Novel ionic liquid supported on Fe3O4 nanoparticles and its application as a catalyst in Mannich reaction under ultrasonic irradiation
[Display omitted] •This work has been successful in achieving the comparison trend under different conditions.•We used IL-Fe3O4 as catalyst for diastereoselective Mannich reaction.•The products were synthesised in short times and high yields under ultrasonic irradiation. A family of novel ionic liqu...
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Veröffentlicht in: | Ultrasonics sonochemistry 2017-01, Vol.34, p.916-923 |
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Format: | Artikel |
Sprache: | eng |
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•This work has been successful in achieving the comparison trend under different conditions.•We used IL-Fe3O4 as catalyst for diastereoselective Mannich reaction.•The products were synthesised in short times and high yields under ultrasonic irradiation.
A family of novel ionic liquid with l-alanine and choline chloride as environmentally benign materials have been synthesized and grafted on Fe3O4 nanoparticles using easy preparation techniques. The structure of ionic liquid supported on Fe3O4 nanoparticles (IL-Fe3O4 NPs) characterized by various analyses such as FE-SEM, EDX, XRD, NMR, FTIR and VSM. The catalytic activities of this catalyst are examined in the Mannich reaction for synthesis of β-aminocarbonyl compounds under ultrasonic irradiation. The recyclability of catalyst is investigated, and the results have indicated that the catalyst can be recycled six times without obvious activity decreasing. |
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ISSN: | 1350-4177 1873-2828 |
DOI: | 10.1016/j.ultsonch.2016.08.003 |