Photocatalytic degradation of phenol using Ag core-TiO2 shell (Ag@TiO2) nanoparticles under UV light irradiation

Ag@TiO 2 nanoparticles were synthesized by one pot synthesis method with postcalcination. These nanoparticles were tested for their photocatalytic efficacies in degradation of phenol both in free and immobilized forms under UV light irradiation through batch experiments. Ag@TiO 2 nanoparticles were...

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Veröffentlicht in:Environmental science and pollution research international 2016-10, Vol.23 (20), p.20055-20064
Hauptverfasser: Shet, Amruta, Shetty K, Vidya
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description Ag@TiO 2 nanoparticles were synthesized by one pot synthesis method with postcalcination. These nanoparticles were tested for their photocatalytic efficacies in degradation of phenol both in free and immobilized forms under UV light irradiation through batch experiments. Ag@TiO 2 nanoparticles were found to be the effective photocatalysts for degradation of phenol. The effects of factors such as pH, initial phenol concentration, and catalyst loading on phenol degradation were evaluated, and these factors were found to influence the process efficiency. The optimum values of these factors were determined to maximize the phenol degradation. The efficacy of the nanoparticles immobilized on cellulose acetate film was inferior to that of free nanoparticles in UV photocatalysis due to light penetration problem and diffusional limitations. The performance of fluidized bed photocatalytic reactor operated under batch with recycle mode was evaluated for UV photocatalysis with immobilized Ag@TiO 2 nanoparticles. In the fluidized bed reactor, the percentage degradation of phenol was found to increase with the increase in catalyst loading.
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These nanoparticles were tested for their photocatalytic efficacies in degradation of phenol both in free and immobilized forms under UV light irradiation through batch experiments. Ag@TiO 2 nanoparticles were found to be the effective photocatalysts for degradation of phenol. The effects of factors such as pH, initial phenol concentration, and catalyst loading on phenol degradation were evaluated, and these factors were found to influence the process efficiency. The optimum values of these factors were determined to maximize the phenol degradation. The efficacy of the nanoparticles immobilized on cellulose acetate film was inferior to that of free nanoparticles in UV photocatalysis due to light penetration problem and diffusional limitations. The performance of fluidized bed photocatalytic reactor operated under batch with recycle mode was evaluated for UV photocatalysis with immobilized Ag@TiO 2 nanoparticles. 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These nanoparticles were tested for their photocatalytic efficacies in degradation of phenol both in free and immobilized forms under UV light irradiation through batch experiments. Ag@TiO 2 nanoparticles were found to be the effective photocatalysts for degradation of phenol. The effects of factors such as pH, initial phenol concentration, and catalyst loading on phenol degradation were evaluated, and these factors were found to influence the process efficiency. The optimum values of these factors were determined to maximize the phenol degradation. The efficacy of the nanoparticles immobilized on cellulose acetate film was inferior to that of free nanoparticles in UV photocatalysis due to light penetration problem and diffusional limitations. The performance of fluidized bed photocatalytic reactor operated under batch with recycle mode was evaluated for UV photocatalysis with immobilized Ag@TiO 2 nanoparticles. 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ispartof Environmental science and pollution research international, 2016-10, Vol.23 (20), p.20055-20064
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source SpringerNature Journals
subjects Aluminum
Aquatic Pollution
Atmospheric Protection/Air Quality Control/Air Pollution
Catalysis
Cellulose acetate
Chemical,Energy and Environmental Engineering
Chemicals
Earth and Environmental Science
Ecotoxicology
Electrons
Energy consumption
Environment
Environmental Chemistry
Environmental Health
Environmental monitoring
Environmental science
Experiments
Fluidized bed reactors
Fluidized beds
Irradiation
Light
Light penetration
Nanoparticles
Oxidation
Phenols
Photocatalysis
Photodegradation
Pollutants
Reactors
Studies
Titanium dioxide
Toxicity
Ultraviolet radiation
Waste Water Technology
Water Management
Water Pollution Control
title Photocatalytic degradation of phenol using Ag core-TiO2 shell (Ag@TiO2) nanoparticles under UV light irradiation
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