The effect of pH of plating bath on electrodeposition and properties of protective ternary Zn–Fe–Mo alloy coatings
Ternary Zn–Fe–Mo alloy coatings electrodeposition in a sulphate bath with tri-sodium citrate in the pH range 4.8–6.0 was studied. The increase of the plating bath pH from 4.8 to 6.0 leads to the iron content increase from 1.5 up to 7.9wt% and it is accompanied by a significant decrease in the curren...
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| Veröffentlicht in: | Surface & coatings technology 2016-08, Vol.299, p.81-89 |
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| creator | Winiarski, J. Leśniewicz, A. Pohl, P. Szczygieł, B. |
| description | Ternary Zn–Fe–Mo alloy coatings electrodeposition in a sulphate bath with tri-sodium citrate in the pH range 4.8–6.0 was studied. The increase of the plating bath pH from 4.8 to 6.0 leads to the iron content increase from 1.5 up to 7.9wt% and it is accompanied by a significant decrease in the current efficiency from 76 to 51%. It was demonstrated that molybdenum co-deposition starts at pH>4.8, because binary Zn–Fe alloy coating without a significant amount of molybdenum was obtained from the plating solution at pH4.8. The Mo content increases from 0.8wt% at pH5.1 to 2.7wt% at pH5.7 and 6.0. X-ray diffraction analysis as well as anodic linear sweep voltammetry measurements showed that within the considered plating solution pH range molybdenum modifies zinc microstructure to a very large extent. The deposited at pH5.4–6.0 Zn–Fe–Mo coatings contain a solid solution of iron and molybdenum in zinc and probably FeZnx phase, where 6.67 |
| doi_str_mv | 10.1016/j.surfcoat.2016.04.073 |
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[Display omitted]
•Zn–Fe–Mo coatings can be deposited from sulphate-citrate baths in pH range: 5.4–6.0.•Deposition of bright and homogenous Zn–Fe–Mo coatings is possible at pH close to 5.7.•The content of Fe and Mo in ternary alloy coatings depends on the pH of plating bath.•Codeposition of Mo causes an increase of Fe amount in Zn–Fe–Mo coating.•Increase in Mo and Fe contents shift corrosion potentials towards noble potentials.</description><identifier>ISSN: 0257-8972</identifier><identifier>EISSN: 1879-3347</identifier><identifier>DOI: 10.1016/j.surfcoat.2016.04.073</identifier><language>eng</language><publisher>Elsevier B.V</publisher><subject>Anodic dissolution ; Coatings ; Cyclic voltammetry ; Electrodeposition ; Iron ; Molybdenum ; Plating ; Plating baths ; X-ray diffraction ; Zinc ; Zinc base alloys ; Zn–Fe–Mo alloy coating</subject><ispartof>Surface & coatings technology, 2016-08, Vol.299, p.81-89</ispartof><rights>2016 Elsevier B.V.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c345t-71956cdbb96f306fc0f9469e1e8fc6f3cad8f10803304a236751beb2b2a51adb3</citedby><cites>FETCH-LOGICAL-c345t-71956cdbb96f306fc0f9469e1e8fc6f3cad8f10803304a236751beb2b2a51adb3</cites><orcidid>0000-0003-0761-1579</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0257897216303565$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3537,27901,27902,65306</link.rule.ids></links><search><creatorcontrib>Winiarski, J.</creatorcontrib><creatorcontrib>Leśniewicz, A.</creatorcontrib><creatorcontrib>Pohl, P.</creatorcontrib><creatorcontrib>Szczygieł, B.