Photocatalytic degradation of phenol using Ag core-TiO2 shell (Ag@TiO2) nanoparticles under UV light irradiation
Ag@TiO 2 nanoparticles were synthesized by one pot synthesis method with postcalcination. These nanoparticles were tested for their photocatalytic efficacies in degradation of phenol both in free and immobilized forms under UV light irradiation through batch experiments. Ag@TiO 2 nanoparticles were...
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creator | Shet, Amruta Shetty K, Vidya |
description | Ag@TiO
2
nanoparticles were synthesized by one pot synthesis method with postcalcination. These nanoparticles were tested for their photocatalytic efficacies in degradation of phenol both in free and immobilized forms under UV light irradiation through batch experiments. Ag@TiO
2
nanoparticles were found to be the effective photocatalysts for degradation of phenol. The effects of factors such as pH, initial phenol concentration, and catalyst loading on phenol degradation were evaluated, and these factors were found to influence the process efficiency. The optimum values of these factors were determined to maximize the phenol degradation. The efficacy of the nanoparticles immobilized on cellulose acetate film was inferior to that of free nanoparticles in UV photocatalysis due to light penetration problem and diffusional limitations. The performance of fluidized bed photocatalytic reactor operated under batch with recycle mode was evaluated for UV photocatalysis with immobilized Ag@TiO
2
nanoparticles. In the fluidized bed reactor, the percentage degradation of phenol was found to increase with the increase in catalyst loading. |
doi_str_mv | 10.1007/s11356-015-5579-z |
format | Article |
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2
nanoparticles were synthesized by one pot synthesis method with postcalcination. These nanoparticles were tested for their photocatalytic efficacies in degradation of phenol both in free and immobilized forms under UV light irradiation through batch experiments. Ag@TiO
2
nanoparticles were found to be the effective photocatalysts for degradation of phenol. The effects of factors such as pH, initial phenol concentration, and catalyst loading on phenol degradation were evaluated, and these factors were found to influence the process efficiency. The optimum values of these factors were determined to maximize the phenol degradation. The efficacy of the nanoparticles immobilized on cellulose acetate film was inferior to that of free nanoparticles in UV photocatalysis due to light penetration problem and diffusional limitations. The performance of fluidized bed photocatalytic reactor operated under batch with recycle mode was evaluated for UV photocatalysis with immobilized Ag@TiO
2
nanoparticles. In the fluidized bed reactor, the percentage degradation of phenol was found to increase with the increase in catalyst loading.</description><identifier>ISSN: 0944-1344</identifier><identifier>EISSN: 1614-7499</identifier><identifier>DOI: 10.1007/s11356-015-5579-z</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Aluminum ; Aquatic Pollution ; Atmospheric Protection/Air Quality Control/Air Pollution ; Catalysis ; Cellulose acetate ; Chemical,Energy and Environmental Engineering ; Chemicals ; Earth and Environmental Science ; Ecotoxicology ; Electrons ; Energy consumption ; Environment ; Environmental Chemistry ; Environmental Health ; Environmental monitoring ; Environmental science ; Experiments ; Fluidized bed reactors ; Fluidized beds ; Irradiation ; Light ; Light penetration ; Nanoparticles ; Oxidation ; Phenols ; Photocatalysis ; Photodegradation ; Pollutants ; Reactors ; Studies ; Titanium dioxide ; Toxicity ; Ultraviolet radiation ; Waste Water Technology ; Water Management ; Water Pollution Control</subject><ispartof>Environmental science and pollution research international, 2016-10, Vol.23 (20), p.20055-20064</ispartof><rights>Springer-Verlag Berlin Heidelberg 2015</rights><rights>Environmental Science and Pollution Research is a copyright of Springer, 2016.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c386t-5e3931d2c8cb4945bd2addb71af434df51b6c74daa3c1231b5ac19236734ae93</citedby><cites>FETCH-LOGICAL-c386t-5e3931d2c8cb4945bd2addb71af434df51b6c74daa3c1231b5ac19236734ae93</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11356-015-5579-z$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s11356-015-5579-z$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>315,781,785,27928,27929,41492,42561,51323</link.rule.ids></links><search><creatorcontrib>Shet, Amruta</creatorcontrib><creatorcontrib>Shetty K, Vidya</creatorcontrib><title>Photocatalytic degradation of phenol using Ag core-TiO2 shell (Ag@TiO2) nanoparticles under UV light irradiation</title><title>Environmental science and pollution research international</title><addtitle>Environ Sci Pollut Res</addtitle><description>Ag@TiO
2
nanoparticles were synthesized by one pot synthesis method with postcalcination. These nanoparticles were tested for their photocatalytic efficacies in degradation of phenol both in free and immobilized forms under UV light irradiation through batch experiments. Ag@TiO
2
nanoparticles were found to be the effective photocatalysts for degradation of phenol. The effects of factors such as pH, initial phenol concentration, and catalyst loading on phenol degradation were evaluated, and these factors were found to influence the process efficiency. The optimum values of these factors were determined to maximize the phenol degradation. The efficacy of the nanoparticles immobilized on cellulose acetate film was inferior to that of free nanoparticles in UV photocatalysis due to light penetration problem and diffusional limitations. The performance of fluidized bed photocatalytic reactor operated under batch with recycle mode was evaluated for UV photocatalysis with immobilized Ag@TiO
2
