A Mixed-Valent Uranium Phosphonate Framework Containing U super(IV), U super(V), and U super(VI)
It is shown that U super(V)O sub(2) super( +) ions can reside at U super(VI)O sub(2) super(2+) lattice sites during mild reduction and crystallization process under solvothermal conditions, yielding a complicated and rare mixed-valent uranium phosphonate compound that simultaneously contains U super...
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| Veröffentlicht in: | Chemistry : a European journal 2016-08, Vol.22 (34), p.11954-11957 |
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| container_issue | 34 |
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| container_title | Chemistry : a European journal |
| container_volume | 22 |
| creator | Chen, Lanhua Zheng, Tao Bao, Songsong Zhang, Linjuan Liu, Hsin-Kuan Zheng, Limin Wang, Jianqiang Wang, Yaxing Diwu, Juan Chai, Zhifang Albrecht-Schmitt, Thomas E Wang, Shuao |
| description | It is shown that U super(V)O sub(2) super( +) ions can reside at U super(VI)O sub(2) super(2+) lattice sites during mild reduction and crystallization process under solvothermal conditions, yielding a complicated and rare mixed-valent uranium phosphonate compound that simultaneously contains U super(IV), U super(V), and U super(VI). The presence of uranium with three oxidation states was confirmed by various characterization techniques, including X-ray crystallography, X-ray photoelectron, electron paramagnetic resonance, FTIR, UV/Vis-NIR absorption, and synchrotron radiation X-ray absorption spectroscopy, and magnetism measurements. Three's company: A complex uranium compound was synthesized by a redox-active solvothermal reaction. It is the first phosphonate compound that contains three oxidation states of uranium simultaneously. |
| doi_str_mv | 10.1002/chem.201602863 |
| format | Article |
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The presence of uranium with three oxidation states was confirmed by various characterization techniques, including X-ray crystallography, X-ray photoelectron, electron paramagnetic resonance, FTIR, UV/Vis-NIR absorption, and synchrotron radiation X-ray absorption spectroscopy, and magnetism measurements. Three's company: A complex uranium compound was synthesized by a redox-active solvothermal reaction. 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The presence of uranium with three oxidation states was confirmed by various characterization techniques, including X-ray crystallography, X-ray photoelectron, electron paramagnetic resonance, FTIR, UV/Vis-NIR absorption, and synchrotron radiation X-ray absorption spectroscopy, and magnetism measurements. Three's company: A complex uranium compound was synthesized by a redox-active solvothermal reaction. 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The presence of uranium with three oxidation states was confirmed by various characterization techniques, including X-ray crystallography, X-ray photoelectron, electron paramagnetic resonance, FTIR, UV/Vis-NIR absorption, and synchrotron radiation X-ray absorption spectroscopy, and magnetism measurements. Three's company: A complex uranium compound was synthesized by a redox-active solvothermal reaction. It is the first phosphonate compound that contains three oxidation states of uranium simultaneously.</abstract><doi>10.1002/chem.201602863</doi></addata></record> |
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| ispartof | Chemistry : a European journal, 2016-08, Vol.22 (34), p.11954-11957 |
| issn | 0947-6539 1521-3765 |
| language | eng |
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Absorption Fourier transforms Infrared spectroscopy Phosphonates Uranium Uranium compounds Valence X-rays |
| title | A Mixed-Valent Uranium Phosphonate Framework Containing U super(IV), U super(V), and U super(VI) |
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