Eight Zn() and Cd() complexes based on the aromatic C-centered triangular multicarboxylate and N-donor mixed ligands
Eight new Zn( ii ) and Cd( ii ) complexes based on the aromatic multicarboxylate and N-donor mixed ligands, namely Zn 2 (TCOPM)(2,2′-bipy)(OH)·1.25DMF (TCOPM = tris( p -carboxyphenyl)methane; 2,2′-bipy = 2,2′-bipyridine; DMF = N , N ′-dimethylformamide) ( 1 ), Zn 2 (α OH -TCOPM)(phen)(OH)·DMF (α OH...
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| Veröffentlicht in: | RSC advances 2016-01, Vol.6 (6), p.54993-54998 |
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| container_title | RSC advances |
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| creator | Nie, Aiyang Tong, Yongli Zhou, Hu Cao, Lingling Yu, Hui Shi, Chao Yuan, Aihua |
| description | Eight new Zn(
ii
) and Cd(
ii
) complexes based on the aromatic multicarboxylate and N-donor mixed ligands, namely Zn
2
(TCOPM)(2,2′-bipy)(OH)·1.25DMF (TCOPM = tris(
p
-carboxyphenyl)methane; 2,2′-bipy = 2,2′-bipyridine; DMF =
N
,
N
′-dimethylformamide) (
1
), Zn
2
(α
OH
-TCOPM)(phen)(OH)·DMF (α
OH
-TCOPM = tris(
p
-carboxyphenyl)methanol; phen = 1,10-phenanthroline) (
2
), Zn
2
(α
OH
-TCOPM)(tpy)(OH)(H
2
O) (tpy = 2,2′:6′,2′′-terpyridine) (
3
), Zn
3
(α
OH
-TCOPM)
2
(dpe)·2H
2
O (dpe = 4,4′-vinylenedipyridine) (
4
), Cd
3
(TCOPM)
2
(DMF)
2
(H
2
O)
2
(
5
), Cd
3
(TCOPM)
2
(4,4′-bipy) (
6
), Cd
3
(TCOPM)
2
(dpe) (
7
), and Cd
3
(α
OH
-TCOPM)
2
(2,2′-bipy)
2
·2DMF (
8
) were synthesized through a solvothermal reaction. The α
OH
-TCOPM ligand is generated
in situ
by the nucleophilic addition of the TCOPM ligand. X-ray crystallographic analysis reveals that complexes
1-3
,
5
, and
8
exhibit a two-dimensional (2D) layered structure, while
4
,
6
, and
7
possess a 3D open framework. The coordination mode of TCOPM and the type of N-donors ligands have obvious effects on the final structures. The luminescence properties in the solid state of
1-4
,
7
, and
8
were also investigated.
Eight Zn(
ii
) and Cd(
ii
) complexes based on the C-centered triangular multicarboxylate and N-donor mixed ligands were synthesized. The coordination mode of ligands have obvious effects on the final structures. Luminescent properties were investigated. |
| doi_str_mv | 10.1039/c6ra10144e |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1825509958</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1825509958</sourcerecordid><originalsourceid>FETCH-LOGICAL-c286t-23d0a0d5fb44fd2ca32ca1e4412be8e9d3c72409c204d34d8297d74288ba10ed3</originalsourceid><addsrcrecordid>eNpNkNFLwzAQxoMoOOZefBfyOIVqkqZZ-zjKpsJQEH3xpaTJdaukzUxS2P574ybqwXHHfT8-uA-hS0puKUmLOyWcpIRyDidoxAgXCSOiOP23n6OJ9x8klsgoE3SEwqJdbwJ-76fXWPYalzouynZbAzvwuJYeNLY9DhvA0tlOhlbhMlHQB3BRCq6V_Xow0uFuMFGUrra7vZEBDn5Piba9jWK7i7Rp1_HoL9BZI42Hyc8co7fl4rV8SFbP94_lfJUolouQsFQTSXTW1Jw3mimZxqbAOWU15FDoVM0YJ4WK_-mU65wVMz3jLM_rmAPodIymR9-ts58D-FB1rVdgjOzBDr6iOcsyUhRZHtGbI6qc9d5BU21d20m3ryipvtOtSvEyP6S7iPDVEXZe_XJ_6adfr0h2eA</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1825509958</pqid></control><display><type>article</type><title>Eight