Rapid copolymerization of carbon dioxide and propylene oxide catalyzed by double metal cyanide complexes in an ultrasonic field
Sonochemistry as a clean, efficient and environmentally friendly synthetic method has shown great potential in the chemical synthesis. In this work, poly (propylene carbonate) (PPC) was successfully obtained from carbon dioxide (CO2) and propylene oxide (PO) by using Zn-Co and Zn-Fe double metal cya...
Gespeichert in:
| Veröffentlicht in: | Materials letters 2016-10, Vol.180, p.89-92 |
|---|---|
| Hauptverfasser: | , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 92 |
|---|---|
| container_issue | |
| container_start_page | 89 |
| container_title | Materials letters |
| container_volume | 180 |
| creator | Dai, Chunyan Zhu, Qidong Pang, Huiying Zhu, Linhua Lin, Qiang |
| description | Sonochemistry as a clean, efficient and environmentally friendly synthetic method has shown great potential in the chemical synthesis. In this work, poly (propylene carbonate) (PPC) was successfully obtained from carbon dioxide (CO2) and propylene oxide (PO) by using Zn-Co and Zn-Fe double metal cyanides (DMCs) as catalyst with the sonochemistry method. With FTIR, 1H NMR and GPC analysis, PPCs prepared in the ultrasonic field have high yield, high molecular weight and wide polydispersity index (PDI). It is proven to be effective for the copolymerization of CO2 and PO with the sonochemistry method.
•PPC was successfully obtained from CO2 and PO with the sonochemistry method.•PPCs prepared in the ultrasonic field have high yield, high molecular weight and wide PDI.•It is effective for the copolymerization of PPC with the sonochemistry method. |
| doi_str_mv | 10.1016/j.matlet.2016.05.119 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1825567267</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><els_id>S0167577X16308849</els_id><sourcerecordid>1825567267</sourcerecordid><originalsourceid>FETCH-LOGICAL-c339t-878901b1e56105eb0f8371c51e51c733e67a3212dcee5933e0ed242ef593094f3</originalsourceid><addsrcrecordid>eNp9UE1LxDAUDKLguvoPPOTopTVpm6a9CLL4BQuCKHgLafIKWdKmJq1s9-JfN1rPnt6befMGZhC6pCSlhJbXu7STo4UxzSJKCUsprY_QilY8T4qa18doFQ88YZy_n6KzEHaEkKImxQp9vcjBaKzc4OzcgTcHORrXY9diJX0TN23c3mjAstd48G6YLfSAF07JUdr5ABo3M9ZuaizgDiKH1Sz7X4XrBgt7CNj00QJPdvQyuN4o3Bqw-hydtNIGuPiba_R2f_e6eUy2zw9Pm9ttovK8HpOKVzWhDQVWUsKgIW2Vc6pYJKjieQ4ll3lGM60AWB0xAZ0VGbQRkLpo8zW6WnxjhI8Jwig6ExRYK3twUxC0yhgreVbyKC0WqfIuBA-tGLzppJ8FJeKnb7ETS9_ip29BmIh9x7eb5Q1ijE8DXgRloFegjQc1Cu3M_wbfkqmNkg</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1825567267</pqid></control><display><type>article</type><title>Rapid copolymerization of carbon dioxide and propylene oxide catalyzed by double metal cyanide complexes in an ultrasonic field</title><source>ScienceDirect Journals (5 years ago - present)</source><creator>Dai, Chunyan ; Zhu, Qidong ; Pang, Huiying ; Zhu, Linhua ; Lin, Qiang</creator><creatorcontrib>Dai, Chunyan ; Zhu, Qidong ; Pang, Huiying ; Zhu, Linhua ; Lin, Qiang</creatorcontrib><description>Sonochemistry as a clean, efficient and environmentally friendly synthetic method has shown great potential in the chemical synthesis. In this work, poly (propylene carbonate) (PPC) was successfully obtained from carbon dioxide (CO2) and propylene oxide (PO) by using Zn-Co and Zn-Fe double metal cyanides (DMCs) as catalyst with the sonochemistry method. With FTIR, 1H NMR and GPC analysis, PPCs prepared in the ultrasonic field have high yield, high molecular weight and wide polydispersity index (PDI). It is proven to be effective for the copolymerization of CO2 and PO with the sonochemistry method.
