Hierarchical Mesoporous Iron Fluoride with Superior Rate Performance for Lithium-Ion Batteries

Hierarchical Mesoporous Iron Fluoride with Superior Rate Performance for Lithium-Ion Batteries

Monodispersed mesoporous iron fluorides were synthesized by a low-cost reversed micelle method. The as-prepared materials with hierarchical mesoporous structure exhibit excellent rate capability (115.6 mAh g–1 at 2000 mA g–1) which is superior to many other carbon-free iron fluorides. In addition, a...

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Veröffentlicht in:ACS applied materials & interfaces 2016-12, Vol.8 (48), p.32869-32874
Hauptverfasser: Han, Yangmei, Li, Huiyu, Li, Jinfeng, Si, Huinan, Zhu, Wentao, Qiu, Xinping
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container_issue 48
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creator Han, Yangmei
Li, Huiyu
Li, Jinfeng
Si, Huinan
Zhu, Wentao
Qiu, Xinping
description Monodispersed mesoporous iron fluorides were synthesized by a low-cost reversed micelle method. The as-prepared materials with hierarchical mesoporous structure exhibit excellent rate capability (115.6 mAh g–1 at 2000 mA g–1) which is superior to many other carbon-free iron fluorides. In addition, a high reversible capacity of 143.2 mAh g–1 can be retained after 100 cycles at 1000 mA g–1. The outstanding electrochemical features can be attributed to the particular hierarchical mesoporous structure, facilitating electrolyte penetration as well as rapid electronic and ionic transportation.
doi_str_mv 10.1021/acsami.6b11889
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title Hierarchical Mesoporous Iron Fluoride with Superior Rate Performance for Lithium-Ion Batteries
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