Zn() and Cd() complexes based on the aromatic C-centered triangular multicarboxylate and N-donor mixed ligands</title><source>Royal Society Of Chemistry Journals 2008-</source><creator>Nie, Aiyang ; Tong, Yongli ; Zhou, Hu ; Cao, Lingling ; Yu, Hui ; Shi, Chao ; Yuan, Aihua</creator><creatorcontrib>Nie, Aiyang ; Tong, Yongli ; Zhou, Hu ; Cao, Lingling ; Yu, Hui ; Shi, Chao ; Yuan, Aihua</creatorcontrib><description>Eight new Zn(
ii
) and Cd(
ii
) complexes based on the aromatic multicarboxylate and N-donor mixed ligands, namely Zn
2
(TCOPM)(2,2′-bipy)(OH)·1.25DMF (TCOPM = tris(
p
-carboxyphenyl)methane; 2,2′-bipy = 2,2′-bipyridine; DMF =
N
,
N
′-dimethylformamide) (
1
), Zn
2
(α
OH
-TCOPM)(phen)(OH)·DMF (α
OH
-TCOPM = tris(
p
-carboxyphenyl)methanol; phen = 1,10-phenanthroline) (
2
), Zn
2
(α
OH
-TCOPM)(tpy)(OH)(H
2
O) (tpy = 2,2′:6′,2′′-terpyridine) (
3
), Zn
3
(α
OH
-TCOPM)
2
(dpe)·2H
2
O (dpe = 4,4′-vinylenedipyridine) (
4
), Cd
3
(TCOPM)
2
(DMF)
2
(H
2
O)
2
(
5
), Cd
3
(TCOPM)
2
(4,4′-bipy) (
6
), Cd
3
(TCOPM)
2
(dpe) (
7
), and Cd
3
(α
OH
-TCOPM)
2
(2,2′-bipy)
2
·2DMF (
8
) were synthesized through a solvothermal reaction. The α
OH
-TCOPM ligand is generated
in situ
by the nucleophilic addition of the TCOPM ligand. X-ray crystallographic analysis reveals that complexes
1-3
,
5
, and
8
exhibit a two-dimensional (2D) layered structure, while
4
,
6
, and
7
possess a 3D open framework. The coordination mode of TCOPM and the type of N-donors ligands have obvious effects on the final structures. The luminescence properties in the solid state of
1-4
,
7
, and
8
were also investigated.
Eight Zn(
ii
) and Cd(
ii
) complexes based on the C-centered triangular multicarboxylate and N-donor mixed ligands were synthesized. The coordination mode of ligands have obvious effects on the final structures. Luminescent properties were investigated.</description><identifier>ISSN: 2046-2069</identifier><identifier>EISSN: 2046-2069</identifier><identifier>DOI: 10.1039/c6ra10144e</identifier><language>eng</language><subject>Crystallography ; Ligands ; Luminescence ; Solid state ; Three dimensional ; Two dimensional ; X-rays</subject><ispartof>RSC advances, 2016-01, Vol.6 (6), p.54993-54998</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c286t-23d0a0d5fb44fd2ca32ca1e4412be8e9d3c72409c204d34d8297d74288ba10ed3</citedby><cites>FETCH-LOGICAL-c286t-23d0a0d5fb44fd2ca32ca1e4412be8e9d3c72409c204d34d8297d74288ba10ed3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids></links><search><creatorcontrib>Nie, Aiyang</creatorcontrib><creatorcontrib>Tong, Yongli</creatorcontrib><creatorcontrib>Zhou, Hu</creatorcontrib><creatorcontrib>Cao, Lingling</creatorcontrib><creatorcontrib>Yu, Hui</creatorcontrib><creatorcontrib>Shi, Chao</creatorcontrib><creatorcontrib>Yuan, Aihua</creatorcontrib><title>Eight Zn() and Cd() complexes based on the aromatic C-centered triangular multicarboxylate and N-donor mixed ligands</title><title>RSC advances</title><description>Eight new Zn(
ii
) and Cd(
ii
