Cesium-containing triple cation perovskite solar cells: improved stability, reproducibility and high efficiency

Today's best perovskite solar cells use a mixture of formamidinium and methylammonium as the monovalent cations. With the addition of inorganic cesium, the resulting triple cation perovskite compositions are thermally more stable, contain less phase impurities and are less sensitive to processi...

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Veröffentlicht in:Energy & environmental science 2016-01, Vol.9 (6), p.1989-1997
Hauptverfasser: Saliba, Michael, Matsui, Taisuke, Seo, Ji-Youn, Domanski, Konrad, Correa-Baena, Juan-Pablo, Nazeeruddin, Mohammad Khaja, Zakeeruddin, Shaik M, Tress, Wolfgang, Abate, Antonio, Hagfeldt, Anders, Grätzel, Michael
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container_end_page 1997
container_issue 6
container_start_page 1989
container_title Energy & environmental science
container_volume 9
creator Saliba, Michael
Matsui, Taisuke
Seo, Ji-Youn
Domanski, Konrad
Correa-Baena, Juan-Pablo
Nazeeruddin, Mohammad Khaja
Zakeeruddin, Shaik M
Tress, Wolfgang
Abate, Antonio
Hagfeldt, Anders
Grätzel, Michael
description Today's best perovskite solar cells use a mixture of formamidinium and methylammonium as the monovalent cations. With the addition of inorganic cesium, the resulting triple cation perovskite compositions are thermally more stable, contain less phase impurities and are less sensitive to processing conditions. This enables more reproducible device performances to reach a stabilized power output of 21.1% and ∼18% after 250 hours under operational conditions. These properties are key for the industrialization of perovskite photovoltaics. Today's best perovskite solar cells use a mixture of formamidinium and methylammonium as the monovalent cations. Adding cesium improves the compositions greatly.
doi_str_mv 10.1039/c5ee03874j
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source Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects Cations
Devices
Industrial development
Perovskites
Photovoltaic cells
Reproducibility
Solar cells
Solar power generation
title Cesium-containing triple cation perovskite solar cells: improved stability, reproducibility and high efficiency
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