Discovering connections between terahertz vibrations and elasticity underpinning the collective dynamics of the HKUST-1 metal-organic framework

We employed a combination of theoretical and experimental techniques to study the metal-organic framework (MOF)-mechanics central to the paddle-wheel Cu 3 (BTC) 2 porous structure, commonly designated as HKUST-1. Lattice dynamics of the hybrid framework at below 18 THz were measured by means of Rama...

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Veröffentlicht in:	CrystEngComm 2016-01, Vol.18 (23), p.433-4312
Hauptverfasser:	Ryder, Matthew R, Civalleri, Bartolomeo, Cinque, Gianfelice, Tan, Jin-Chong
Format:	Artikel
Sprache:	eng
Schlagworte:	Deformation mechanisms Dynamics Elastic constants Lattices Metal-organic frameworks Poissons ratio Shear Vibration
Online-Zugang:	Volltext
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