•PPC was successfully obtained from CO2 and PO with the sonochemistry method.•PPCs prepared in the ultrasonic field have high yield, high molecular weight and wide PDI.•It is effective for the copolymerization of PPC with the sonochemistry method.</description><identifier>ISSN: 0167-577X</identifier><identifier>EISSN: 1873-4979</identifier><identifier>DOI: 10.1016/j.matlet.2016.05.119</identifier><language>eng</language><publisher>Elsevier B.V</publisher><subject>Bulk molding compounds ; Carbon dioxide ; Copolymerization ; Cyanides ; Double metal cyanides ; Molecular weight ; Nanosize ; Poly (propylene carbonate) ; Polymers ; Propylene ; Propylene oxide ; Rapid copolymerization ; Sonochemistry ; Zinc</subject><ispartof>Materials letters, 2016-10, Vol.180, p.89-92</ispartof><rights>2016 Elsevier B.V.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c339t-878901b1e56105eb0f8371c51e51c733e67a3212dcee5933e0ed242ef593094f3</citedby><cites>FETCH-LOGICAL-c339t-878901b1e56105eb0f8371c51e51c733e67a3212dcee5933e0ed242ef593094f3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.matlet.2016.05.119$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,780,784,3550,27924,27925,45995</link.rule.ids></links><search><creatorcontrib>Dai, Chunyan</creatorcontrib><creatorcontrib>Zhu, Qidong</creatorcontrib><creatorcontrib>Pang, Huiying</creatorcontrib><creatorcontrib>Zhu, Linhua</creatorcontrib><creatorcontrib>Lin, Qiang</creatorcontrib><title>Rapid copolymerization of carbon dioxide and propylene oxide catalyzed by double metal cyanide complexes in an ultrasonic field</title><title>Materials letters</title><description>Sonochemistry as a clean, efficient and environmentally friendly synthetic method has shown great potential in the chemical synthesis. In this work, poly (propylene carbonate) (PPC) was successfully obtained from carbon dioxide (CO2) and propylene oxide (PO) by using Zn-Co and Zn-Fe double metal cyanides (DMCs) as catalyst with the sonochemistry method. With FTIR, 1H NMR and GPC analysis, PPCs prepared in the ultrasonic field have high yield, high molecular weight and wide polydispersity index (PDI). It is proven to be effective for the copolymerization of CO2 and PO with the sonochemistry method.
•PPC was successfully obtained from CO2 and PO with the sonochemistry method.•PPCs prepared in the ultrasonic field have high yield, high molecular weight and wide PDI.•It is effective for the copolymerization of PPC with the sonochemistry method.</description><subject>Bulk molding compounds</subject><subject>Carbon dioxide</subject><subject>Copolymerization</subject><subject>Cyanides</subject><subject>Double metal cyanides</subject><subject>Molecular weight</subject><subject>Nanosize</subject><subject>Poly (propylene carbonate)</subject><subject>Polymers</subject><subject>Propylene</subject><subject>Propylene oxide</subject><subject>Rapid copolymerization</subject><subject>Sonochemistry</subject><subject>Zinc</subject><issn>0167-577X</issn><issn>1873-4979</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNp9UE1LxDAUDKLguvoPPOTopTVpm6a9CLL4BQuCKHgLafIKWdKmJq1s9-JfN1rPnt6befMGZhC6pCSlhJbXu7STo4UxzSJKCUsprY_QilY8T4qa18doFQ88YZy_n6KzEHaEkKImxQp9vcjBaKzc4OzcgTcHORrXY9diJX0TN23c3mjAstd48G6YLfSAF07JUdr5ABo3M9ZuaizgDiKH1Sz7X4XrBgt7CNj00QJPdvQyuN4o3Bqw-hydtNIGuPiba_R2f_e6eUy2zw9Pm9ttovK8HpOKVzWhDQVWUsKgIW2Vc6pYJKjieQ4ll3lGM60AWB0xAZ0VGbQRkLpo8zW6WnxjhI8Jwig6ExRYK3twUxC0yhgreVbyKC0WqfIuBA-tGLzppJ8FJeKnb7ETS9_ip29BmIh9x7eb5Q1ijE8DXgRloFegjQc1Cu3M_wbfkqmNkg</recordid><startdate>20161001</startdate><enddate>20161001</enddate><creator>Dai, Chunyan</creator><creator>Zhu, Qidong</creator><creator>Pang, Huiying</creator><creator>Zhu, Linhua</creator><creator>Lin, Qiang</creator><general>Elsevier B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20161001</creationdate><title>Rapid copolymerization of carbon