Synthesis of Aluminosilicates Containing a Ba(Sr)–O–Al–O–Si Arrangement of Natural Feldspar Mineral

Synthesis of Aluminosilicates Containing a Ba(Sr)–O–Al–O–Si Arrangement of Natural Feldspar Mineral

We report a facile route to multicomponent complexes of [M­{(μ-ddbfo)2Al­(OSiR3)2}2] (M = Ba, Sr; ddbfoH = 2,3-dihydro-2,2-dimethylbenzofuran-7-ol; R = Ph, OtBu) as new efficient single-source routes to barium and strontium celsian feldspar Ba­(Sr)­Al2Si2O8. The resulting complexes were characterize...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Inorganic chemistry 2016-10, Vol.55 (19), p.9524-9527
Hauptverfasser: Drąg-Jarząbek, Anna, Petrus, Rafał, Sobota, Piotr
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 9527
container_issue 19
container_start_page 9524
container_title Inorganic chemistry
container_volume 55
creator Drąg-Jarząbek, Anna
Petrus, Rafał
Sobota, Piotr
description We report a facile route to multicomponent complexes of [M­{(μ-ddbfo)2Al­(OSiR3)2}2] (M = Ba, Sr; ddbfoH = 2,3-dihydro-2,2-dimethylbenzofuran-7-ol; R = Ph, OtBu) as new efficient single-source routes to barium and strontium celsian feldspar Ba­(Sr)­Al2Si2O8. The resulting complexes were characterized by elemental analysis, IR and NMR spectroscopy, and single-crystal X-ray diffraction. These compounds calcined at 1100 °C to give porous material Ba­(Sr)­Al2Si2O8·2SiO2 as an amorphous silica matrix containing spherical oxide nanocrystals of celsian feldspar of ca. 5 nm diameter, as evidenced by transmission and scanning electron microscopies.
doi_str_mv 10.1021/acs.inorgchem.6b01900
format Article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1835389240</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1835389240</sourcerecordid><originalsourceid>FETCH-LOGICAL-a417t-2d21db9177494844a1c04fc45d32a293b3e5a56e49fe090eae1458462940b9773</originalsourceid><addsrcrecordid>eNqFkE1u20AMhQdBithxe4QEWroLO5w_ybN0jKQpkJ-FU6A7gZIoZ1xp5M5IC-96h96wJ-kYdrPtgiBBvPcIfoxdcZhzEPwGyzC3rvOb8o3aeVoANwBnbMy1gJnm8P2cjQHizNPUjNhlCFsAMFKlF2wkslRIDXLMfqz3rn-jYEPS1cmyGdoYGmxjS-wpJKvO9WiddZsEk1ucrv3nP79-v8RaNqdhbZOl9-g21JLrDynP2A8em-Semirs0CdP1lFcfGQfamwCfTr1Cft2f_e6epg9vnz5ulo-zlDxrJ-JSvCqMDzLlFELpZCXoOpS6UoKFEYWkjTqlJSpCQwQEld6oVJhFBQmy-SETY-5O9_9HCj0eWtDSU2Djroh5HwhtVwYoSBK9VFa-i4ET3W-87ZFv8855AfOeeScv3POT5yj7_p0Yihaqt5d_8BGAT8KDv5tN3gXP_5P6F9LKZDs</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1835389240</pqid></control><display><type>article</type><title>Synthesis of Aluminosilicates Containing a Ba(Sr)–O–Al–O–Si Arrangement of Natural Feldspar Mineral</title><source>ACS Publications</source><creator>Drąg-Jarząbek, Anna ; Petrus, Rafał ; Sobota, Piotr</creator><creatorcontrib>Drąg-Jarząbek, Anna ; Petrus, Rafał ; Sobota, Piotr</creatorcontrib><description>We report a facile route to multicomponent complexes of [M­{(μ-ddbfo)2Al­(OSiR3)2}2] (M = Ba, Sr; ddbfoH = 2,3-dihydro-2,2-dimethylbenzofuran-7-ol; R = Ph, OtBu) as new efficient single-source routes to barium and strontium celsian feldspar Ba­(Sr)­Al2Si2O8. The resulting complexes were characterized by elemental analysis, IR and NMR spectroscopy, and single-crystal X-ray diffraction. These compounds calcined at 1100 °C to give porous material Ba­(Sr)­Al2Si2O8·2SiO2 as an amorphous silica matrix containing spherical oxide nanocrystals of celsian feldspar of ca. 5 nm diameter, as evidenced by transmission and scanning electron microscopies.</description><identifier>ISSN: 0020-1669</identifier><identifier>EISSN: 1520-510X</identifier><identifier>DOI: 10.1021/acs.inorgchem.6b01900</identifier><identifier>PMID: 27623503</identifier><language>eng</language><publisher>United States: American Chemical Society</publisher><ispartof>Inorganic chemistry, 2016-10, Vol.55 (19), p.9524-9527</ispartof><rights>Copyright © 2016 American Chemical Society</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a417t-2d21db9177494844a1c04fc45d32a293b3e5a56e49fe090eae1458462940b9773</citedby><cites>FETCH-LOGICAL-a417t-2d21db9177494844a1c04fc45d32a293b3e5a56e49fe090eae1458462940b9773</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/acs.inorgchem.6b01900$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/acs.inorgchem.6b01900$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,776,780,2752,27053,27901,27902,56713,56763</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/27623503$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Drąg-Jarząbek, Anna</creatorcontrib><creatorcontrib>Petrus, Rafał</creatorcontrib><creatorcontrib>Sobota, Piotr</creatorcontrib><title>Synthesis