</creatorcontrib><title>The effect of pH of plating bath on electrodeposition and properties of protective ternary Zn–Fe–Mo alloy coatings</title><title>Surface & coatings technology</title><description>Ternary Zn–Fe–Mo alloy coatings electrodeposition in a sulphate bath with tri-sodium citrate in the pH range 4.8–6.0 was studied. The increase of the plating bath pH from 4.8 to 6.0 leads to the iron content increase from 1.5 up to 7.9wt% and it is accompanied by a significant decrease in the current efficiency from 76 to 51%. It was demonstrated that molybdenum co-deposition starts at pH>4.8, because binary Zn–Fe alloy coating without a significant amount of molybdenum was obtained from the plating solution at pH4.8. The Mo content increases from 0.8wt% at pH5.1 to 2.7wt% at pH5.7 and 6.0. X-ray diffraction analysis as well as anodic linear sweep voltammetry measurements showed that within the considered plating solution pH range molybdenum modifies zinc microstructure to a very large extent. The deposited at pH5.4–6.0 Zn–Fe–Mo coatings contain a solid solution of iron and molybdenum in zinc and probably FeZnx phase, where 6.67<x<13. Potentiodynamic polarization revealed that the deposited at pH5.7 and 6.0 Zn–Fe–Mo coatings are characterized by a significantly lower corrosion rate in 0.5moldm−3 NaCl solution. This was confirmed by an electrochemical impedance spectroscopy test, where Zn–Fe(7.9wt%)–Mo(2.7wt%) alloy coating reached the highest resistance of charge transfer reaction during 24hours of exposure to NaCl solution.
[Display omitted]
•Zn–Fe–Mo coatings can be deposited from sulphate-citrate baths in pH range: 5.4–6.0.•Deposition of bright and homogenous Zn–Fe–Mo coatings is possible at pH close to 5.7.•The content of Fe and Mo in ternary alloy coatings depends on the pH of plating bath.•Codeposition of Mo causes an increase of Fe amount in Zn–Fe–Mo coating.•Increase in Mo and Fe contents shift corrosion potentials towards noble potentials.</description><subject>Anodic dissolution</subject><subject>Coatings</subject><subject>Cyclic voltammetry</subject><subject>Electrodeposition</subject><subject>Iron</subject><subject>Molybdenum</subject><subject>Plating</subject><subject>Plating baths</subject><subject>X-ray diffraction</subject><subject>Zinc</subject><subject>Zinc base alloys</subject><subject>Zn–Fe–Mo alloy coating</subject><issn>0257-8972</issn><issn>1879-3347</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNqFkD1OAzEQhS0EEiFwBeSSZhd7vX_uQBEhSEE0oaGxvN4xcbRZL7YTKR134IacBCeBmmYsz7z3NPMhdE1JSgktb1ep3zitrAxpFv8pyVNSsRM0onXFE8by6hSNSFZUSc2r7BxdeL8ihNCK5yO0XSwBg9agArYaD7ND7WQw_TtuZFhi22Po4tjZFgbrTTCxI_sWD84O4IIBf_A4G6LKbAEHcL10O_zWf39-TSGWZ4tl19kd3m8Zk_0lOtOy83D1-47R6_RhMZkl85fHp8n9PFEsL0JSUV6Uqm0aXmpGSq2I5nnJgUKtVWwp2daakpowRnKZsbIqaANN1mSyoLJt2BjdHHPjeh8b8EGsjVfQdbIHu_GC1llRxICcR2l5lCpnvXegxeDMOt4hKBF70GIl_kCLPWhBchFBR-Pd0QjxkK0BJ7wy0CtojYtERGvNfxE_PraOxQ</recordid><startdate>20160801</startdate><enddate>20160801</enddate><creator>Winiarski, J.</creator><creator>Leśniewicz, A.</creator><creator>Pohl, P.</creator><creator>Szczygieł, B.</creator><general>Elsevier B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7QQ</scope><scope>7SE</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><orcidid>https://orcid.org/0000-0003-0761-1579</orcidid></search><sort><creationdate>20160801</creationdate><title>The effect of pH of plating bath on electrodeposition and properties of protective ternary Zn–Fe–Mo alloy coatings</title><author>Winiarski, J. ; Leśniewicz, A. ; Pohl, P. ; Szczygieł, B.