Nitrogen-rich hypergolic ionic salts based on (2-methyltetrazol-5-yl)diazotates
A series of hypergolic (2-methyltetrazol-5-yl)diazotates have been synthesized by treatment of bases with the diazotatic acid, which were prepared by using isoamyl nitrite at low temperature. These hypergolic energetic salts showed remarkable short ignition delay times (IDs) by droplet test and a hi...
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| Veröffentlicht in: | RSC advances 2016-01, Vol.6 (62), p.56827-5683 |
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| container_title | RSC advances |
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| creator | Wang, Qi Lu, Huijie Pang, Fuqing Huang, Jinglun Nie, Fude Chen, Fu-Xue |
| description | A series of hypergolic (2-methyltetrazol-5-yl)diazotates have been synthesized by treatment of bases with the diazotatic acid, which were prepared by using isoamyl nitrite at low temperature. These hypergolic energetic salts showed remarkable short ignition delay times (IDs) by droplet test and a high specific impulse up to 291.2 s by calculation. All compounds were fully characterized using IR spectroscopy,
1
H and
13
C NMR spectroscopy and differential scanning calorimetry (DSC), and, in the case of aminoguanidinium (2-methyltetrazol-5-yl)diazotate (
8
) and diaminoguanidinium (2-methyltetrazol-5-yl)diazotate (
9
), with single crystal X-ray structuring.
Novel hypergolic energetic salts containing the (2-methyltetrazol-5-yl)diazotate anion were synthesized and exhibit attractive short ignition delay times with white fuming HNO
3
. |
| doi_str_mv | 10.1039/c6ra11494f |
| format | Article |
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1
H and
13
C NMR spectroscopy and differential scanning calorimetry (DSC), and, in the case of aminoguanidinium (2-methyltetrazol-5-yl)diazotate (
8
) and diaminoguanidinium (2-methyltetrazol-5-yl)diazotate (
9
), with single crystal X-ray structuring.
Novel hypergolic energetic salts containing the (2-methyltetrazol-5-yl)diazotate anion were synthesized and exhibit attractive short ignition delay times with white fuming HNO
3
.</description><identifier>ISSN: 2046-2069</identifier><identifier>EISSN: 2046-2069</identifier><identifier>DOI: 10.1039/c6ra11494f</identifier><language>eng</language><subject>Delay ; Differential scanning calorimetry ; Droplets ; Infrared spectroscopy ; Mathematical analysis ; NMR spectroscopy ; Specific impulse ; X-rays</subject><ispartof>RSC advances, 2016-01, Vol.6 (62), p.56827-5683</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c286t-e8c44b4f3022ecffbca74236c4a5d27ea1416ae48921acdd1728ffcefc6a7ba53</citedby><cites>FETCH-LOGICAL-c286t-e8c44b4f3022ecffbca74236c4a5d27ea1416ae48921acdd1728ffcefc6a7ba53</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Wang, Qi</creatorcontrib><creatorcontrib>Lu, Huijie</creatorcontrib><creatorcontrib>Pang, Fuqing</creatorcontrib><creatorcontrib>Huang, Jinglun</creatorcontrib><creatorcontrib>Nie, Fude</creatorcontrib><creatorcontrib>Chen, Fu-Xue</creatorcontrib><title>Nitrogen-rich hypergolic ionic salts based on (2-methyltetrazol-5-yl)diazotates</title><title>RSC advances</title><description>A series of hypergolic (2-methyltetrazol-5-yl)diazotates have been synthesized by treatment of bases with the diazotatic acid, which were prepared by using isoamyl nitrite at low temperature. These hypergolic energetic salts showed remarkable short ignition delay times (IDs) by droplet test and a high specific impulse up to 291.2 s by calculation. All compounds were fully characterized using IR spectroscopy,
1
H and
13
C NMR spectroscopy and differential scanning calorimetry (DSC), and, in the case of aminoguanidinium (2-methyltetrazol-5-yl)diazotate (
8
) and diaminoguanidinium (2-methyltetrazol-5-yl)diazotate (
9
), with single crystal X-ray structuring.
