Structure and Magnetic Behavior of Layered Honeycomb Tellurates, BiM(III)TeO6 (M = Cr, Mn, Fe)

New layered honeycomb tellurates, BiM­(III)­TeO6 (M = Cr, Mn, Fe) were synthesized and characterized. BiM­(III)­TeO6 (M = Cr, Fe) species crystallize in a trigonal space group, P3̅1c (No. 163), of edge-sharing M3+/Te6+O6 octahedra, which form honeycomb-like double layers in the ab plane with Bi3+ ca...

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Veröffentlicht in:Inorganic chemistry 2016-10, Vol.55 (20), p.10229-10237
Hauptverfasser: Kim, Sun Woo, Deng, Zheng, Fischer, Zachary, Lapidus, Saul H., Stephens, Peter W., Li, Man-Rong, Greenblatt, Martha
Format: Artikel
Sprache:eng
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