Synergy between Experimental and Computational Chemistry Reveals the Mechanism of Decomposition of Nickel–Ketene Complexes
A series of (dppf)Ni(ketene) complexes were synthesized and fully characterized. In the solid state, the complexes possess η2-(C,O) coordination of the ketene in an overall planar configuration. They display similar structure in solution, except in some cases, the η2-(C,C) coordination mode is als...
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| Veröffentlicht in: | Journal of the American Chemical Society 2016-10, Vol.138 (42), p.14083-14091 |
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| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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