Novel hypergolic energetic salts containing the (2-methyltetrazol-5-yl)diazotate anion were synthesized and exhibit attractive short ignition delay times with white fuming HNO
3
.</description><subject>Delay</subject><subject>Differential scanning calorimetry</subject><subject>Droplets</subject><subject>Infrared spectroscopy</subject><subject>Mathematical analysis</subject><subject>NMR spectroscopy</subject><subject>Specific impulse</subject><subject>X-rays</subject><issn>2046-2069</issn><issn>2046-2069</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNpNkMFLwzAUxoMoOOYu3oUepxBN0jRtj2M4FYYD0XN5TV-2StbMJDvUv97OifoO3_sOP77Dj5BLzm45S8s7rTxwLktpTshIMKmoYKo8_dfPySSEdzacyrhQfERWz230bo0d9a3eJJt-h37tbKuT1nVDBrAxJDUEbBLXJVNBtxg3vY0YPXw6SzPa2-umHXqEiOGCnBmwASc_f0zeFvev80e6XD08zWdLqkWhIsVCS1lLkzIhUBtTa8ilSJWWkDUiR-CSK0BZlIKDbhqei8IYjUYryGvI0jGZHnd33n3sMcRq2waN1kKHbh8qXogsE6UsD-jNEdXeheDRVDvfbsH3FWfVQVw1Vy-zb3GLAb46wj7oX-5PbPoFFXZrTA</recordid><startdate>20160101</startdate><enddate>20160101</enddate><creator>Wang, Qi</creator><creator>Lu, Huijie</creator><creator>Pang, Fuqing</creator><creator>Huang, Jinglun</creator><creator>Nie, Fude</creator><creator>Chen, Fu-Xue</creator><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20160101</creationdate><title>Nitrogen-rich hypergolic ionic salts based on (2-methyltetrazol-5-yl)diazotates</title><author>Wang, Qi ; Lu, Huijie ; Pang, Fuqing ; Huang, Jinglun ; Nie, Fude ; Chen, Fu-Xue</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c286t-e8c44b4f3022ecffbca74236c4a5d27ea1416ae48921acdd1728ffcefc6a7ba53</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Delay</topic><topic>Differential scanning calorimetry</topic><topic>Droplets</topic><topic>Infrared spectroscopy</topic><topic>Mathematical analysis</topic><topic>NMR spectroscopy</topic><topic>Specific impulse</topic><topic>X-rays</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Wang, Qi</creatorcontrib><creatorcontrib>Lu, Huijie</creatorcontrib><creatorcontrib>Pang, Fuqing</creatorcontrib><creatorcontrib>Huang, Jinglun</creatorcontrib><creatorcontrib>Nie, Fude</creatorcontrib><creatorcontrib>Chen, Fu-Xue</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>RSC advances</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wang, Qi</au><au>Lu, Huijie</au><au>Pang, Fuqing</au><au>Huang, Jinglun</au><au>Nie, Fude</au><au>Chen, Fu-Xue</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Nitrogen-rich hypergolic ionic salts based on (2-methyltetrazol-5-yl)diazotates</atitle><jtitle>RSC advances</jtitle><date>2016-01-01</date><risdate>2016</risdate><volume>6</volume><issue>62</issue><spage>56827</spage><epage>5683</epage><pages>56827-5683</pages><issn>2046-2069</issn><eissn>2046-2069</eissn><abstract>A series of hypergolic (2-methyltetrazol-5-yl)diazotates have been synthesized by treatment of bases with the diazotatic acid, which were prepared by using isoamyl nitrite at low temperature. These hypergolic energetic salts showed remarkable short ignition delay times (IDs) by droplet test and a high specific impulse up to 291.2 s by calculation. All compounds were fully characterized using IR spectroscopy,
1
H and
13
C NMR spectroscopy and differential scanning calorimetry (DSC), and, in the case of aminoguanidinium (2-methyltetrazol-5-yl)diazotate (
8
) and diaminoguanidinium (2-methyltetrazol-5-yl)diazotate (
9
), with single crystal X-ray structuring.
Novel hypergolic energetic salts containing the (2-methyltetrazol-5-yl)diazotate anion were synthesized and exhibit attractive short ignition delay times with white fuming HNO
3
.</abstract><doi>10.1039/c6ra11494f</doi><tpages>4</tpages></addata></record> |
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| source | Royal Society Of Chemistry Journals |
| subjects | Delay Differential scanning calorimetry Droplets Infrared spectroscopy Mathematical analysis NMR spectroscopy Specific impulse X-rays |
| title | Nitrogen-rich hypergolic ionic salts based on (2-methyltetrazol-5-yl)diazotates |
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