) complexes based on the aromatic multicarboxylate and N-donor mixed ligands, namely Zn
2
(TCOPM)(2,2′-bipy)(OH)·1.25DMF (TCOPM = tris(
p
-carboxyphenyl)methane; 2,2′-bipy = 2,2′-bipyridine; DMF =
N
,
N
′-dimethylformamide) (
1
), Zn
2
(α
OH
-TCOPM)(phen)(OH)·DMF (α
OH
-TCOPM = tris(
p
-carboxyphenyl)methanol; phen = 1,10-phenanthroline) (
2
), Zn
2
(α
OH
-TCOPM)(tpy)(OH)(H
2
O) (tpy = 2,2′:6′,2′′-terpyridine) (
3
), Zn
3
(α
OH
-TCOPM)
2
(dpe)·2H
2
O (dpe = 4,4′-vinylenedipyridine) (
4
), Cd
3
(TCOPM)
2
(DMF)
2
(H
2
O)
2
(
5
), Cd
3
(TCOPM)
2
(4,4′-bipy) (
6
), Cd
3
(TCOPM)
2
(dpe) (
7
), and Cd
3
(α
OH
-TCOPM)
2
(2,2′-bipy)
2
·2DMF (
8
) were synthesized through a solvothermal reaction. The α
OH
-TCOPM ligand is generated
in situ
by the nucleophilic addition of the TCOPM ligand. X-ray crystallographic analysis reveals that complexes
1-3
,
5
, and
8
exhibit a two-dimensional (2D) layered structure, while
4
,
6
, and
7
possess a 3D open framework. The coordination mode of TCOPM and the type of N-donors ligands have obvious effects on the final structures. The luminescence properties in the solid state of
1-4
,
7
, and
8
were also investigated.
Eight Zn(
ii
) and Cd(
ii
) complexes based on the C-centered triangular multicarboxylate and N-donor mixed ligands were synthesized. The coordination mode of ligands have obvious effects on the final structures. Luminescent properties were investigated.</description><subject>Crystallography</subject><subject>Ligands</subject><subject>Luminescence</subject><subject>Solid state</subject><subject>Three dimensional</subject><subject>Two dimensional</subject><subject>X-rays</subject><issn>2046-2069</issn><issn>2046-2069</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNpNkNFLwzAQxoMoOOZefBfyOIVqkqZZ-zjKpsJQEH3xpaTJdaukzUxS2P574ybqwXHHfT8-uA-hS0puKUmLOyWcpIRyDidoxAgXCSOiOP23n6OJ9x8klsgoE3SEwqJdbwJ-76fXWPYalzouynZbAzvwuJYeNLY9DhvA0tlOhlbhMlHQB3BRCq6V_Xow0uFuMFGUrra7vZEBDn5Piba9jWK7i7Rp1_HoL9BZI42Hyc8co7fl4rV8SFbP94_lfJUolouQsFQTSXTW1Jw3mimZxqbAOWU15FDoVM0YJ4WK_-mU65wVMz3jLM_rmAPodIymR9-ts58D-FB1rVdgjOzBDr6iOcsyUhRZHtGbI6qc9d5BU21d20m3ryipvtOtSvEyP6S7iPDVEXZe_XJ_6adfr0h2eA</recordid><startdate>20160101</startdate><enddate>20160101</enddate><creator>Nie, Aiyang</creator><creator>Tong, Yongli</creator><creator>Zhou, Hu</creator><creator>Cao, Lingling</creator><creator>Yu, Hui</creator><creator>Shi, Chao</creator><creator>Yuan, Aihua</creator><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20160101</creationdate><title>Eight Zn() and Cd() complexes based on the aromatic C-centered triangular multicarboxylate and N-donor mixed ligands</title><author>Nie, Aiyang ; Tong, Yongli ; Zhou, Hu ; Cao, Lingling ; Yu, Hui ; Shi, Chao ; Yuan, Aihua</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c286t-23d0a0d5fb44fd2ca32ca1e4412be8e9d3c72409c204d34d8297d74288ba10ed3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Crystallography</topic><topic>Ligands</topic><topic>Luminescence</topic><topic>Solid state</topic><topic>Three dimensional</topic><topic>Two