Rhodium-catalyzed asymmetric synthesis of silicon-stereogenic silicon-bridged arylpyridinones

A rhodium-catalyzed regio- and enantioselective synthesis of silicon-stereogenic silicon-bridged arylpyridinones has been developed through [2 + 2 + 2] cycloaddition of silicon-containing prochiral triynes with isocyanates. High yields and enantioselectivities have been achieved by employing an axia...

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Veröffentlicht in:	Chemical science (Cambridge) 2016-01, Vol.7 (2), p.125-1211
Hauptverfasser:	Shintani, Ryo, Takano, Ryo, Nozaki, Kyoko
Format:	Artikel
Sprache:	eng
Schlagworte:	Asymmetry Catalysis Catalysts Chemistry Cycloaddition Ligands Polymers Rhodium Synthesis
Online-Zugang:	Volltext
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