Ir( iii )-catalyzed synthesis of isoquinolines from benzimidates and α-diazocarbonyl compounds

We report herein a tandem Ir( iii )-catalyzed C–H activation and annulation reaction for the synthesis of isoquinolines by using readily available substituted benzimidates and α-diazocarbonyl compounds under mild conditions. The catalytic reaction exhibits excellent tolerance to different functional...

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Veröffentlicht in:	RSC advances 2016-01, Vol.6 (62), p.57371-57374
Hauptverfasser:	Yang, Xiaobo, Jie, Jiyang, Li, Haoyi, Piao, Meihui
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Sprache:	eng
Schlagworte:	Activation Chemical reactions Derivatives Functional groups Organic chemistry Strategy Synthesis Tolerances
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creator	Yang, Xiaobo Jie, Jiyang Li, Haoyi Piao, Meihui
description	We report herein a tandem Ir( iii )-catalyzed C–H activation and annulation reaction for the synthesis of isoquinolines by using readily available substituted benzimidates and α-diazocarbonyl compounds under mild conditions. The catalytic reaction exhibits excellent tolerance to different functional groups and the corresponding isoquinolines were obtained in good to excellent yields. This novel method affords an alternative strategy for the construction of diverse and useful isoquinoline derivatives.
doi_str_mv	10.1039/C6RA10045G
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title	Ir( iii )-catalyzed synthesis of isoquinolines from benzimidates and α-diazocarbonyl compounds
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