Synthesis and flame retardant potential of polyols based on bisphenol‐S
Polyether polyols based on bisphenol‐S were prepared by alkoxylation and compared with analogs based on bisphenol‐A, as well as standard aromatic polyester, and polyether polyols for viscosity and temperature stability. Thermo‐oxidative stability was determined by thermo‐gravimetric analysis, pyroly...
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| Veröffentlicht in: | Journal of polymer science. Part A, Polymer chemistry Polymer chemistry, 2016-07, Vol.54 (14), p.2102-2108 |
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| container_issue | 14 |
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| container_title | Journal of polymer science. Part A, Polymer chemistry |
| container_volume | 54 |
| creator | Sonnenschein, Mark F. Virgili, Justin M. Babb, David A. Bell, Bruce M. Nickless, Brian C. |
| description | Polyether polyols based on bisphenol‐S were prepared by alkoxylation and compared with analogs based on bisphenol‐A, as well as standard aromatic polyester, and polyether polyols for viscosity and temperature stability. Thermo‐oxidative stability was determined by thermo‐gravimetric analysis, pyrolysis gas chromatography/mass spectroscopy, and evolved gas analysis mass spectroscopy. Incorporation of the sulfone moiety was found to dramatically improve the thermo‐oxidative stability of the neat polyol. Significant char formation was observed with gas phase evolution of flame retardant SO₂ and aromatic sulfone only apparent at about 600 °C. © 2016 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2016, 54, 2102–2108 |
| doi_str_mv | 10.1002/pola.28077 |
| format | Article |
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Chem. 2016, 54, 2102–2108</description><subject>Bisphenol A</subject><subject>Combustion</subject><subject>double-metal cyanide catalyst</subject><subject>flame retardance</subject><subject>Flame retardants</subject><subject>Mass spectroscopy</subject><subject>Polyester resins</subject><subject>Polyethers</subject><subject>polyethersulfone</subject><subject>Polyols</subject><subject>Stability</subject><issn>0887-624X</issn><issn>1099-0518</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNp90M1u1DAUBWALFYlpYcMLNBIbhJRy_Z8sq6rtVBpR6FDozrrJ2DTFE6d2RnR2fQSesU-CSwoLFmxsWf7O1dUh5DWFAwrA3g_B4wGrQOtnZEahrkuQtNohM6gqXSomrl6Q3ZRuAPKfrGbkbLntx2ubulRgvyqcx7Utoh0xrrAfiyGMth879EVw-eG3waeiwWRXReiLpkvDte2Df7j_uXxJnjv0yb56uvfI5cnx56N5uTg_PTs6XJSt4FyXrkHgQlKr6UpKLWvGRD6cayQHpRpFQXLtLCrdoKsVaqEZ1AJbbFvVAN8jb6e5Qwy3G5tGs-5Sa73H3oZNMrRiUlR5DM30zT_0Jmxin7czVNdcVRpEndW7SbUxpBStM0Ps1hi3hoJ5bNU8tmp-t5oxnfCPztvtf6T5eL44_JMpp0yXRnv3N4Pxu1Gaa2m-fjg19fzi0xd-NTci-_3JOwwGv8UumcslA6oAqJaMaf4LrH6SOQ</recordid><startdate>20160715</startdate><enddate>20160715</enddate><creator>Sonnenschein, Mark F.</creator><creator>Virgili, Justin M.</creator><creator>Babb, David A.</creator><creator>Bell, Bruce M.</creator><creator>Nickless, Brian C.</creator><general>John Wiley & Sons, Ltd</general><general>Blackwell Publishing Ltd</general><general>Wiley Subscription Services, Inc</general><scope>FBQ</scope><scope>BSCLL</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20160715</creationdate><title>Synthesis and flame retardant potential of polyols based on bisphenol‐S</title><author>Sonnenschein, Mark F. ; Virgili, Justin M. ; Babb, David A. ; Bell, Bruce M. ; Nickless, Brian C.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4337-fba03451e71d55759224592ffb53066b610537fea67baf96a7472094acacc6b03</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Bisphenol A</topic><topic>Combustion</topic><topic>double-metal cyanide catalyst</topic><topic>flame retardance</topic><topic>Flame retardants</topic><topic>Mass spectroscopy</topic><topic>Polyester resins</topic><topic>Polyethers</topic><topic>polyethersulfone</topic><topic>Polyols</topic><topic>Stability</topic><toplevel>online_resources</toplevel><creatorcontrib>Sonnenschein, Mark F.</creatorcontrib><creatorcontrib>Virgili, Justin M.</creatorcontrib><creatorcontrib>Babb, David A.</creatorcontrib><creatorcontrib>Bell, Bruce M.</creatorcontrib><creatorcontrib>Nickless, Brian C.</creatorcontrib><collection>AGRIS</collection><collection>Istex</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of polymer science. 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| ispartof | Journal of polymer science. Part A, Polymer chemistry, 2016-07, Vol.54 (14), p.2102-2108 |
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Bisphenol A Combustion double-metal cyanide catalyst flame retardance Flame retardants Mass spectroscopy Polyester resins Polyethers polyethersulfone Polyols Stability |
| title | Synthesis and flame retardant potential of polyols based on bisphenol‐S |
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