Adsorption and adhesion studies of PdSn-nanoparticles on protonated amine and carboxylic acid-terminated surfaces

Electroless plating of acrylonitrile‐butadiene‐styrene‐terpolymers (ABS‐plastics) is used for decorative applications and relies on the immobilization of catalytic palladium‐tin nanoparticles. We used chemical force microscopy to measure the adhesion force of palladium‐tin nanoparticles on a pattern...

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Veröffentlicht in:Surface and interface analysis 2016-09, Vol.48 (9), p.1017-1025
Hauptverfasser: Mosebach, Bastian, Bayer, Frank Markus, Fels, Carl-Christian, Voigt, Markus, Oezkaya, Berkem, Pomorska, Agata, Torun, Boray, Keller, Adrian, Grundmeier, Guido
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container_end_page 1025
container_issue 9
container_start_page 1017
container_title Surface and interface analysis
container_volume 48
creator Mosebach, Bastian
Bayer, Frank Markus
Fels, Carl-Christian
Voigt, Markus
Oezkaya, Berkem
Pomorska, Agata
Torun, Boray
Keller, Adrian
Grundmeier, Guido
description Electroless plating of acrylonitrile‐butadiene‐styrene‐terpolymers (ABS‐plastics) is used for decorative applications and relies on the immobilization of catalytic palladium‐tin nanoparticles. We used chemical force microscopy to measure the adhesion force of palladium‐tin nanoparticles on a patterned amine and carboxyl‐terminated surface prepared by micro‐contact printing. The kinetics of the adsorption process and the population density of the nanoparticles on amine and carboxyl‐terminated surfaces were monitored by quartz crystal microbalance with dissipation analysis. The surface chemistry was investigated by means of polarization‐modulated infrared reflection absorption spectroscopy and X‐ray photoelectron spectroscopy. Enhanced adhesion and population density of PdSn nanoparticles on protonated amine‐terminated surfaces compared with carboxyl‐terminated surfaces is observed. Copyright © 2016 John Wiley & Sons, Ltd.
doi_str_mv 10.1002/sia.6016
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source Wiley Online Library Journals Frontfile Complete
subjects Adhesion
Adsorption
Amines
chemical force microscopy
Microbalances
Nanoparticles
Palladium
palladium-tin nanoparticle
Population density
QCM
Surface chemistry
title Adsorption and adhesion studies of PdSn-nanoparticles on protonated amine and carboxylic acid-terminated surfaces
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