dimensional</topic><topic>X-rays</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Nie, Aiyang</creatorcontrib><creatorcontrib>Tong, Yongli</creatorcontrib><creatorcontrib>Zhou, Hu</creatorcontrib><creatorcontrib>Cao, Lingling</creatorcontrib><creatorcontrib>Yu, Hui</creatorcontrib><creatorcontrib>Shi, Chao</creatorcontrib><creatorcontrib>Yuan, Aihua</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>RSC advances</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Nie, Aiyang</au><au>Tong, Yongli</au><au>Zhou, Hu</au><au>Cao, Lingling</au><au>Yu, Hui</au><au>Shi, Chao</au><au>Yuan, Aihua</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Eight Zn() and Cd() complexes based on the aromatic C-centered triangular multicarboxylate and N-donor mixed ligands</atitle><jtitle>RSC advances</jtitle><date>2016-01-01</date><risdate>2016</risdate><volume>6</volume><issue>6</issue><spage>54993</spage><epage>54998</epage><pages>54993-54998</pages><issn>2046-2069</issn><eissn>2046-2069</eissn><abstract>Eight new Zn(
ii
) and Cd(
ii
) complexes based on the aromatic multicarboxylate and N-donor mixed ligands, namely Zn
2
(TCOPM)(2,2′-bipy)(OH)·1.25DMF (TCOPM = tris(
p
-carboxyphenyl)methane; 2,2′-bipy = 2,2′-bipyridine; DMF =
N
,
N
′-dimethylformamide) (
1
), Zn
2
(α
OH
-TCOPM)(phen)(OH)·DMF (α
OH
-TCOPM = tris(
p
-carboxyphenyl)methanol; phen = 1,10-phenanthroline) (
2
), Zn
2
(α
OH
-TCOPM)(tpy)(OH)(H
2
O) (tpy = 2,2′:6′,2′′-terpyridine) (
3
), Zn
3
(α
OH
-TCOPM)
2
(dpe)·2H
2
O (dpe = 4,4′-vinylenedipyridine) (
4
), Cd
3
(TCOPM)
2
(DMF)
2
(H
2
O)
2
(
5
), Cd
3
(TCOPM)
2
(4,4′-bipy) (
6
), Cd
3
(TCOPM)
2
(dpe) (
7
), and Cd
3
(α
OH
-TCOPM)
2
(2,2′-bipy)
2
·2DMF (
8
) were synthesized through a solvothermal reaction. The α
OH
-TCOPM ligand is generated
in situ
by the nucleophilic addition of the TCOPM ligand. X-ray crystallographic analysis reveals that complexes
1-3
,
5
, and
8
exhibit a two-dimensional (2D) layered structure, while
4
,
6
, and
7
possess a 3D open framework. The coordination mode of TCOPM and the type of N-donors ligands have obvious effects on the final structures. The luminescence properties in the solid state of
1-4
,
7
, and
8
were also investigated.
Eight Zn(
ii
) and Cd(
ii
) complexes based on the C-centered triangular multicarboxylate and N-donor mixed ligands were synthesized. The coordination mode of ligands have obvious effects on the final structures. Luminescent properties were investigated.</abstract><doi>10.1039/c6ra10144e</doi><tpages>6</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 2046-2069 |
| ispartof | RSC advances, 2016-01, Vol.6 (6), p.54993-54998 |
| issn | 2046-2069 2046-2069 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_1825509958 |
| source | Royal Society Of Chemistry Journals 2008- |
| subjects | Crystallography Ligands Luminescence Solid state Three dimensional Two dimensional X-rays |
| title | Eight Zn() and Cd() complexes based on the aromatic C-centered triangular multicarboxylate and N-donor mixed ligands |
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