of Aluminosilicates Containing a Ba(Sr)–O–Al–O–Si Arrangement of Natural Feldspar Mineral</title><title>Inorganic chemistry</title><addtitle>Inorg. Chem</addtitle><description>We report a facile route to multicomponent complexes of [M­{(μ-ddbfo)2Al­(OSiR3)2}2] (M = Ba, Sr; ddbfoH = 2,3-dihydro-2,2-dimethylbenzofuran-7-ol; R = Ph, OtBu) as new efficient single-source routes to barium and strontium celsian feldspar Ba­(Sr)­Al2Si2O8. The resulting complexes were characterized by elemental analysis, IR and NMR spectroscopy, and single-crystal X-ray diffraction. These compounds calcined at 1100 °C to give porous material Ba­(Sr)­Al2Si2O8·2SiO2 as an amorphous silica matrix containing spherical oxide nanocrystals of celsian feldspar of ca. 5 nm diameter, as evidenced by transmission and scanning electron microscopies.</description><issn>0020-1669</issn><issn>1520-510X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNqFkE1u20AMhQdBithxe4QEWroLO5w_ybN0jKQpkJ-FU6A7gZIoZ1xp5M5IC-96h96wJ-kYdrPtgiBBvPcIfoxdcZhzEPwGyzC3rvOb8o3aeVoANwBnbMy1gJnm8P2cjQHizNPUjNhlCFsAMFKlF2wkslRIDXLMfqz3rn-jYEPS1cmyGdoYGmxjS-wpJKvO9WiddZsEk1ucrv3nP79-v8RaNqdhbZOl9-g21JLrDynP2A8em-Semirs0CdP1lFcfGQfamwCfTr1Cft2f_e6epg9vnz5ulo-zlDxrJ-JSvCqMDzLlFELpZCXoOpS6UoKFEYWkjTqlJSpCQwQEld6oVJhFBQmy-SETY-5O9_9HCj0eWtDSU2Djroh5HwhtVwYoSBK9VFa-i4ET3W-87ZFv8855AfOeeScv3POT5yj7_p0Yihaqt5d_8BGAT8KDv5tN3gXP_5P6F9LKZDs</recordid><startdate>20161003</startdate><enddate>20161003</enddate><creator>Drąg-Jarząbek, Anna</creator><creator>Petrus, Rafał</creator><creator>Sobota, Piotr</creator><general>American Chemical Society</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>20161003</creationdate><title>Synthesis of Aluminosilicates Containing a Ba(Sr)–O–Al–O–Si Arrangement of Natural Feldspar Mineral</title><author>Drąg-Jarząbek, Anna ; Petrus, Rafał ; Sobota, Piotr</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a417t-2d21db9177494844a1c04fc45d32a293b3e5a56e49fe090eae1458462940b9773</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Drąg-Jarząbek, Anna</creatorcontrib><creatorcontrib>Petrus, Rafał</creatorcontrib><creatorcontrib>Sobota, Piotr</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Drąg-Jarząbek, Anna</au><au>Petrus, Rafał</au><au>Sobota, Piotr</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis of Aluminosilicates Containing a Ba(Sr)–O–Al–O–Si Arrangement of Natural Feldspar Mineral</atitle><jtitle>Inorganic chemistry</jtitle><addtitle>Inorg. Chem</addtitle><date>2016-10-03</date><risdate>2016</risdate><volume>55</volume><issue>19</issue><spage>9524</spage><epage>9527</epage><pages>9524-9527</pages><issn>0020-1669</issn><eissn>1520-510X</eissn><abstract>We report a facile route to multicomponent complexes of [M­{(μ-ddbfo)2Al­(OSiR3)2}2] (M = Ba, Sr; ddbfoH = 2,3-dihydro-2,2-dimethylbenzofuran-7-ol; R = Ph, OtBu) as new efficient single-source routes to barium and strontium celsian feldspar Ba­(Sr)­Al2Si2O8. The resulting complexes were characterized by elemental analysis, IR and NMR spectroscopy, and single-crystal X-ray diffraction. These compounds calcined at 1100 °C to give porous material Ba­(Sr)­Al2Si2O8·2SiO2 as an amorphous silica matrix containing spherical oxide nanocrystals of celsian feldspar of ca. 5 nm diameter, as evidenced by transmission and scanning electron microscopies.</abstract><cop>United States</cop><pub>American Chemical Society</pub><pmid>27623503</pmid><doi>10.1021/acs.inorgchem.6b01900</doi><tpages>4</tpages></addata></record>
fulltext fulltext
identifier ISSN: 0020-1669
ispartof Inorganic chemistry, 2016-10, Vol.55 (19), p.9524-9527
issn 0020-1669
1520-510X
language eng
recordid cdi_proquest_miscellaneous_1835389240
source ACS Publications
title Synthesis of Aluminosilicates Containing a Ba(Sr)–O–Al–O–Si Arrangement of Natural Feldspar Mineral
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-14T10%3A21%3A32IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Synthesis%20of%20Aluminosilicates%20Containing%20a%20Ba(Sr)%E2%80%93O%E2%80%93Al%E2%80%93O%E2%80%93Si%20Arrangement%20of%20Natural%20Feldspar%20Mineral&rft.jtitle=Inorganic%20chemistry&rft.au=Dra%CC%A8g-Jarza%CC%A8bek,%20Anna&rft.date=2016-10-03&rft.volume=55&rft.issue=19&rft.spage=9524&rft.epage=9527&rft.pages=9524-9527&rft.issn=0020-1669&rft.eissn=1520-510X&rft_id=info:doi/10.1021/acs.inorgchem.6b01900&rft_dat=%3Cproquest_cross%3E1835389240%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1835389240&rft_id=info:pmid/27623503&rfr_iscdi=true