A vacuum flash-assisted solution process for high-efficiency large-area perovskite solar cells

Metal halide perovskite solar cells (PSCs) currently attract enormous research interest because of their high solar-to-electric power conversion efficiency (PCE) and low fabrication costs, but their practical development is hampered by difficulties in achieving high performance with large-size devic...

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Veröffentlicht in:Science (American Association for the Advancement of Science) 2016-07, Vol.353 (6294), p.58-62
Hauptverfasser: Li, Xiong, Bi, Dongqin, Yi, Chenyi, Décoppet, Jean-David, Luo, Jingshan, Zakeeruddin, Shaik Mohammed, Hagfeldt, Anders, Grätzel, Michael
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container_issue 6294
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container_title Science (American Association for the Advancement of Science)
container_volume 353
creator Li, Xiong
Bi, Dongqin
Yi, Chenyi
Décoppet, Jean-David
Luo, Jingshan
Zakeeruddin, Shaik Mohammed
Hagfeldt, Anders
Grätzel, Michael
description Metal halide perovskite solar cells (PSCs) currently attract enormous research interest because of their high solar-to-electric power conversion efficiency (PCE) and low fabrication costs, but their practical development is hampered by difficulties in achieving high performance with large-size devices. We devised a simple vacuum flash—assisted solution processing method to obtain shiny, smooth, crystalline perovskite films of high electronic quality over large areas. This enabled us to fabricate solar cells with an aperture area exceeding 1 square centimeter, a maximum efficiency of 20.5%, and a certified PCE of 19.6%. By contrast, the best certified PCE to date is 15.6% for PSCs of similar size. We demonstrate that the reproducibility of the method is excellent and that the cells show virtually no hysteresis. Our approach enables the realization of highly efficient large-area PSCs for practical deployment.
doi_str_mv 10.1126/science.aaf8060
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source American Association for the Advancement of Science; Jstor Complete Legacy
subjects Crystal structure
Electric power
Electronics
Energy conversion efficiency
Fabrication
Materials science
Metal halides
Perovskites
Photovoltaic cells
Production costs
Reproducibility
Solar cells
title A vacuum flash-assisted solution process for high-efficiency large-area perovskite solar cells
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