subject><subject>Tetrahedrons</subject><issn>0040-4020</issn><issn>1464-5416</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNp9kM9OGzEQhy1UpIbAA_TmYy-7He-unV16qvhTkCL1AmfLa88KRxs7tR0EOfECPfECeZY8Ck-CQzj3Yv9mNN9I8xHyjUHJgIkfizJhKqscS-AlzKojMmGNaAreMPGFTAAaKBqo4Cs5iXEBAIxV9YT8u_TOh7eXV6U1rpIP1OcXR9QpeGc1Xfqc1yNG2quIhnpHH_BJFSsMttinHt3Ga5-n0SFVztCPTnqwyli1yThdO5viOcVhyGt3Wz_stsbmIqBLVPtlb51K1rt4So4HNUY8-_yn5P766u7ippj_-X178Wte6LqGVBim2wo7o9qmE9BCjb3o25nmZtYJ1huD7dD13DS8rbkQda14pzhi1RkQpm_rKfl-2LsK_u8aY5JLGzWOo3Lo11GyPQdQZXRK2GFUBx9jwEGugl2q8CwZyL16uZBZvdyrl8BlVp-ZnwcG8w2PFoOM2qLTaGzIBqTx9j_0O56Zk0Q</recordid><startdate>20160721</startdate><enddate>20160721</enddate><creator>Liang, Long</creator><creator>Chen, Xue-Qiang</creator><creator>Liu, Li-Na</creator><creator>Ling, Jun</creator><creator>Xiang, Xuan</creator><creator>Xiao, Wen-Jing</creator><creator>Ge, Cong-Wu</creator><creator>Zhao, Fu-Gang</creator><creator>Xie, Guanghui</creator><creator>Lu, Zhengquan</creator><creator>Li, Jingjing</creator><creator>Li, Wei-Shi</creator><general>Elsevier Ltd</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20160721</creationdate><title>Donor–acceptor optoelectronic molecules based on hexa-peri-hexabenzocoronene and benzothiadiazole units: effect of different combinations</title><author>Liang, Long ; Chen, Xue-Qiang ; Liu, Li-Na ; Ling, Jun ; Xiang, Xuan ; Xiao, Wen-Jing ; Ge, Cong-Wu ; Zhao, Fu-Gang ; Xie, Guanghui ; Lu, Zhengquan ; Li, Jingjing ; Li, Wei-Shi</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c330t-d1c82e9da84960803eb6b87c5d7961bdde8f9b5d458356633a59a5ee29d06db83</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Benzothiadiazole</topic><topic>Field effect transistors</topic><topic>Hexa-peri-hexabenzocoronene</topic><topic>Light absorption</topic><topic>Molecular interactions</topic><topic>Molecular structure</topic><topic>Optical properties</topic><topic>Optoelectronic molecules</topic><topic>Optoelectronics</topic><topic>Photovoltaics</topic><topic>Solar cells</topic><topic>Tetrahedrons</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Liang, Long</creatorcontrib><creatorcontrib>Chen, Xue-Qiang</creatorcontrib><creatorcontrib>Liu, Li-Na</creatorcontrib><creatorcontrib>Ling, Jun</creatorcontrib><creatorcontrib>Xiang, Xuan</creatorcontrib><creatorcontrib>Xiao, Wen-Jing</creatorcontrib><creatorcontrib>Ge, Cong-Wu</creatorcontrib><creatorcontrib>Zhao, Fu-Gang</creatorcontrib><creatorcontrib>Xie, Guanghui</creatorcontrib><creatorcontrib>Lu, Zhengquan</creatorcontrib><creatorcontrib>Li, Jingjing</creatorcontrib><creatorcontrib>Li, Wei-Shi</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Tetrahedron</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Liang, Long</au><au>Chen, Xue-Qiang</au><au>Liu, Li-Na</au><au>Ling, Jun</au><au>Xiang, Xuan</au><au>Xiao, Wen-Jing</au><au>Ge, Cong-Wu</au><au>Zhao, Fu-Gang</au><au>Xie, Guanghui</au><au>Lu, Zhengquan</au><au>Li, Jingjing</au><au>Li, Wei-Shi</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Donor–acceptor optoelectronic molecules based on hexa-peri-hexabenzocoronene and benzothiadiazole units: effect of different combinations</atitle><jtitle>Tetrahedron</jtitle><date>2016-07-21</date><risdate>2016</risdate><volume>72</volume><issue>29</issue><spage>4329</spage><epage>4336</epage><pages>4329-4336</pages><issn>0040-4020</issn><eissn>1464-5416</eissn><abstract>Three donor–acceptor (D–A) conjugated molecules using hexa-peri-hexabenzocoronene (HBC) as D unit while benzo[2,1,3]thiadiazole (BT) as A unit have been synthesized. They have different D–A combination fashions, including D–A, A–D–A and D–A–D. Their thermal, optical, electrochemical properties and molecular interactions have been thoroughly studied, with particular attention paid on the effect of different D–A combinations. Property comparison reveals that the ADA molecule using HBC as core and two BT units as arms possesses a better light absorption property and a more ordered film structure than the other two. Finally, such ADA molecule displayed the best field-effect transistor and photovoltaic performances.
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| subjects | Benzothiadiazole Field effect transistors Hexa-peri-hexabenzocoronene Light absorption Molecular interactions Molecular structure Optical properties Optoelectronic molecules Optoelectronics Photovoltaics Solar cells Tetrahedrons |
| title | Donor–acceptor optoelectronic molecules based on hexa-peri-hexabenzocoronene and benzothiadiazole units: effect of different combinations |
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