nanoparticles. In the fluidized bed reactor, the percentage degradation of phenol was found to increase with the increase in catalyst loading.</description><subject>Aluminum</subject><subject>Aquatic Pollution</subject><subject>Atmospheric Protection/Air Quality Control/Air Pollution</subject><subject>Catalysis</subject><subject>Cellulose acetate</subject><subject>Chemical,Energy and Environmental Engineering</subject><subject>Chemicals</subject><subject>Earth and Environmental Science</subject><subject>Ecotoxicology</subject><subject>Electrons</subject><subject>Energy consumption</subject><subject>Environment</subject><subject>Environmental Chemistry</subject><subject>Environmental Health</subject><subject>Environmental monitoring</subject><subject>Environmental science</subject><subject>Experiments</subject><subject>Fluidized bed reactors</subject><subject>Fluidized beds</subject><subject>Irradiation</subject><subject>Light</subject><subject>Light penetration</subject><subject>Nanoparticles</subject><subject>Oxidation</subject><subject>Phenols</subject><subject>Photocatalysis</subject><subject>Photodegradation</subject><subject>Pollutants</subject><subject>Reactors</subject><subject>Studies</subject><subject>Titanium dioxide</subject><subject>Toxicity</subject><subject>Ultraviolet radiation</subject><subject>Waste Water Technology</subject><subject>Water Management</subject><subject>Water Pollution 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degradation of phenol using Ag core-TiO2 shell (Ag@TiO2) nanoparticles under UV light irradiation</title><author>Shet, Amruta ; Shetty K, Vidya</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c386t-5e3931d2c8cb4945bd2addb71af434df51b6c74daa3c1231b5ac19236734ae93</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Aluminum</topic><topic>Aquatic Pollution</topic><topic>Atmospheric Protection/Air Quality Control/Air Pollution</topic><topic>Catalysis</topic><topic>Cellulose acetate</topic><topic>Chemical,Energy and Environmental Engineering</topic><topic>Chemicals</topic><topic>Earth and Environmental Science</topic><topic>Ecotoxicology</topic><topic>Electrons</topic><topic>Energy consumption</topic><topic>Environment</topic><topic>Environmental Chemistry</topic><topic>Environmental Health</topic><topic>Environmental monitoring</topic><topic>Environmental science</topic><topic>Experiments</topic><topic>Fluidized bed reactors</topic><topic>Fluidized beds</topic><topic>Irradiation</topic><topic>Light</topic><topic>Light penetration</topic><topic>Nanoparticles</topic><topic>Oxidation</topic><topic>Phenols</topic><topic>Photocatalysis</topic><topic>Photodegradation</topic><topic>Pollutants</topic><topic>Reactors</topic><topic>Studies</topic><topic>Titanium dioxide</topic><topic>Toxicity</topic><topic>Ultraviolet radiation</topic><topic>Waste Water Technology</topic><topic>Water Management</topic><topic>Water Pollution Control</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Shet, Amruta</creatorcontrib><creatorcontrib>Shetty K, Vidya</creatorcontrib><collection>CrossRef</collection><collection>ProQuest Central (Corporate)</collection><collection>Bacteriology Abstracts (Microbiology B)</collection><collection>Ecology Abstracts</collection><collection>Industrial and Applied Microbiology Abstracts 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Basic</collection><collection>MEDLINE - Academic</collection><jtitle>Environmental science and pollution research international</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Shet, Amruta</au><au>Shetty K, Vidya</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Photocatalytic degradation of phenol using Ag core-TiO2 shell (Ag@TiO2) nanoparticles under UV light irradiation</atitle><jtitle>Environmental science and pollution research international</jtitle><stitle>Environ Sci Pollut Res</stitle><date>2016-10-01</date><risdate>2016</risdate><volume>23</volume><issue>20</issue><spage>20055</spage><epage>20064</epage><pages>20055-20064</pages><issn>0944-1344</issn><eissn>1614-7499</eissn><abstract>Ag@TiO
2
nanoparticles were synthesized by one pot synthesis method with postcalcination. These nanoparticles were tested for their photocatalytic efficacies in degradation of phenol both in free and immobilized forms under UV light irradiation through batch experiments. Ag@TiO
2
nanoparticles were found to be the effective photocatalysts for degradation of phenol. The effects of factors such as pH, initial phenol concentration, and catalyst loading on phenol degradation were evaluated, and these factors were found to influence the process efficiency. The optimum values of these factors were determined to maximize the phenol degradation. The efficacy of the nanoparticles immobilized on cellulose acetate film was inferior to that of free nanoparticles in UV photocatalysis due to light penetration problem and diffusional limitations. The performance of fluidized bed photocatalytic reactor operated under batch with recycle mode was evaluated for UV photocatalysis with immobilized Ag@TiO
2
nanoparticles. In the fluidized bed reactor, the percentage degradation of phenol was found to increase with the increase in catalyst loading.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s11356-015-5579-z</doi><tpages>10</tpages></addata></record> |
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subjects | Aluminum Aquatic Pollution Atmospheric Protection/Air Quality Control/Air Pollution Catalysis Cellulose acetate Chemical,Energy and Environmental Engineering Chemicals Earth and Environmental Science Ecotoxicology Electrons Energy consumption Environment Environmental Chemistry Environmental Health Environmental monitoring Environmental science Experiments Fluidized bed reactors Fluidized beds Irradiation Light Light penetration Nanoparticles Oxidation Phenols Photocatalysis Photodegradation Pollutants Reactors Studies Titanium dioxide Toxicity Ultraviolet radiation Waste Water Technology Water Management Water Pollution Control |
title | Photocatalytic degradation of phenol using Ag core-TiO2 shell (Ag@TiO2) nanoparticles under UV light irradiation |
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