A light/pH/multiple ion-driven smart switchable module for computing sequential logic operations via a resettable dual-optical readout
A switchable module comprising pendant pyridine groups, an amide linkage and a photoswitchable functionality (azobenzene) has been designed and characterized via a full battery of physico-chemical techniques. The module has been exploited for ternary/binary data storage with non-destructive optical...
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Veröffentlicht in: | Journal of materials chemistry. C, Materials for optical and electronic devices Materials for optical and electronic devices, 2015-01, Vol.3 (46), p.12123-12129 |
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container_issue | 46 |
container_start_page | 12123 |
container_title | Journal of materials chemistry. C, Materials for optical and electronic devices |
container_volume | 3 |
creator | Singh, Alok Kumar Yadav, Promod Kumar Kumari, Niraj Nagarajan, Rajamani Mishra, Lallan |
description | A switchable module comprising pendant pyridine groups, an amide linkage and a photoswitchable functionality (azobenzene) has been designed and characterized
via
a full battery of physico-chemical techniques. The module has been exploited for ternary/binary data storage with non-destructive optical identity owing to its high photo-stability, excellent reversibility, and chemical-/photo-switchability. Moreover the module exhibits sequential logic gate-based detection of multiple ions (Cu
2+
, CN
−
, F
−
and I
−
) at ppm levels
via
a “turn on” signature which potentially meets real-world challenges in terms of the simple synthesis route, rapid response, water based activity, naked-eye visualization, regenerative action, high selectivity and multiple readout for precise analysis. |
doi_str_mv | 10.1039/C5TC02698A |
format | Article |
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via
a full battery of physico-chemical techniques. The module has been exploited for ternary/binary data storage with non-destructive optical identity owing to its high photo-stability, excellent reversibility, and chemical-/photo-switchability. Moreover the module exhibits sequential logic gate-based detection of multiple ions (Cu
2+
, CN
−
, F
−
and I
−
) at ppm levels
via
a “turn on” signature which potentially meets real-world challenges in terms of the simple synthesis route, rapid response, water based activity, naked-eye visualization, regenerative action, high selectivity and multiple readout for precise analysis.</description><identifier>ISSN: 2050-7526</identifier><identifier>EISSN: 2050-7534</identifier><identifier>DOI: 10.1039/C5TC02698A</identifier><language>eng</language><subject>Amides ; Linkages ; Logic ; Modules ; Pyridines ; Signatures ; Visualization ; Water based</subject><ispartof>Journal of materials chemistry. C, Materials for optical and electronic devices, 2015-01, Vol.3 (46), p.12123-12129</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c330t-b6d90cbc9cf0046960e209ae3ae4e6f3414ca414c4f2456d0a197e216625490c3</citedby><cites>FETCH-LOGICAL-c330t-b6d90cbc9cf0046960e209ae3ae4e6f3414ca414c4f2456d0a197e216625490c3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,777,781,27905,27906</link.rule.ids></links><search><creatorcontrib>Singh, Alok Kumar</creatorcontrib><creatorcontrib>Yadav, Promod Kumar</creatorcontrib><creatorcontrib>Kumari, Niraj</creatorcontrib><creatorcontrib>Nagarajan, Rajamani</creatorcontrib><creatorcontrib>Mishra, Lallan</creatorcontrib><title>A light/pH/multiple ion-driven smart switchable module for computing sequential logic operations via a resettable dual-optical readout</title><title>Journal of materials chemistry. C, Materials for optical and electronic devices</title><description>A switchable module comprising pendant pyridine groups, an amide linkage and a photoswitchable functionality (azobenzene) has been designed and characterized
via
a full battery of physico-chemical techniques. The module has been exploited for ternary/binary data storage with non-destructive optical identity owing to its high photo-stability, excellent reversibility, and chemical-/photo-switchability. Moreover the module exhibits sequential logic gate-based detection of multiple ions (Cu
2+
, CN
−
, F
−
and I
−
) at ppm levels
via
