Thermal stability of specialty optical fiber coatings
Thermal stability of coatings used on specialty optical fibers is assessed via thermogravimetry (TG). The coating lifetimes are evaluated by analyzing dynamic TG curves and assuming a particular level of mass loss as a failure criterion. The studied coating systems include single and dual acrylate,...
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| Veröffentlicht in: | Journal of thermal analysis and calorimetry 2016-06, Vol.124 (3), p.1411-1423 |
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| container_issue | 3 |
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| container_title | Journal of thermal analysis and calorimetry |
| container_volume | 124 |
| creator | Stolov, Andrei A Wrubel, Jacob A Simoff, Debra A |
| description | Thermal stability of coatings used on specialty optical fibers is assessed via thermogravimetry (TG). The coating lifetimes are evaluated by analyzing dynamic TG curves and assuming a particular level of mass loss as a failure criterion. The studied coating systems include single and dual acrylate, fluorinated acrylate, epoxy, epoxy acrylate, silicone, silicone acrylate, silsesquioxane acrylate and polyimide materials. Processing the data by Arrhenius and Eyring equations indicates that a kinetic compensation effect (KCE) is observed for the decomposition processes, with distinct parameters for different classes of the coatings. Two aspects of the KCE are considered: (1) decomposition within several series of similar compounds in air and (2) decomposition of the same classes in different environments. An attempt is made to use the KCE to predict the lifetimes of the coatings at elevated temperatures. |
| doi_str_mv | 10.1007/s10973-016-5250-z |
| format | Article |
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The coating lifetimes are evaluated by analyzing dynamic TG curves and assuming a particular level of mass loss as a failure criterion. The studied coating systems include single and dual acrylate, fluorinated acrylate, epoxy, epoxy acrylate, silicone, silicone acrylate, silsesquioxane acrylate and polyimide materials. Processing the data by Arrhenius and Eyring equations indicates that a kinetic compensation effect (KCE) is observed for the decomposition processes, with distinct parameters for different classes of the coatings. Two aspects of the KCE are considered: (1) decomposition within several series of similar compounds in air and (2) decomposition of the same classes in different environments. 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The coating lifetimes are evaluated by analyzing dynamic TG curves and assuming a particular level of mass loss as a failure criterion. The studied coating systems include single and dual acrylate, fluorinated acrylate, epoxy, epoxy acrylate, silicone, silicone acrylate, silsesquioxane acrylate and polyimide materials. Processing the data by Arrhenius and Eyring equations indicates that a kinetic compensation effect (KCE) is observed for the decomposition processes, with distinct parameters for different classes of the coatings. Two aspects of the KCE are considered: (1) decomposition within several series of similar compounds in air and (2) decomposition of the same classes in different environments. An attempt is made to use the KCE to predict the lifetimes of the coatings at elevated temperatures.</description><subject>Acrylates</subject><subject>Analysis</subject><subject>Coatings</subject><subject>Decomposition</subject><subject>Dynamics</subject><subject>Epoxy resins</subject><subject>Equipment and supplies</subject><subject>Fiber optics</subject><subject>Mathematical analysis</subject><subject>Optical fibers</subject><subject>Silicones</subject><subject>Thermal stability</subject><issn>1388-6150</issn><issn>1588-2926</issn><issn>1572-8943</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNpVjUtPwzAQhC0EEuXxA7jlCAeX9cZO4mNV8ahUCQnKOXLsdTFKkxK7EvDrSVUOcNqZ3W9mGbsSMBUA5W0UoMucgyi4QgX8-4hNhKoqjhqL41Hnoy6EglN2FuM7AGgNYsLU6o2GjWmzmEwT2pC-st5ncUs2mHZvtinY8exDQ0Nme5NCt44X7MSbNtLl7zxnr_d3q_kjXz49LOazJbdCSeSErrTGmsZ7bCRV1oJTIBSiQaepdLLRhSEsvUMNEhopSeaIBTohLej8nF0ferdD_7GjmOpNiJba1nTU72ItKlRKCoE4otMDujYt1aHzfRrM_rmjTbB9Rz6M-5lUKHSp9L775l9gZBJ9prXZxVgvXp7_sj8DY2e-</recordid><startdate>20160601</startdate><enddate>20160601</enddate><creator>Stolov, Andrei A</creator><creator>Wrubel, Jacob A</creator><creator>Simoff, Debra A</creator><general>Springer</general><scope>ISR</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20160601</creationdate><title>Thermal stability of specialty optical fiber coatings</title><author>Stolov, Andrei A ; Wrubel, Jacob A ; Simoff, Debra A</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c1542-e2d7cacabff2b4e8cc0d501522a2d9e7d4b96ae27fd29040b44e432262d14c093</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Acrylates</topic><topic>Analysis</topic><topic>Coatings</topic><topic>Decomposition</topic><topic>Dynamics</topic><topic>Epoxy resins</topic><topic>Equipment and supplies</topic><topic>Fiber optics</topic><topic>Mathematical analysis</topic><topic>Optical fibers</topic><topic>Silicones</topic><topic>Thermal stability</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Stolov, Andrei A</creatorcontrib><creatorcontrib>Wrubel, Jacob A</creatorcontrib><creatorcontrib>Simoff, Debra A</creatorcontrib><collection>Gale In Context: Science</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Journal of thermal analysis and calorimetry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Stolov, Andrei A</au><au>Wrubel, Jacob A</au><au>Simoff, Debra A</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Thermal stability of specialty optical fiber coatings</atitle><jtitle>Journal of thermal analysis and calorimetry</jtitle><date>2016-06-01</date><risdate>2016</risdate><volume>124</volume><issue>3</issue><spage>1411</spage><epage>1423</epage><pages>1411-1423</pages><issn>1388-6150</issn><eissn>1588-2926</eissn><eissn>1572-8943</eissn><abstract>Thermal stability of coatings used on specialty optical fibers is assessed via thermogravimetry (TG). The coating lifetimes are evaluated by analyzing dynamic TG curves and assuming a particular level of mass loss as a failure criterion. The studied coating systems include single and dual acrylate, fluorinated acrylate, epoxy, epoxy acrylate, silicone, silicone acrylate, silsesquioxane acrylate and polyimide materials. Processing the data by Arrhenius and Eyring equations indicates that a kinetic compensation effect (KCE) is observed for the decomposition processes, with distinct parameters for different classes of the coatings. Two aspects of the KCE are considered: (1) decomposition within several series of similar compounds in air and (2) decomposition of the same classes in different environments. An attempt is made to use the KCE to predict the lifetimes of the coatings at elevated temperatures.</abstract><pub>Springer</pub><doi>10.1007/s10973-016-5250-z</doi><tpages>13</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1388-6150 |
| ispartof | Journal of thermal analysis and calorimetry, 2016-06, Vol.124 (3), p.1411-1423 |
| issn | 1388-6150 1588-2926 1572-8943 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_1825541122 |
| source | Springer Nature - Complete Springer Journals |
| subjects | Acrylates Analysis Coatings Decomposition Dynamics Epoxy resins Equipment and supplies Fiber optics Mathematical analysis Optical fibers Silicones Thermal stability |
| title | Thermal stability of specialty optical fiber coatings |
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