Copper-catalyzed hydroboration of propargyl-functionalized alkynes in water
The Cu-catalyzed hydroboration of alkynes in operationally simple and environmentally friendly conditions is reported. The reactions are performed in water, at room temperature, under micellar catalysis. Conditions to form the α or β borylated products selectively have been found and as an applicati...
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| Veröffentlicht in: | RSC advances 2016-01, Vol.6 (65), p.59935-59938 |
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| container_issue | 65 |
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| container_title | RSC advances |
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| creator | da Costa, Jessie S Braun, Roger K Horn, Pedro A Lüdtke, Diogo S Moro, Angélica V |
| description | The Cu-catalyzed hydroboration of alkynes in operationally simple and environmentally friendly conditions is reported. The reactions are performed in water, at room temperature, under micellar catalysis. Conditions to form the α or β borylated products selectively have been found and as an application a protocol for the tandem hydroboration/Suzuki coupling in water was developed.
The Cu-catalyzed hydroboration of alkynes in operationally simple and environmentally friendly conditions is reported. |
| doi_str_mv | 10.1039/c6ra14465a |
| format | Article |
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The Cu-catalyzed hydroboration of alkynes in operationally simple and environmentally friendly conditions is reported.</description><subject>Alkynes</subject><subject>Catalysis</subject><subject>Copper</subject><subject>Coupling</subject><subject>Hydroboration</subject><issn>2046-2069</issn><issn>2046-2069</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNpN0E1LxDAQBuAgCi7rXrwLPYpQzUeTbY9L8QsXBNFzmSYTrWabmnSR-uvtWlHnMsPwMAwvIceMnjMqigutArAsUxL2yIzTTKWcqmL_33xIFjG-0rGUZFyxGbkrfddhSDX04IZPNMnLYIKvfYC-8W3ibdIF30F4Hlxqt63ebcE1OwnubWgxJk2bfECP4YgcWHARFz99Tp6uLh_Lm3R9f31brtapFpL3aZ5lwvBCKgPcGgucCpYzIWteZ0ZJy2qTI2rNaosCl7AUnGMhBBrQIleZmJPT6e742fsWY19tmqjROWjRb2PFci6lYEotR3o2UR18jAFt1YVmA2GoGK12oVWlelh9h7Ya8cmEQ9S_7i9U8QXu8Go7</recordid><startdate>20160101</startdate><enddate>20160101</enddate><creator>da Costa, Jessie S</creator><creator>Braun, Roger K</creator><creator>Horn, Pedro A</creator><creator>Lüdtke, Diogo S</creator><creator>Moro, Angélica V</creator><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20160101</creationdate><title>Copper-catalyzed hydroboration of propargyl-functionalized alkynes in water</title><author>da Costa, Jessie S ; Braun, Roger K ; Horn, Pedro A ; Lüdtke, Diogo S ; Moro, Angélica V</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c352t-8443d2956da2fdfa20318135b2b4d65f1bd8eecc1bfe3e7a7322e933edac38643</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Alkynes</topic><topic>Catalysis</topic><topic>Copper</topic><topic>Coupling</topic><topic>Hydroboration</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>da Costa, Jessie S</creatorcontrib><creatorcontrib>Braun, Roger K</creatorcontrib><creatorcontrib>Horn, Pedro A</creatorcontrib><creatorcontrib>Lüdtke, Diogo S</creatorcontrib><creatorcontrib>Moro, Angélica V</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>RSC advances</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>da Costa, Jessie S</au><au>Braun, Roger K</au><au>Horn, Pedro A</au><au>Lüdtke, Diogo S</au><au>Moro, Angélica V</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Copper-catalyzed hydroboration of propargyl-functionalized alkynes in water</atitle><jtitle>RSC advances</jtitle><date>2016-01-01</date><risdate>2016</risdate><volume>6</volume><issue>65</issue><spage>59935</spage><epage>59938</epage><pages>59935-59938</pages><issn>2046-2069</issn><eissn>2046-2069</eissn><abstract>The Cu-catalyzed hydroboration of alkynes in operationally simple and environmentally friendly conditions is reported. The reactions are performed in water, at room temperature, under micellar catalysis. Conditions to form the α or β borylated products selectively have been found and as an application a protocol for the tandem hydroboration/Suzuki coupling in water was developed.
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| source | Royal Society Of Chemistry Journals 2008- |
| subjects | Alkynes Catalysis Copper Coupling Hydroboration |
| title | Copper-catalyzed hydroboration of propargyl-functionalized alkynes in water |
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