An insecticidal mixture of tetramethylcyclohexenedione isomers from Kunzea ambigua and Kunzea baxterii

A mixture of isomers, all 4-[1-(5,7-dihydroxy-6-methyl-4-oxo-2-phenyl-chroman-8-yl)-3-methyl-butyl]-5-hydroxy-2,2,6,6-tetramethyl-cyclohex-4-en-1,3-diones, which comprises a pair of epimers, each of which is a pair of conformers, has been isolated from the hexane extract of the aerial parts of Kunze...

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Veröffentlicht in:Phytochemistry (Oxford) 2002-01, Vol.59 (1), p.69-71
Hauptverfasser: Khambay, Bhupinder P.S, Beddie, David G, Simmonds, Monique S.J
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creator Khambay, Bhupinder P.S
Beddie, David G
Simmonds, Monique S.J
description A mixture of isomers, all 4-[1-(5,7-dihydroxy-6-methyl-4-oxo-2-phenyl-chroman-8-yl)-3-methyl-butyl]-5-hydroxy-2,2,6,6-tetramethyl-cyclohex-4-en-1,3-diones, which comprises a pair of epimers, each of which is a pair of conformers, has been isolated from the hexane extract of the aerial parts of Kunzea ambigua and K. baxterii (Myrtaceae). The mixture exhibits moderate insecticidal activity in comparison with natural pyrethrum extract. Two Australasian species of Myrtaceae contain a mixture, which has insecticidal activity. It comprises two epimers (at C-1′) each of which exists as a pair of conformers.
doi_str_mv 10.1016/S0031-9422(01)00410-1
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source MEDLINE; ScienceDirect Journals (5 years ago - present)
subjects Biological and medical sciences
Chemical control
Chromones - isolation & purification
Control
Cyclohexanones - isolation & purification
Flavanone
Fundamental and applied biological sciences. Psychology
Insecticide
Insecticides - isolation & purification
Isomerism
Kunzea
Kunzea ambigua
Kunzea baxterii
Myrtaceae
Myrtaceae - chemistry
Phytopathology. Animal pests. Plant and forest protection
Protozoa. Invertebrates
pyrethrum
Tetramethylcyclohexenedione
title An insecticidal mixture of tetramethylcyclohexenedione isomers from Kunzea ambigua and Kunzea baxterii
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