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c345t-71956cdbb96f306fc0f9469e1e8fc6f3cad8f10803304a236751beb2b2a51adb3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Anodic dissolution</topic><topic>Coatings</topic><topic>Cyclic voltammetry</topic><topic>Electrodeposition</topic><topic>Iron</topic><topic>Molybdenum</topic><topic>Plating</topic><topic>Plating baths</topic><topic>X-ray diffraction</topic><topic>Zinc</topic><topic>Zinc base alloys</topic><topic>Zn–Fe–Mo alloy coating</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Winiarski, J.</creatorcontrib><creatorcontrib>Leśniewicz, A.</creatorcontrib><creatorcontrib>Pohl, P.</creatorcontrib><creatorcontrib>Szczygieł, B.</creatorcontrib><collection>CrossRef</collection><collection>Ceramic Abstracts</collection><collection>Corrosion Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Surface & coatings technology</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Winiarski, J.</au><au>Leśniewicz, A.</au><au>Pohl, P.</au><au>Szczygieł, B.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>The effect of pH of plating bath on electrodeposition and properties of protective ternary Zn–Fe–Mo alloy coatings</atitle><jtitle>Surface & coatings technology</jtitle><date>2016-08-01</date><risdate>2016</risdate><volume>299</volume><spage>81</spage><epage>89</epage><pages>81-89</pages><issn>0257-8972</issn><eissn>1879-3347</eissn><abstract>Ternary Zn–Fe–Mo alloy coatings electrodeposition in a sulphate bath with tri-sodium citrate in the pH range 4.8–6.0 was studied. The increase of the plating bath pH from 4.8 to 6.0 leads to the iron content increase from 1.5 up to 7.9wt% and it is accompanied by a significant decrease in the current efficiency from 76 to 51%. It was demonstrated that molybdenum co-deposition starts at pH>4.8, because binary Zn–Fe alloy coating without a significant amount of molybdenum was obtained from the plating solution at pH4.8. The Mo content increases from 0.8wt% at pH5.1 to 2.7wt% at pH5.7 and 6.0. X-ray diffraction analysis as well as anodic linear sweep voltammetry measurements showed that within the considered plating solution pH range molybdenum modifies zinc microstructure to a very large extent. The deposited at pH5.4–6.0 Zn–Fe–Mo coatings contain a solid solution of iron and molybdenum in zinc and probably FeZnx phase, where 6.67<x<13. Potentiodynamic polarization revealed that the deposited at pH5.7 and 6.0 Zn–Fe–Mo coatings are characterized by a significantly lower corrosion rate in 0.5moldm−3 NaCl solution. This was confirmed by an electrochemical impedance spectroscopy test, where Zn–Fe(7.9wt%)–Mo(2.7wt%) alloy coating reached the highest resistance of charge transfer reaction during 24hours of exposure to NaCl solution.
[Display omitted]
•Zn–Fe–Mo coatings can be deposited from sulphate-citrate baths in pH range: 5.4–6.0.•Deposition of bright and homogenous Zn–Fe–Mo coatings is possible at pH close to 5.7.•The content of Fe and Mo in ternary alloy coatings depends on the pH of plating bath.•Codeposition of Mo causes an increase of Fe amount in Zn–Fe–Mo coating.•Increase in Mo and Fe contents shift corrosion potentials towards noble potentials.</abstract><pub>Elsevier B.V</pub><doi>10.1016/j.surfcoat.2016.04.073</doi><tpages>9</tpages><orcidid>https://orcid.org/0000-0003-0761-1579</orcidid></addata></record> |
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| subjects | Anodic dissolution Coatings Cyclic voltammetry Electrodeposition Iron Molybdenum Plating Plating baths X-ray diffraction Zinc Zinc base alloys Zn–Fe–Mo alloy coating |
| title | The effect of pH of plating bath on electrodeposition and properties of protective ternary Zn–Fe–Mo alloy coatings |
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