Core-shell morphology of Au-TiO sub(2)-graphene oxide nanocomposite exhibiting enhanced hydrogen production from water
The core-shell morphology of graphene oxide (GO) coated Au-TiO sub(2) (Au-TiO sub(2)-GO) nanocatalysts has displayed enhanced photocatalytic activity for hydrogen production from water. The structural morphology of Au-TiO sub(2)-GO revealed a thin layer ( similar to 2.5 nm) of GO shell over Au-TiO s...
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Veröffentlicht in: | Journal of industrial and engineering chemistry (Seoul, Korea) Korea), 2016-05, Vol.37, p.288-294 |
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container_title | Journal of industrial and engineering chemistry (Seoul, Korea) |
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creator | Rather, Rayees Ahmad Singh, Satnam Pal, Bonamali |
description | The core-shell morphology of graphene oxide (GO) coated Au-TiO sub(2) (Au-TiO sub(2)-GO) nanocatalysts has displayed enhanced photocatalytic activity for hydrogen production from water. The structural morphology of Au-TiO sub(2)-GO revealed a thin layer ( similar to 2.5 nm) of GO shell over Au-TiO sub(2) core, possessing higher specific surface area ( similar to 100 m super(2) g super(-1)). Raman spectroscopy revealed bands at 1593 cm super(-1) and 1317 cm super(-1) corresponding to G and D lines. GO facilitates decreases in the rate of e super(-)/h super(+) recombination due to its reduction potential and Au loading increase sensitization of TiO sub(2) in the visible light resulting in the increased activity for H sub(2) production ( similar to 114 mu mol) from the water. |
doi_str_mv | 10.1016/j.jiec.2016.03.039 |
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GO facilitates decreases in the rate of e super(-)/h super(+) recombination due to its reduction potential and Au loading increase sensitization of TiO sub(2) in the visible light resulting in the increased activity for H sub(2) production ( similar to 114 mu mol) from the water.</description><subject>Band spectra</subject><subject>Graphene</subject><subject>Hydrogen production</subject><subject>Morphology</subject><subject>Nanocomposites</subject><subject>Oxides</subject><subject>Thin films</subject><subject>Titanium dioxide</subject><issn>1226-086X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNqVjrtOwzAUhj2ARLm8ANMZy-DgSzFhRBWIrUsHtspNTmJHiU_wBdq3JwMvgPRL3zd8w8_YvRSVFNI8DtXgsanU4pXQy14u2EoqZbiozecVu05pEMIIXZsV-95SRJ4cjiNMFGdHI_VnoA5eC9_7HaRyXKsH3kc7OwwIdPItQrCBGppmSj4j4Mn5o88-9IDB2dBgC-7cRuoxwBypLU32FKCLNMGPzRhv2WVnx4R3f7xh6_e3_faDL_VXwZQPk0_NcsoGpJIOslZPm2etzUb_I_0F85BXOQ</recordid><startdate>20160525</startdate><enddate>20160525</enddate><creator>Rather, Rayees Ahmad</creator><creator>Singh, Satnam</creator><creator>Pal, Bonamali</creator><scope>7U5</scope><scope>8FD</scope><scope>L7M</scope></search><sort><creationdate>20160525</creationdate><title>Core-shell morphology of Au-TiO sub(2)-graphene oxide nanocomposite exhibiting enhanced hydrogen production from water</title><author>Rather, Rayees Ahmad ; Singh, Satnam ; Pal, Bonamali</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-proquest_miscellaneous_18254733643</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Band spectra</topic><topic>Graphene</topic><topic>Hydrogen production</topic><topic>Morphology</topic><topic>Nanocomposites</topic><topic>Oxides</topic><topic>Thin films</topic><topic>Titanium dioxide</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Rather, Rayees Ahmad</creatorcontrib><creatorcontrib>Singh, Satnam</creatorcontrib><creatorcontrib>Pal, Bonamali</creatorcontrib><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Journal of industrial and engineering chemistry (Seoul, Korea)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Rather, Rayees Ahmad</au><au>Singh, Satnam</au><au>Pal, Bonamali</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Core-shell morphology of Au-TiO sub(2)-graphene oxide nanocomposite exhibiting enhanced hydrogen production from water</atitle><jtitle>Journal of industrial and engineering chemistry (Seoul, Korea)</jtitle><date>2016-05-25</date><risdate>2016</risdate><volume>37</volume><spage>288</spage><epage>294</epage><pages>288-294</pages><issn>1226-086X</issn><abstract>The core-shell morphology of graphene oxide (GO) coated Au-TiO sub(2) (Au-TiO sub(2)-GO) nanocatalysts has displayed enhanced photocatalytic activity for hydrogen production from water. The structural morphology of Au-TiO sub(2)-GO revealed a thin layer ( similar to 2.5 nm) of GO shell over Au-TiO sub(2) core, possessing higher specific surface area ( similar to 100 m super(2) g super(-1)). Raman spectroscopy revealed bands at 1593 cm super(-1) and 1317 cm super(-1) corresponding to G and D lines. GO facilitates decreases in the rate of e super(-)/h super(+) recombination due to its reduction potential and Au loading increase sensitization of TiO sub(2) in the visible light resulting in the increased activity for H sub(2) production ( similar to 114 mu mol) from the water.</abstract><doi>10.1016/j.jiec.2016.03.039</doi></addata></record> |
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subjects | Band spectra Graphene Hydrogen production Morphology Nanocomposites Oxides Thin films Titanium dioxide |
title | Core-shell morphology of Au-TiO sub(2)-graphene oxide nanocomposite exhibiting enhanced hydrogen production from water |
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