dioxide and propylene oxide catalyzed by double metal cyanide complexes in an ultrasonic field</title><author>Dai, Chunyan ; Zhu, Qidong ; Pang, Huiying ; Zhu, Linhua ; Lin, Qiang</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c339t-878901b1e56105eb0f8371c51e51c733e67a3212dcee5933e0ed242ef593094f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Bulk molding compounds</topic><topic>Carbon dioxide</topic><topic>Copolymerization</topic><topic>Cyanides</topic><topic>Double metal cyanides</topic><topic>Molecular weight</topic><topic>Nanosize</topic><topic>Poly (propylene carbonate)</topic><topic>Polymers</topic><topic>Propylene</topic><topic>Propylene oxide</topic><topic>Rapid copolymerization</topic><topic>Sonochemistry</topic><topic>Zinc</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Dai, Chunyan</creatorcontrib><creatorcontrib>Zhu, Qidong</creatorcontrib><creatorcontrib>Pang, Huiying</creatorcontrib><creatorcontrib>Zhu, Linhua</creatorcontrib><creatorcontrib>Lin, Qiang</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Materials letters</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Dai, Chunyan</au><au>Zhu, Qidong</au><au>Pang, Huiying</au><au>Zhu, Linhua</au><au>Lin, Qiang</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Rapid copolymerization of carbon dioxide and propylene oxide catalyzed by double metal cyanide complexes in an ultrasonic field</atitle><jtitle>Materials letters</jtitle><date>2016-10-01</date><risdate>2016</risdate><volume>180</volume><spage>89</spage><epage>92</epage><pages>89-92</pages><issn>0167-577X</issn><eissn>1873-4979</eissn><abstract>Sonochemistry as a clean, efficient and environmentally friendly synthetic method has shown great potential in the chemical synthesis. In this work, poly (propylene carbonate) (PPC) was successfully obtained from carbon dioxide (CO2) and propylene oxide (PO) by using Zn-Co and Zn-Fe double metal cyanides (DMCs) as catalyst with the sonochemistry method. With FTIR, 1H NMR and GPC analysis, PPCs prepared in the ultrasonic field have high yield, high molecular weight and wide polydispersity index (PDI). It is proven to be effective for the copolymerization of CO2 and PO with the sonochemistry method.
•PPC was successfully obtained from CO2 and PO with the sonochemistry method.•PPCs prepared in the ultrasonic field have high yield, high molecular weight and wide PDI.•It is effective for the copolymerization of PPC with the sonochemistry method.</abstract><pub>Elsevier B.V</pub><doi>10.1016/j.matlet.2016.05.119</doi><tpages>4</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0167-577X |
| ispartof | Materials letters, 2016-10, Vol.180, p.89-92 |
| issn | 0167-577X 1873-4979 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_1825567267 |
| source | ScienceDirect Journals (5 years ago - present) |
| subjects | Bulk molding compounds Carbon dioxide Copolymerization Cyanides Double metal cyanides Molecular weight Nanosize Poly (propylene carbonate) Polymers Propylene Propylene oxide Rapid copolymerization Sonochemistry Zinc |
| title | Rapid copolymerization of carbon dioxide and propylene oxide catalyzed by double metal cyanide complexes in an ultrasonic field |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-06T05%3A48%3A46IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Rapid%20copolymerization%20of%20carbon%20dioxide%20and%20propylene%20oxide%20catalyzed%20by%20double%20metal%20cyanide%20complexes%20in%20an%20ultrasonic%20field&rft.jtitle=Materials%20letters&rft.au=Dai,%20Chunyan&rft.date=2016-10-01&rft.volume=180&rft.spage=89&rft.epage=92&rft.pages=89-92&rft.issn=0167-577X&rft.eissn=1873-4979&rft_id=info:doi/10.1016/j.matlet.2016.05.119&rft_dat=%3Cproquest_cross%3E1825567267%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1825567267&rft_id=info:pmid/&rft_els_id=S0167577X16308849&rfr_iscdi=true |