a “turn on” signature which potentially meets real-world challenges in terms of the simple synthesis route, rapid response, water based activity, naked-eye visualization, regenerative action, high selectivity and multiple readout for precise analysis.</description><subject>Amides</subject><subject>Linkages</subject><subject>Logic</subject><subject>Modules</subject><subject>Pyridines</subject><subject>Signatures</subject><subject>Visualization</subject><subject>Water based</subject><issn>2050-7526</issn><issn>2050-7534</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><recordid>eNpFkMFKAzEQhoMoWGovPkGOIqxNNtl0cyyLWqHgpZ6XNDvbRrKbNclWfAGf27QVncP8A_PNz_AjdEvJAyVMzqtiU5FcyHJ5gSY5KUi2KBi__JtzcY1mIbyTVCUVpZAT9L3E1uz2cT6s5t1ooxksYOP6rPHmAD0OnfIRh08T9V5t065zzZikdR5r1w1jNP0OB_gYoY9GWWzdzmjsBvAqJp-AD0ZhhT0EiPHk0IzKZm6IRifcg2rcGG_QVatsgNmvTtHb0-OmWmXr1-eXarnONGMkZlvRSKK3WuqWEC6kIJATqYAp4CBaxinX6th4m_NCNERRuYCcCpEXPF2yKbo7-w7epZdDrDsTNFirenBjqGnJiqJkpSgTen9GtXcheGjrwZuUxldNSX3Mu_7Pm_0AQ_t0uQ</recordid><startdate>20150101</startdate><enddate>20150101</enddate><creator>Singh, Alok Kumar</creator><creator>Yadav, Promod Kumar</creator><creator>Kumari, Niraj</creator><creator>Nagarajan, Rajamani</creator><creator>Mishra, Lallan</creator><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20150101</creationdate><title>A light/pH/multiple ion-driven smart switchable module for computing sequential logic operations via a resettable dual-optical readout</title><author>Singh, Alok Kumar ; Yadav, Promod Kumar ; Kumari, Niraj ; Nagarajan, Rajamani ; Mishra, Lallan</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c330t-b6d90cbc9cf0046960e209ae3ae4e6f3414ca414c4f2456d0a197e216625490c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><topic>Amides</topic><topic>Linkages</topic><topic>Logic</topic><topic>Modules</topic><topic>Pyridines</topic><topic>Signatures</topic><topic>Visualization</topic><topic>Water based</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Singh, Alok Kumar</creatorcontrib><creatorcontrib>Yadav, Promod Kumar</creatorcontrib><creatorcontrib>Kumari, Niraj</creatorcontrib><creatorcontrib>Nagarajan, Rajamani</creatorcontrib><creatorcontrib>Mishra, Lallan</creatorcontrib><collection>CrossRef</collection><collection>Electronics & Communications Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Journal of materials chemistry. C, Materials for optical and electronic devices</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Singh, Alok Kumar</au><au>Yadav, Promod Kumar</au><au>Kumari, Niraj</au><au>Nagarajan, Rajamani</au><au>Mishra, Lallan</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A light/pH/multiple ion-driven smart switchable module for computing sequential logic operations via a resettable dual-optical readout</atitle><jtitle>Journal of materials chemistry. C, Materials for optical and electronic devices</jtitle><date>2015-01-01</date><risdate>2015</risdate><volume>3</volume><issue>46</issue><spage>12123</spage><epage>12129</epage><pages>12123-12129</pages><issn>2050-7526</issn><eissn>2050-7534</eissn><abstract>A switchable module comprising pendant pyridine groups, an amide linkage and a photoswitchable functionality (azobenzene) has been designed and characterized
via
a full battery of physico-chemical techniques. The module has been exploited for ternary/binary data storage with non-destructive optical identity owing to its high photo-stability, excellent reversibility, and chemical-/photo-switchability. Moreover the module exhibits sequential logic gate-based detection of multiple ions (Cu
2+
, CN
−
, F
−
and I
−
) at ppm levels
via
a “turn on” signature which potentially meets real-world challenges in terms of the simple synthesis route, rapid response, water based activity, naked-eye visualization, regenerative action, high selectivity and multiple readout for precise analysis.</abstract><doi>10.1039/C5TC02698A</doi><tpages>7</tpages></addata></record> |
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ispartof | Journal of materials chemistry. C, Materials for optical and electronic devices, 2015-01, Vol.3 (46), p.12123-12129 |
issn | 2050-7526 2050-7534 |
language | eng |
recordid | cdi_proquest_miscellaneous_1835583868 |
source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
subjects | Amides Linkages Logic Modules Pyridines Signatures Visualization Water based |
title | A light/pH/multiple ion-driven smart switchable module for computing sequential logic operations via a resettable dual-optical readout |
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